Topic
Sodium sulfide
About: Sodium sulfide is a research topic. Over the lifetime, 2851 publications have been published within this topic receiving 27733 citations. The topic is also known as: disodium sulfide.
Papers published on a yearly basis
Papers
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TL;DR: In this article, a cleaner production process was proposed that would selectively remove antimony as sodium pyroantimonate, which exhibited a regular tetragonal morphology and achieved a precipitation ratio of antimony exceeded 99.80% during the second step.
26 citations
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TL;DR: In this article, a simple one-pot reaction of 3-formyl-2-mercaptoquinolines with sodium sulfide and hydrochloric acid in ethanol was proposed.
Abstract: A convenient, efficient, and inexpensive procedure for the synthesis of 3-formyl-2-mercaptoquinolines 2a–l has been developed by a simple one-pot reaction of 3-formyl-2-chloroquinolines 1a–l with sodium sulfide and hydrochloric acid in ethanol. The structures of all the synthesized compounds were elucidated on the basis of elemental analyses and IR, 1 H NMR, and mass spectral data.
26 citations
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TL;DR: Ionic strength and pH were found to be important factors controlling the extent of adsorptive losses with minimal loss for pHs greater than 9 and for soft waters.
Abstract: Zinc sulfide clusters were synthesized and characterized at low micromolar concentrations to assess the effect of metal-sulfide ligands on metal toxicity to aquatic organisms in oxic environments. Recommended preparation times are greater than 2 h initial reaction of equimolar sodium sulfide and zinc nitrate, followed by oxic aeration for 3 d. Ionic strength, pH, and anoxic stabilization time were found to be relatively unimportant in controlling the final yield. Adsorptive losses of zinc sulfide (ZnS) clusters to surfaces, however, were significant for a variety of vessel materials and membrane filters. Ionic strength and pH were found to be important factors controlling the extent of adsorptive losses with minimal loss for pHs greater than 9 and for soft waters. The Ag(I), Cu(II), and Hg(II) as metal sulfides completely suppress the analysis of sulfide, whereas Pb(II), Mn(II), and Co(II) partially suppress the analysis of sulfide by the methylene blue technique. Ultraviolet and fluorescence spectra are shown for synthesized ZnS clusters.
25 citations
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10 May 1985
TL;DR: In this paper, a treatment technique for drastically reducing the volume of hazardous sludge generated by the chemical reduction of chromium contaminants and the precipitation of heavy metal contaminants from contaminated electroplating wastewater is presented.
Abstract: The present invention involves a treatment technique for drastically reducing the volume of hazardous sludge generated by the chemical reduction of chromium contaminants and the precipitation of heavy metal contaminants from contaminated electroplating wastewater. The wastewater is first adjusted to a pH of from about 8 to 10 and then treated with sodium sulfide to provide sulfide ions to effect precipitation of heavy metal contaminants followed by treatment with ferrous sulfate or ferrous chloride to provide ferrous ions to chemically reduce the hexavalent chromium to its trivalent state. This method produces approximately one-fourth the sludge generated by the previously known acidic reaction treatment using only ferrous sulfide.
25 citations
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TL;DR: In this article, a protocol for the absolute determination of the various polysulfide species based on 1H NMR was applied to monitor the amount of such ions in alkaline media produced at different conditions.
Abstract: The recently developed protocol for the absolute determination of the various polysulfide species based by 1H NMR was applied to monitor the amount of such ions in alkaline media produced at different conditions. The thermal stability of each individual polysulfide species was also evaluated in temperature ranges representative of a typical alkaline pulping process. Overall, the species, S12-, S22-, S32-, S42-, S52-, and S62- were detected and quantified in all alkaline conditions evaluated. The concentration of sodium sulfide and the temperature were found to have a significant effect on the total amount of polysulfides detected. In summary, the di- and trisulfide anions were found to predominate over the other polysulfide species in all examined experimental conditions. Additionally, the experimental values of Ea for the thermal degradation of polysulfide species correlate with the observed stability of the individual species; i.e., S22- has the highest Ea, followed by S32-.
25 citations