Showing papers on "Sodium chlorate published in 1984"
TL;DR: A critical review of the chemistry, electrochemistry, and engineering principles involved in the production of sodium chlorate is presented in this paper, with emphasis on materials of construction, and trends towards developing cost and energy effective methods for producing Sodium chlorate.
Abstract: A critical review of the chemistry, electrochemistry, and engineering principles involved in the production of sodium chlorate is presented. Various chlorate manufacturing technologies were discussed, with emphasis on materials of construction, and trends towards developing cost and energy effective methods for producing sodium chlorate.
64 citations
TL;DR: The inefficacy of methylene blue in the treatment of a case of chlorate poisoning that was observed suggests an increased membrane rigidity due to membrane protein polymerisation, as demonstrated by SDS polyacrylamide gel electrophoresis.
27 citations
TL;DR: A critical review of the chemistry, electrochemistry, and engineering principles involved in the production of sodium chlorate is presented in this article, with emphasis on materials of construction, and trends towards developing cost and energy effective methods for producing Sodium chlorate.
Abstract: A critical review of the chemistry, electrochemistry, and engineering principles involved in the production of sodium chlorate is presented. Various chlorate manufacturing technologies were discussed, with emphasis on materials of construction, and trends towards developing cost and energy effective methods for producing sodium chlorate.
14 citations
Patent•
19 Sep 1984
TL;DR: Amorphous alloys for electrodes in the electrolysis which are surface-activated and consist of 10-30 atomic percent P and/or Si, 20 atomic percent or more Pd and 20-50 atomic percent Ru, Rh, Ir and or Pt have been used for bromides or organic compounds or as electrodes in batteries or fuel cells.
Abstract: Amorphous alloys for electrodes in the electrolysis which are surface-activated and consist of 10-30 atomic percent P and/or Si, 20 atomic percent or more Pd and 20-50 atomic percent Ru, Rh, Ir and/or Pt The alloys sometimes contain further 15 atomic percent or less Ti, Zr, Nb and/or Ta By surface activating certain amorphous alloy electrodes (generally known from GB 2051158B) their electrocatalytic activity is enhanced The electrodes may be surface activated by diffusing zinc into the surface and then leaching the zinc from the surface The electrodes may be used from the electrolysis of dilute sodium chloride solutions to produce sodium chlorate, for the electrolysis of bromides or of organic compounds or as electrodes in batteries or fuel cells
6 citations
Patent•
06 Jun 1984
TL;DR: In this paper, a solution of acid sodium chlorate at high sulphuric acid normality to which methanol is fed is used to produce high efficiency chlorine dioxide, and the incidence of white-out is avoided by feeding chloride ions to the reaction medium.
Abstract: @ Chlorine dioxide is formed at high efficiency from a solution of acid sodium chlorate at high sulphuric acid normality to which methanol is fed. The reaction medium is at its boiling point under a subatmospheric pressure. The incidence of white-outs is avoided by feeding chloride ions to the reaction medium, while the efficiency of chlorine dioxide production remains high. The chlorine dioxide generating process may be effected over a wide range of total acid normality from about 7 to about 12 normal.
2 citations