Sodium sulfide

About: Sodium sulfide is a research topic. Over the lifetime, 2851 publications have been published within this topic receiving 27733 citations. The topic is also known as: disodium sulfide.

Studies on the potential of coal fly ash as a heterogeneous catalyst in oxidation of aqueous sodium sulfide solutions with hydrogen peroxide

Abstract: The potential of fly ash procured form coal-fired thermal power plants was studied as a heterogeneous catalyst in the oxidation of aqueous sodium sulfide solutions with hydrogen peroxide in the temperature range of 303–323 K. The effects of various parameters (source of fly ash, fly ash loading, initial concentrations of sodium sulfide and hydrogen peroxide, electrolyte and deactivation of catalytic effect of fly ash) were studied. For an initial sodium sulfide and hydrogen peroxide concentration of 26·98×10−2 kmol m−3 and 24·28×10−2 kmol m−3 respectively, only 4% (w/v) fly ash loading intensified the rate of oxidation by a factor of 4·52 over that without fly ash at 303 K. The deactivation of the catalytic effect of fly ash was found to be less than 20% even after six repeated uses. The kinetics of aqueous phase decomposition of hydrogen peroxide was also studied in the presence of fly ash in alkaline medium. ©1997 SCI

Sodium sulfide leaching of low-grade jamesonite concentrate in production of sodium pyroantimoniate

Abstract: Sodium sulfide leaching of a low-grade jamesonite concentrate in the production of sodium pyroantimoniate through the air oxidation process and the influencing factors on the leaching rate of antimony were investigated In order to decrease the consumption of sodium sulfide and increase the concentration of antimony in the leaching solution, two-stage leaching of jamesonite concentrate and combination leaching of high-grade stibnite concentrate and jamesonite concentrate were used The experimental results show that the consumptions of sodium sulfide for the two-stage leaching process and the combination leaching process are decreased by 20% and 60% compared to those of one-stage leaching process respectively The final concentrations of antimony in the leaching solutions of both processes are above 100 g/L

A simple synthesis of SnS nanoflakes at ambient conditions

Abstract: The present work reports a simple route to prepare tin monosulfide semiconductor nanocrystals at ambient conditions. In the presence of complexant L-tartaric acid, SnCl2·2H2O was dissolved in ethylene glycol (EG) solution. After adjusting the solution pH value, sodium sulfide dissolved in EG was added into the solution. The solution changed from colorless into brown immediately and phase-pure SnS, which was confirmed by powder X-ray diffraction (XRD) was produced. The transmission electron microscopic (TEM) investigation shows very thin rectangular flake like SnS crystals of 10∼20 nm in size.

Formate--pyruvate exchange reaction in streptococcus faecalis. ii. reaction conditions for cell extracts.

Abstract: Oster, M. O. (A. & M. College of Texas, College Station), and N. P. Wood. Formate-pyruvate exchange reaction in Streptococcus faecalis. II. Reaction conditions for cell extracts. J. Bacteriol. 87:104-113. 1964.-In contrast to intact cells of Streptococcus faecalis, no stimulation of the formate-pyruvate exchange reaction was observed in cell extracts when yeast extract was added to the reaction mixture. A heated extract of Micrococcus lactilyticus, vitamin K(5), ferrous sulfate, and ferrous ammonium sulfate stimulated an active exchange by protecting the system from oxygen. Tetrahydrofolate, 2,3-dimercaptopropanol, and sodium sulfide provided partial protection, whereas ascorbate, glutathione, sodium hydrosulfite, ammonium sulfide, and sodium bisulfite gave insufficient protection or were inhibitory. Oxidation-reduction (O-R) indicators were not inhibitory and were used to estimate the O-R potentials of reaction mixtures. A potential at least as negative as -125 mv was estimated to be necessary to preserve or initiate formate-pyruvate exchange activity. The reaction operated over a narrow pH range when strict anaerobic conditions were not maintained but, when the system was suitably poised, the pH range was broader. The influence of high phosphate concentrations was less under strictly anaerobic conditions, and orthophosphate could be replaced by small amounts of pyrophosphate. Effect of temperature, time, and amount of extract is presented. Addition of reduced benzyl viologen and hydrogen-saturated palladium in the buffer during 8 hr of dialysis prevented inactivation of extracts. Recovery of activity could be obtained after ammonium sulfate treatment when a combination of palladium chloride, neutral red, and hydrogen bubbling were used.