Silicon nitride

About: Silicon nitride is a research topic. Over the lifetime, 32678 publications have been published within this topic receiving 413599 citations. The topic is also known as: N₄Si₃.

Semiconductor device and manufacturing method therefor

Abstract: A semiconductor device has a diffusion layer formed on a silicon substrate, an interlayer insulator which covers a surface of the silicon substrate and whose surface is planarized, and a dielectric capacitor composed of a lower electrode connected to the diffusion layer via a buried conductive layer which is buried within a contact hole opened in the interlayer insulator and which is formed of a barrier metal layer composed of a contact plug, a low resistance layer and tantalum silicon nitride, and a dielectric film formed on the lower electrode, and an upper electrode. The lower electrode has a side-wall sloped configuration that its cross-sectional area monotonously increases from the buried conductive layer side toward the upper dielectric film. Thus, a high-integration semiconductor device which allows the lower electrode to be micro-fabricated and enables lower-voltage operation and higher reliability can be obtained.

Plasma etch resistant coating and process

Abstract: A protective coating is provided herein and methods of using the protective coating for susceptors used in semiconductor deposition chambers are described. In the preferred embodiments, CVD chamber equipment, such as a susceptor, is protected from plasma etch cleaning. Prior to CVD of silicon nitride, the chamber equipment is first coated with an emissivity-stabilizing layer, such as silicon nitride. This layer is then superficially oxidized. After repeated cycles of deposited silicon nitride upon different substrates in sequence, the chamber is emptied of wafers and a plasma cleaning process is conducted. Plasma cleaning is preferably selective against the silicon oxynitride protective coating. After the plasma cleaning process, the emissivity-stabilizing layer is reapplied, oxidized, and a plurality of deposition cycles can commence again.

Chemical vapour deposition promoted by r.f. discharge

Abstract: In the vapour deposition method investigated, chemical reactions take place in an r.f. discharge instead of being promoted thermally. Glassy layers are deposited at 2–4μ/hr on cold or heated substrates. Materials prepared and evaluated include: (a) silicon from silane, (b) silicon dioxide from silane and nitrous oxide, (c) silicon nitride from silane and anhydrous ammonia. The method is expected to have a much wider application.

Method of fabricating silicon nitride nanodots

Abstract: A method of forming silicon nitride nanodots that comprises the steps of forming silicon nanodots and then nitriding the silicon nanodots by exposing them to a nitrogen containing gas. Silicon nanodots were formed by low pressure chemical vapor deposition. Nitriding of the silicon nanodots was performed by exposing them to nitrogen radicals formed in a microwave radical generator, using N2 as the source gas.

Overcoming Si3N4 film stress limitations for High Quality factor ring resonators

Abstract: Silicon nitride (Si3N4) ring resonators are critical for a variety of photonic devices. However the intrinsically high film stress of silicon nitride has limited both the optical confinement and quality factor (Q) of ring resonators. We show that stress in Si3N4 films can be overcome by introducing mechanical trenches for isolating photonic devices from propagating cracks. We demonstrate a Si3N4 ring resonator with an intrinsic quality factor of 7 million, corresponding to a propagation loss of 4.2 dB/m. This is the highest quality factor reported to date for high confinement Si3N4 ring resonators in the 1550 nm wavelength range.