Topic
Silane
About: Silane is a research topic. Over the lifetime, 21198 publications have been published within this topic receiving 303199 citations. The topic is also known as: monosilane & silicon tetrahydride.
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TL;DR: In this paper, the authors review the recent progress in using silane coupling agents for NFPCs, summarizes the effective silane structures from the silane family, clarifies the interaction mechanisms between natural fibers and polymer matrices, and presents the effects of silane treatments on the mechanical and outdoor performance of the resulting composites.
Abstract: Natural fiber reinforced polymer composites (NFPCs) provide the customers with more alternatives in the material market due to their unique advantages. Poor fiber–matrix interfacial adhesion may, however, negatively affect the physical and mechanical properties of the resulting composites due to the surface incompatibility between hydrophilic natural fibers and non-polar polymers (thermoplastics and thermosets). A variety of silanes (mostly trialkoxysilanes) have been applied as coupling agents in the NFPCs to promote interfacial adhesion and improve the properties of composites. This paper reviews the recent progress in using silane coupling agents for NFPCs, summarizes the effective silane structures from the silane family, clarifies the interaction mechanisms between natural fibers and polymer matrices, and presents the effects of silane treatments on the mechanical and outdoor performance of the resulting composites.
1,725 citations
Patent•
16 Sep 1974TL;DR: In this article, a carboxylic acid anhydride was used as a coupling agent for glass fibers to resinous plastics, including thermoplastics and thermosetting resins and the elastomeric materials.
Abstract: The silane coupling agents are prepared by reaction of the mercapto silane with a carboxylic acid anhydride whereby the mercapto group adds across the double bond of the anhydride. The compounds can be converted to the corresponding diacid by reaction with water, and are useful as coupling agents for bonding glass fibers to resinous plastics, including thermoplastics and thermosetting resins and the elastomeric materials.
1,331 citations
TL;DR: In this article, thin film solar cells, ∼ 1 μm thick, have been fabricated from amorphous silicon deposited from a glow discharge in silane, and the cells were made in a p i n structure by using doping gases in the discharge.
Abstract: Thin film solar cells, ∼1 μm thick, have been fabricated from amorphous silicon deposited from a glow discharge in silane. The cells were made in a p‐i‐n structure by using doping gases in the discharge. The best power conversion efficiency to date is 2.4% in AM‐1 sunlight. The maximum efficiency of thin‐film amorphous silicon solar cells is estimated to be ∼14–15%.
1,158 citations
TL;DR: In this paper, the magnetite nanoparticles were prepared by coprecipitation of Fe 2 and Fe 3 with NH4OH, and then, amino silane was coated onto the surface of magnetite particles.
803 citations
TL;DR: In this paper, the degree of fiber-matrix adhesion and its effect on the mechanical reinforcement of short henequen fibers and a polyethylene matrix was studied, and the surface treatments were: an alkali treatment, a silane coupling agent and the pre-impregnation process of the HDPE/xylene solution.
Abstract: The degree of fiber–matrix adhesion and its effect on the mechanical reinforcement of short henequen fibers and a polyethylene matrix was studied. The surface treatments were: an alkali treatment, a silane coupling agent and the pre-impregnation process of the HDPE/xylene solution. The presence of Si–O–cellulose and Si–O–Si bonds on the lignocellulosic surface confirmed that the silane coupling agent was efficiently held on the fibres surface through both condensation with cellulose hydroxyl groups and self-condensation between silanol groups. The fiber–matrix interface shear strength (IFSS) was used as an indicator of the fiber–matrix adhesion improvement, and also to determine a suitable value of fiber length in order to process the composite with relative ease. It was noticed that the IFSS observed for the different fiber surface treatments increased and such interface strength almost doubled only by changing the mechanical interaction and the chemical interactions between fiber and matrix. HDPE-henequen fiber composite materials were prepared with a 20% v/v fiber content and the tensile, flexural and shear properties were studied. The comparison of tensile properties of the composites showed that the silane treatment and the matrix-resin pre-impregnation process of the fiber produced a significant increase in tensile strength, while the tensile modulus remained relatively unaffected. The increase in tensile strength was only possible when the henequen fibers were treated first with an alkaline solution. It was also shown that the silane treatment produced a significant increase in flexural strength while the flexural modulus also remained relatively unaffected. The shear properties of the composites also increased significantly, but, only when the henequen fibers were treated with the silane coupling agent. Scanning electron microscopy (SEM) studies of the composites failure surfaces also indicated that there is an improved adhesion between fiber and matrix. Examination of the failure surfaces also indicated differences in the interfacial failure mode. With increasing fiber–matrix adhesion the failure mode changed from interfacial failure and considerable fiber pull-out from the matrix for the untreated fiber to matrix yielding and fiber and matrix tearing for the alkaline, matrix-resin pre-impregnation and silane treated fibers.
769 citations