Rheometer

About: Rheometer is a research topic. Over the lifetime, 5759 publications have been published within this topic receiving 125849 citations.

Nonlinear Shear and Extensional Flow Dynamics of Wormlike Surfactant Solutions

Abstract: Nonlinear shear and extensional flow dynamics of a wormlike micellar solution based on erucyl bis(2-hydroxyethyl) methyl ammonium chloride (EHAC) are reported here. The influences of surfactant (EHAC) and salt (NH4Cl) concentrations on the linear viscoelastic parameters are determined using small amplitude oscillatory shear experiments. The steady and time-dependent shear rheology is determined in a double gap Couette cell, and transient extensional flow measurements are performed in a capillary breakup extensional rheometer (CABER). In the nonlinear shear flow experiments, the micellar fluid samples show strong hysteretic behavior upon increasing and decreasing the imposed shear stress due to the development of shear-banding instabilities. The non-monotone flow curves of stress versus shear rate can be successfully modeled in a macroscopic sense by using the single-mode Giesekus constitutive equation. The temporal evolution of the flow structure of the surfactant solutions in the Couette flow geometry is analyzed by instantaneous shear rate measurements for various values of controlled shear stress, along with FFT analysis. The results indicate that the steady flow bifurcates to a global time-dependent state as soon as the shear-banding/hysteresis regime is reached. Increasing the salt–surfactant ratio or the temperature is found to stabilize the flow, and corresponds to decreasing values of anisotropy factor in the Giesekus model. Finally, we have investigated the dynamics of capillary breakup of the micellar fluid samples in uniaxial extensional flow. The filament thinning behavior of the micellar fluid samples is also accurately predicted by the Giesekus constitutive equation. Indeed quantitative agreement between the experimental and numerical results can be obtained providing that the relaxation time of the wormlike micellar solutions in extensional flows is a factor of three lower than in shear flows.

Microdevices for extensional rheometry of low viscosity elastic liquids: a review

Abstract: Extensional flows and the underlying stability/instability mechanisms are of extreme relevance to the efficient operation of inkjet printing, coating processes and drug delivery systems, as well as for the generation of micro droplets. The development of an extensional rheometer to characterize the extensional properties of low viscosity fluids has therefore stimulated great interest of researchers, particularly in the last decade. Microfluidics has proven to be an extraordinary working platform and different configurations of potential extensional microrheometers have been proposed. In this review, we present an overview of several successful designs, together with a critical assessment of their capabilities and limitations.

Non‐Linear Behavior of Viscoelastic Materials. I. Disperse Systems of Polystyrene Solution and Carbon Black

Abstract: To determine non‐linear viscoelasticity parameters for disperse and high‐polymeric systems, some fundamental relations have been derived between these parameters and the experimental quantities by viscoelastometry, particularly with a torsionally oscillating rheometer, on the basis of the general theory presented by Green and Rivlin. The non‐linear viscoelasticity of several disperse systems consisting of polystyrene solutions and carbon black has been measured by means of the torsionally oscillating rheometer at various temperatures ranging from 100 to 170°C, and in a frequency range from 2×10−3 to 0.5 cycle per sec. As a result of harmonic analysis of the experimental results, it has been revealed that the resultant torque consists of the fundamental component and odd harmonics, and that the energy dissipated during one cycle is the same as that calculated from the fundamental component alone. Frequency dependence curves at various temperatures for G1′ and G1″, which correspond to G′ and G″ for linear v...

Determination of chocolate viscosity

Abstract: A critical appraisal of the Casson model for measuring chocolate versus a new proposed method is performed. The new method is validated with both research grade rheometers and factory grade viscometers. This includes elements of measurement uncertainty. In this way, a new reference method is validated for the viscosity of chocolate and related cocoa products using factory grade viscometers. It involves recording: (1) the value of the stress at a shear rate of 5 s -1 to represent the yield stress of chocolate, (2) the value of the viscosity at a shear rate of 40 s -1 to represent the high shear viscosity, and (3) the difference between the viscosity measured at a shear rate of 40 s -1 during the ramp up and down in shear rate to represent thixotropy. Results relate to the solid to liquid glass transition of dispersions under applied stress, and it is shown that they reflect existing theories of stress induced formation and rupture of fractal aggregates, for particle crowded colloidal suspensions with low interaction energy.