Single crystal

About: Single crystal is a research topic. Over the lifetime, 59617 publications have been published within this topic receiving 870828 citations.

Structural Characterization of Self-Assembled MnO2 Nanosheets from Birnessite Manganese Oxide Single Crystals

Abstract: We report in this paper the studies on protonation, exfoliation, and self-assembly of birnessite-type manganese oxide single crystals. The protonation was carried out by extracting K+ ions from the potassium manganese oxide single crystals in a (NH4)2S2O8 aqueous solution heated at 60 °C, exfoliation to nanosheets by the intercalation of TMA+ ions followed by water-washing, and the self-assembly of MnO2 nanosheets in a dilute NaCl solution. The structures of the samples at these stages were systematically investigated using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared, thermogravimetric analysis-differential thermal analysis, and chemical compositional analysis. Electron density distribution in the protonated single crystal was visualized by whole-pattern fitting based on the maximum entropy method. The results indicated that the protonated single crystals can be exfoliated to MnO2 u...

Controlling the growth and luminescence properties of well-faceted ZnO nanorods

Abstract: In this work, we synthesized ZnO nanorods by a wet chemical process. By varying different parameters of the synthesis process like precursor concentration, solvent used, surfactant, temperature, and reaction time, we were able to control the aspect ratio (l/d) and sharpness factor (Sf = h/b) of the rods. Rods with an aspect ratio of ∼20 and a sharpness factor of 10 were repeatedly obtained and characterized from scanning electron microscopy. High-resolution transmission electron microscopy and dark field analysis revealed that nanorods grow as a single crystal along the c axis [0001]. UV and visible emission was obtained in both flat- and sharp-terminated rods. According to the XPS analysis, rods present an excess of Zn2+ of ∼4% that is responsible for the strong yellow emission band. Such defects were removed by annealing of the sample at 200 °C for 2 h. Possible mechanisms of changes in the morphology produced by changes in the synthesis process are also discussed.

Single-Crystal Thin Films of Cesium Lead Bromide Perovskite Epitaxially Grown on Metal Oxide Perovskite (SrTiO3)

Abstract: High-quality metal halide perovskite single crystals have low defect densities and excellent photophysical properties, yet thin films are the most sought after material geometry for optoelectronic devices. Perovskite single-crystal thin films (SCTFs) would be highly desirable for high-performance devices, but their growth remains challenging, particularly for inorganic metal halide perovskites. Herein, we report the facile vapor-phase epitaxial growth of cesium lead bromide perovskite (CsPbBr3) continuous SCTFs with controllable micrometer thickness, as well as nanoplate arrays, on traditional oxide perovskite SrTiO3(100) substrates. Heteroepitaxial single-crystal growth is enabled by the serendipitous incommensurate lattice match between these two perovskites, and overcoming the limitation of island-forming Volmer–Weber crystal growth is critical for growing large-area continuous thin films. Time-resolved photoluminescence, transient reflection spectroscopy, and electrical transport measurements show tha...

Epitaxial Mn2.5Ga thin films with giant perpendicular magnetic anisotropy for spintronic devices

Abstract: We report on epitaxial growth and magnetic properties of Mn2.5Ga thin films, which were deposited on Cr/MgO single crystal substrates by magnetron sputtering. X-ray diffraction results revealed the epitaxial relationships as Mn2.5Ga(001)[100]∥Cr(001)[110]∥MgO(001)[100]. The presence of (002) and (011) superlattice peaks indicates that the films were crystallized into DO22 ordered structures. The perpendicular magnetic anisotropy (PMA) properties were found to be related to the extent of DO22 chemical ordering. A giant PMA (Kueff=1.2×107 erg/cm3) and low saturation magnetization (Ms=250 emu/cm3) can be obtained for the film with highest chemical ordering parameter (S=0.8).

The low-temperature plastic deformation of α-titanium and the core structure of a-type screw dislocations

Abstract: α-titanium single crystals, containing three different amounts of interstitial impurities, have been tested in compression at temperatures between 77 and 700 K. The mechanical behaviour is characterized by a strong temperature dependence of the yield stress for slip on the primary prismatic slip plane (1010)[1210], a strong dependence of the critical resolved shear stress on the orientation of crystal axis and the failure of the Schmid law, an anomaly at temperatures between 300 and 500 K which is associated with cross-slip into a first-order pyramidal plane, and the occurrence of two hardening stages on the deformation curves at low temperatures. Both conventional and in situ transmission electron microscopy examinations revealed that a large lattice friction opposes the motion of a-type screw dislocations at temperatures below 550 K. Since edge dislocations are found to be highly mobile, it appears that, at low temperatures, the yield stress of pure α-titanium is governed by a Peierls force act...