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Selective catalytic reduction

About: Selective catalytic reduction is a research topic. Over the lifetime, 10502 publications have been published within this topic receiving 226291 citations.


Papers
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Journal ArticleDOI
TL;DR: In this article, the effects of water on vanadia/titania catalysts were investigated in the presence and absence of water in the feed gas, as well as some results from vacuum temperatureprogrammed desorption studies.

83 citations

Journal ArticleDOI
TL;DR: In this article, the authors investigated the effect of ABS on selective catalytic reduction (SCR) process at low temperatures via TG-MS analysis and showed that CeO 2 could facilitate ABS decomposition over the V 2 O 5 -MoO 3 /CeO 2 -TiO 2 catalyst.

83 citations

Journal ArticleDOI
TL;DR: A series of Ce-Ti mixed oxides (CeaTi1−a) were successfully synthesized by a spontaneous deposition method and evaluated in selective catalytic reduction of NO with NH3 (NH3-SCR) as discussed by the authors.

83 citations

Journal ArticleDOI
TL;DR: In this article, the resistances of the Cu-SSZ-13 to aging and alkali metal poisoning for selective catalytic reduction of NOx with NH3 (NH3-SCR) were studied and comprehensive investigations were performed to better understand the poisoning mechanisms.

83 citations

Journal ArticleDOI
TL;DR: A series of Ag-based catalysts supported on unpromoted or Ce-promoted γ-alumina were prepared and studied for the selective catalytic reduction (SCR) of NOx with various reductants as discussed by the authors.
Abstract: A series of Ag-based catalysts supported on unpromoted or Ce-promoted γ-alumina were prepared and studied for the selective catalytic reduction (SCR) of NOx with various reductants. The activity for NO reduction increased as the oxygen-content in the reaction mixture increased from 2% to 10%. The influence of Ag loading, the catalytic support used and the type of the reductant on NO reduction was examined. Moderate silver loadings (3%) exhibit the most efficient deNOx activity, while increasing the metal loading or using a Ce-promoted alumina support inhibits the catalytic activity. Among C3H6, CH4 and CO used as reducing agents, C3H6 has the higher reducing activity. C2H4, C2H6, C3H8, C4H10, 1-C4H8 and 1,3-C4H6 were also tested as reducing agents, suggesting that use of higher and less saturated hydrocarbons results in an enhanced deNOx performance. Higher concentrations of the optimum reductant (1-C4H8) significantly improved the deNOx performance, achieving over 80% NOx reduction and an interestingly broad active temperature window (300–550 °C). NOx is reduced by reacting with intermediates generated from partial oxidation of hydrocarbons used as reductants. Increased availability of these species either by more C atoms in higher hydrocarbons, their easier formation from less saturated hydrocarbons or higher reductant concentration explains the improvement of NOx reduction. The performance of Ag catalysts was linked with the formation of different crystal phases, which are stabilized through a strong interaction with the alumina support. Existence of Ag in oxidation state +1 seems to be the active phase that favors most the NO reduction.

83 citations


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Performance
Metrics
No. of papers in the topic in previous years
YearPapers
2023311
2022632
2021546
2020583
2019604
2018595