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Showing papers on "Solar energy published in 2008"


Journal ArticleDOI
TL;DR: Polymer-based organic photovoltaic systems hold the promise for a cost-effective, lightweight solar energy conversion platform, which could benefit from simple solution processing of the active layer.
Abstract: Fossil fuel alternatives, such as solar energy, are moving to the forefront in a variety of research fields. Polymer-based organic photovoltaic systems hold the promise for a cost-effective, lightweight solar energy conversion platform, which could benefit from simple solution processing of the active layer. The function of such excitonic solar cells is based on photoinduced electron transfer from a donor to an acceptor. Fullerenes have become the ubiquitous acceptors because of their high electron affinity and ability to transport charge effectively. The most effective solar cells have been made from bicontinuous polymer–fullerene composites, or so-called bulk heterojunctions. The best solar cells currently achieve an efficiency of about 5 %, thus significant advances in the fundamental understanding of the complex interplay between the active layer morphology and electronic properties are required if this technology is to find viable application.

3,911 citations


Journal ArticleDOI
TL;DR: In this paper, the authors reported a new record total area efficiency of 19·9% for thin-film solar cells using three-stage co-evaporation with a modified surface termination.
Abstract: We report a new record total-area efficiency of 19·9% for CuInGaSe2-based thin-film solar cells. Improved performance is due to higher fill factor. The device was made by three-stage co-evaporation with a modified surface termination. Growth conditions, device analysis, and basic film characterization are presented. Published in 2008 by John Wiley & Sons, Ltd.

1,964 citations


Journal ArticleDOI
TL;DR: The scattering from metal nanoparticles near their localized plasmon resonance is a promising way of increasing the light absorption in thin-film solar cells and experimental and theoretical progress is reviewed.
Abstract: The scattering from metal nanoparticles near their localized plasmon resonance is a promising way of increasing the light absorption in thin-film solar cells. Enhancements in photocurrent have been observed for a wide range of semiconductors and solar cell configurations. We review experimental and theoretical progress that has been made in recent years, describe the basic mechanisms at work, and provide an outlook on future prospects in this area.

1,464 citations


PatentDOI
TL;DR: In this paper, the authors present a solar cell consisting of an anode, a p-type semiconductor layer formed on the anode and an active organic layer consisting of electron-donating organic material and an electron-accepting organic material.
Abstract: The present invention, in one aspect, relates to a solar cell In one embodiment, the solar cell includes an anode, a p-type semiconductor layer formed on the anode, and an active organic layer formed on the p-type semiconductor layer, where the active organic layer has an electron-donating organic material and an electron-accepting organic material

1,132 citations


Journal ArticleDOI
TL;DR: The "grand challenge" for chemists is to find a convenient means for artificial conversion of solar energy into fuels, if chemists succeed to create an artificial photosynthetic process, as the Italian scientist Giacomo Ciamician forecast almost one hundred years ago.
Abstract: Energy is the most important issue of the 21st century. About 85 % of our energy comes from fossil fuels, a finite resource unevenly distributed beneath the Earth’s surface. Reserves of fossil fuels are progressively decreasing, and their continued use produces harmful effects such as pollution that threatens human health and greenhouse gases associated with global warming. Prompt global action to solve the energy crisis is therefore needed. To pursue such an action, we are urged to save energy and to use energy in more efficient ways, but we are also forced to find alternative energy sources, the most convenient of which is solar energy for several reasons. The sun continuously provides the Earth with a huge amount of energy, fairly distributed all over the world. Its enormous potential as a clean, abundant, and economical energy source, however, cannot be exploited unless it is converted into useful forms of energy. This Review starts with a brief description of the mechanism at the basis of the natural photosynthesis and, then, reports the results obtained so far in the field of photochemical conversion of solar energy. The “grand challenge” for chemists is to find a convenient means for artificial conversion of solar energy into fuels. If chemists succeed to create an artificial photosynthetic process, “… life and civilization will continue as long as the sun shines!”, as the Italian scientist Giacomo Ciamician forecast almost one hundred years ago.

993 citations


Journal ArticleDOI
TL;DR: The potential efficiency of each step of the photosynthetic process from light capture to carbohydrate synthesis is examined, and it is revealed the maximum conversion efficiency of solar energy to biomass is 4.6% for C3 photosynthesis at 30 degrees C and today's 380 ppm atmospheric [CO2], but 6% forC4 photosynthesis.

948 citations


Journal ArticleDOI
TL;DR: This NC device produces one of the largest short-circuit currents of any nanostructured solar cell, without the need for sintering, superlattice order or separate phases for electron and hole transport.
Abstract: We describe here a simple, all-inorganic metal/NC/metal sandwich photovoltaic (PV) cell that produces an exceptionally large short-circuit photocurrent (>21 mA cm -2 ) by way of a Schottky junction at the negative electrode. The PV cell consists of a PbSe NC film, deposited via layer-by-layer (LbL) dip coating that yields an EQE of 55-65% in the visible and up to 25% in the infrared region of the solar spectrum, with a spectrally corrected AM1.5G power conversion efficiency of 2.1%. This NC device produces one of the largest short-circuit currents of any nanostructured solar cell, without the need for sintering, superlattice order or separate phases for electron and hole transport.

941 citations


Journal ArticleDOI
TL;DR: The U.S. Department of Energy and the National Renewable Energy Laboratory are developing technologies to produce hydrogen from renewable, sustainable sources as discussed by the authors, and a cost goal of $2.00-$3.00 kg−1 of hydrogen has been identified as the range at which delivered hydrogen becomes cost competitive with gasoline for passenger vehicles.
Abstract: The U.S. Department of Energy and the National Renewable Energy Laboratory are developing technologies to produce hydrogen from renewable, sustainable sources. A cost goal of $2.00–$3.00 kg−1 of hydrogen has been identified as the range at which delivered hydrogen becomes cost competitive with gasoline for passenger vehicles. Electrolysis of water is a standard commercial technology for producing hydrogen. Using wind and solar resources to produce the electricity for the process creates a renewable system. Biomass-to-hydrogen processes, including gasification, pyrolysis, and fermentation, are less well-developed technologies. These processes offer the possibility of producing hydrogen from energy crops and from biomass materials such as forest residue and municipal sewage. Solar energy can be used to produce hydrogen from water and biomass by several conversion pathways. Concentrated solar energy can generate high temperatures at which thermochemical reactions can be used to split water. Photoelectrochemical water splitting and photobiology are long-term options for producing hydrogen from water using solar energy. All these technologies are in the development stage. Copyright © 2007 John Wiley & Sons, Ltd.

853 citations


Journal ArticleDOI
Arif Hepbasli1
TL;DR: In this article, a comprehensive review of the exergetic analysis and performance evaluation of a wide range of renewable energy resources (RERs) for the first time to the best of the author's knowledge is presented.
Abstract: Energy resources and their utilization intimately relate to sustainable development. In attaining sustainable development, increasing the energy efficiencies of processes utilizing sustainable energy resources plays an important role. The utilization of renewable energy offers a wide range of exceptional benefits. There is also a link between exergy and sustainable development. A sustainable energy system may be regarded as a cost-efficient, reliable, and environmentally friendly energy system that effectively utilizes local resources and networks. Exergy analysis has been widely used in the design, simulation and performance evaluation of energy systems. The present study comprehensively reviews exergetic analysis and performance evaluation of a wide range of renewable energy resources (RERs) for the first time to the best of the author's knowledge. In this regard, general relations (i.e., energy, exergy, entropy and exergy balance equations along with exergy efficiency, exergetic improvement potential rate and some thermodynamic parameters, such as fuel depletion ratio, relative irreversibility, productivity lack and exergetic factor) used in the analysis are presented first. Next, exergetically analyzed and evaluated RERs include (a) solar energy systems; (a1) solar collector applications such as solar water heating systems, solar space heating and cooling, solar refrigeration, solar cookers, industrial process heat, solar desalination systems and solar thermal power plants), (a2) photovoltaics (PVs) and (a3) hybrid (PV/thermal) solar collectors, (b) wind energy systems, (c) geothermal energy systems, (c1) direct utilization (district heating, geothermal or ground-source heat pumps, greenhouses and drying) and (c2) indirect utilization (geothermal power plants), (d) biomass, (e) other renewable energy systems, and (f) country based RERs. Studies conducted on these RERs are then compared with the previously ones in tabulated forms, while the Grassmann (or exergy flow) diagrams, which are a very useful representation of exergy flows and losses, for some RERs are given. Finally, the conclusions are presented. It is expected that this comprehensive study will be very beneficial to everyone involved or interested in the exergetic design, simulation, analysis and performance assessment of RERs.

777 citations


Journal ArticleDOI
TL;DR: In this paper, the operating principles of photo-electrochemical devices for water splitting, their main bottlenecks, and various device concepts are reviewed, and the advantages and pitfalls of the use of interfacial layers and dopants are discussed.
Abstract: The direct conversion of solar energy into hydrogen represents an attractive but challenging alternative for photo-voltaic solar cells. Several metal oxide semiconductors are able to split water into hydrogen and oxygen upon illumination, but the efficiencies are still (too) low. The operating principles of photo-electrochemical devices for water splitting, their main bottlenecks, and the various device concepts will be reviewed. Materials properties play a key role, and the advantages and pitfalls of the use of interfacial layers and dopants will be discussed. Special attention will be given to recent progress made in the synthesis of nanostructured metal oxides with high aspect ratios, such as nanowire arrays, which offers new opportunities to develop efficient photo-active materials for solar water splitting.

645 citations


Journal ArticleDOI
TL;DR: Modules that use large-scale arrays of silicon solar microcells created from bulk wafers and integrated in diverse spatial layouts on foreign substrates by transfer printing are described, including high degrees of mechanical flexibility, user-definable transparency and ultrathin-form-factor microconcentrator designs.
Abstract: The high natural abundance of silicon, together with its excellent reliability and good efficiency in solar cells, suggest its continued use in production of solar energy, on massive scales, for the foreseeable future. Although organics, nanocrystals, nanowires and other new materials hold significant promise, many opportunities continue to exist for research into unconventional means of exploiting silicon in advanced photovoltaic systems. Here, we describe modules that use large-scale arrays of silicon solar microcells created from bulk wafers and integrated in diverse spatial layouts on foreign substrates by transfer printing. The resulting devices can offer useful features, including high degrees of mechanical flexibility, user-definable transparency and ultrathin-form-factor microconcentrator designs. Detailed studies of the processes for creating and manipulating such microcells, together with theoretical and experimental investigations of the electrical, mechanical and optical characteristics of several types of module that incorporate them, illuminate the key aspects.

Journal ArticleDOI
TL;DR: The goal of this paper is to provide an overview of the open problems related to PV power processing systems and to focus the attention of researchers and industries on present and future challenges in this field.
Abstract: Power processing systems will be a key factor of future photovoltaic (PV) applications. They will play a central role in transferring, to the load and/or to the grid, the electric power produced by the high-efficiency PV cells of the next generation. In order to come up the expectations related to the use of solar energy for producing electrical energy, such systems must ensure high efficiency, modularity, and, particularly, high reliability. The goal of this paper is to provide an overview of the open problems related to PV power processing systems and to focus the attention of researchers and industries on present and future challenges in this field.

Journal ArticleDOI
TL;DR: In this article, the high transparency metal wire grid electrodes for organic solar cell applications are presented, which are fabricated by nano-print lithography (NIL) and have several advan-
Abstract: Cost effective and highly efficient renewable energy is becoming ever more important in our age of rising energy prices and global climate change. Solar energy is a nonexhaustible and green energy. Organic solar cells (OSC) have the merits of low cost and simplistic fabrication in addition to compatibility with flexible plastic substrates over large areas. They have therefore been considered a promising energy conversion platform for clean and carbon-neutral energy production. In recent years, the power conversion efficiency of OSCs based on conjugated polymers has steadily increased through improved energy harvesting, enhanced exciton separation in improved device structures, and optimization of processing parameters, e.g., solvent evaporation time, and annealing conditions. Most OSCs are built on indium tin oxide (ITO) coated substrates because ITO offers transparency in the visible range of the electromagnetic spectrum as well as good electrical conductivity. However, ITO is not the optimum electrode for solar cell applications as it has been reported that the band structure of ITO hinders efficient photocurrent generation. Moreover, the poor mechanical stability of ITO can cause device failure when an ITO-coated flexible substrate is bent. In addition, the limited supply of indium and the increasing demand from the rapidly expanding display market have increased the cost of ITO drastically, which potentially prevents the realization of low cost and large scale OSC fabrication. Therefore, there is a strong need to find alternative materials that can replace ITO as high transparency electrode. Some examples that have been investigated recently are nanotube networks, and Ag wire grids. In this communication, we report on high transparency metal wire grid electrodes for organic solar cell applications. The high transparency metal electrodes are fabricated by nanoimprint lithography (NIL), and have several advan-

Journal ArticleDOI
TL;DR: In this paper, plasmon-active silver nanoparticle layers were included in solution-processed bulk-heterojunction solar cells to increase optical absorption and consequently increase photoconversion at solar-conversion relevant wavelengths.
Abstract: Plasmon-active silver nanoparticle layers were included in solution-processed bulk-heterojunction solar cells. Nanoparticle layers were fabricated using vapor-phase deposition on indium tin oxide electrodes. Owing to the increase in optical electrical field inside the photoactive layer, the inclusion of such particle films lead to increased optical absorption and consequently increased photoconversion at solar-conversion relevant wavelengths. The resulting solar energy conversion efficiency for a bulk heterojunction photovoltaic device of poly(3-hexylthiophene)/[6,6]-phenyl C61 butyric acid methyl ester was found to increase from 1.3%±0.2% to 2.2%±0.1% for devices employing thin plasmon-active layers. Based on six measurements, the improvement factor of 1.7 was demonstrated to be statistically significant.

Journal ArticleDOI
TL;DR: In this article, a state-of-the-art review is presented of the different technologies that are available to deliver refrigeration from solar energy, including solar electric, solar thermal and some new emerging technologies.
Abstract: A state-of-the-art review is presented of the different technologies that are available to deliver refrigeration from solar energy. The review covers solar electric, solar thermal and some new emerging technologies. The solar thermal systems include thermo-mechanical, absorption, adsorption and desiccant solutions. A comparison is made between the different solutions both from the point of view of energy efficiency and economic feasibility. Solar electric and thermo-mechanical systems appear to be more expensive than thermal sorption systems. Absorption and adsorption are comparable in terms of performance but adsorption chillers are more expensive and bulkier than absorption chillers. The total cost of a single-effect LiBr–water absorption system is estimated to be the lowest.

Journal ArticleDOI
TL;DR: This paper proposes a low-power maximum power point tracker (MPPT) circuit specifically designed for wireless sensor nodes, i.e., a power transferring circuit for optimally conveying solar energy into rechargeable batteries even in not optimal weather conditions.
Abstract: The success of wireless sensor networks and their pervasive use is somehow constrained by energy supply which, generally provided by batteries, is a finite resource. Energy harvesting mechanisms must hence be taken into account to grant a long time operational life, with solar energy being the most interesting one in outdoor deployments due to its relatively high power density. In this paper we propose a low-power maximum power point tracker (MPPT) circuit specifically designed for wireless sensor nodes (hence effective, flexible, low cost and power-aware), i.e., a power transferring circuit for optimally conveying solar energy into rechargeable batteries even in not optimal weather conditions. High efficiency is granted by an ad hoc adaptive algorithm which, by keeping the MPPT electronics in its optimal working point, maximizes energy transfer from the solar cell to the batteries. The suggested implementation is particularly effective in critical weather conditions where traditional solutions do not work and is characterized by a flexible enough design for immediately hosting, in a plug in fashion, different solar panels and battery typologies.

Journal ArticleDOI
TL;DR: The use of solar energy in thermal desalination processes is one of the most promising applications of the renewable energies as discussed by the authors, however, it requires large land areas and has a relatively low productivity.

Journal ArticleDOI
TL;DR: An adaptive reconfiguration scheme to reduce the effect of shadows on solar panels using a switching matrix according to a model-based control algorithm that increases the power output of the solar PV array.
Abstract: This paper proposes an adaptive reconfiguration scheme to reduce the effect of shadows on solar panels. A switching matrix connects a solar adaptive bank to a fixed part of a solar photovoltaic (PV) array, according to a model-based control algorithm that increases the power output of the solar PV array. Control algorithms are implemented in real time. An experimental reconfiguration PV system with a resistive load is presented and is shown to verify the proposed reconfigurations.

Journal ArticleDOI
TL;DR: In this article, to augment evaporation of the still basin water, fins were integrated at the basin of the solar still to accelerate the production rate, and for further increase in exposure area sponges were used.

Journal ArticleDOI
TL;DR: A methodology for optimizing a solar harvester with maximum power point tracking for self-powered wireless sensor network (WSN) nodes and helps in boosting efficiency, allowing to reach a maximum efficiency of 85% with discrete components.
Abstract: In this paper, we propose a methodology for optimizing a solar harvester with maximum power point tracking for self-powered wireless sensor network (WSN) nodes. We focus on maximizing the harvester's efficiency in transferring energy from the solar panel to the energy storing device. A photovoltaic panel analytical model, based on a simplified parameter extraction procedure, is adopted. This model predicts the instantaneous power collected by the panel helping the harvester design and optimization procedure. Moreover, a detailed modeling of the harvester is proposed to understand basic harvester behavior and optimize the circuit. Experimental results based on the presented design guidelines demonstrate the effectiveness of the adopted methodology. This design procedure helps in boosting efficiency, allowing to reach a maximum efficiency of 85% with discrete components. The application field of this circuit is not limited to self-powered WSN nodes; it can easily be extended in embedded portable applications to extend the battery life.

Journal ArticleDOI
TL;DR: In this paper, an electronic glue-based lamination process combined with interface modification is presented as a one-step process for semitransparent polymer solar-cell fabrication, which represents a critical step towards the ultimate goal of low-cost polymer solar cells.
Abstract: Polymer solar cells have attracted broad research interest because of their advantageous solution processing capability and formation of low-cost, flexible, and large area electronic devices. However, the efficiency of polymer solar cells is still low compared to that of inorganic solar cells. Therefore, it is a challenge to find a polymer that has all the required properties for high efficiency devices, such as strong and broad absorption, high carrier mobility, and appropriate energy levels. One possible solution to avoid the strict material requirements is to stack two or more devices with different spectral responses, which enables more efficient utilization of solar energy. Such a solution would require a semitransparent solarcell device with high efficiency in its absorption wavelength range, while high transparency would be required in the complementary wavelength range. Semitransparent solar cells are also interesting for other appealing applications, such as energy-generating color window glasses. It is desirable that such solar cell devices can be fabricated using a low-cost strategy, such as the roll-to-roll fabrication process. One critical issue in this fabrication process is how to form the active-layer/cathode mechanic and electronic contacts. The lamination process is one very promising technique to fulfill this requirement owing to its simplicity and low cost. It has been reported to produce two-layer heterojunction solar cells; however, the method is not applicable to bulk heterojunction solar cells, nor compatible with roll-to-roll fabrication process. In this Communication, an electronic glue-based lamination process combined with interface modification is presented as a one-step process for semitransparent polymer solar-cell fabrication. The finished device is metalfree, semitransparent, flexible, self-encapsulated, and highly efficient (with a maximum external quantum efficiency of 70 % and power efficiency of 3 % under AM 1.5 global 1 sun solar illumination conditions with spectral mismatch correction). This approach represents a critical step towards the ultimate goal of low-cost polymer solar cells. The device fabrication process is illustrated in Figure 1, and can be described by the following steps. In Step I, two transparent substrates coated with a transparent conductor such as indium tin oxide (ITO), fluorine-doped tin oxide (FTO), or a high conductivity polymer, etc., are selected. In Step II, one substrate is coated with a very thin buffer layer (Cs2CO3 ) to act as the low-work-function cathode, followed by coating of the active polymer layer. Step III involves the coating of conductive polymer glue to the other transparent substrate. We used modified conducting polymer poly(ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as the electronic glue, which was spin-coated to form the adhesive anode. Step IV is the lamination process: after drying both the substrates, they are laminated together by exerting force so that the two substrates are tightly glued together. During this lamination, a plastic rod with proper hardness rolls the plastic substrate to remove air bubbles. Both substrates are heated to a temperature of 105–120 °C during the lamination process, and the finished devices are then kept on the hotplate for 5–10 min for the final heat treatment. The PEDOT:PSS was purposely modified to become adhesive, so that the two separate films formed good contact at the interface, both electronically and mechanically. In this work, this adhesive and conductive PEDOT:PSS layer was obtained by doping D-sorbitol or volemitol into PEDOT:PSS, as has been successfully demonstrated in polymer light emitting diodes. However, the efficiency of such a device is too low for application. The polymer blend used in this work is regioregular poly(3-hexylthiophene):[6,6]-phenyl-C61-butyric acid methyl ester (RRP3HT:PCBM) in 1:1 w/w ratio. The 200 nm thick polymer blend film was deposited by the slow-growth method (or solvent annealing) to enhance device efficiency. Either glass or plastic can be used as the transparent substrate. Figure 1b shows a picture of an all-plastic solar cell. The device area is ca. 40 mm. With both cathode and anode being transparent, a semitransparent polymer solar cell is formed. The transparency (T%) of the device is shown in Figure 1c, together with the solar illumination spectrum. A transparency of around 70 % was obtained in the wavelength range where polymer/PCBM has no absorption, which makes this device suitable for application in stacking devices to make full use of the solar spectrum. This device fabrication method has many advantages over the regular procedure. First of all, no thermal evaporation process is involved in the process, and each layer is coated by a low-cost and easy solution process. Second, in contrast to the reactive metal cathode in regular devices, the cathode in C O M M U N IC A IO N

Journal ArticleDOI
TL;DR: The photovoltaics (PV) area is rapidly evolving based on new materials and deposition approaches as discussed by the authors, which is a leading contender for next-generation green power production.
Abstract: The direct conversion of solar energy to electricity by photovoltaic cells or thermal energy in concentrated solar power systems is emerging as a leading contender for next-generation green power production. The photovoltaics (PV) area is rapidly evolving based on new materials and deposition approaches. At present, PV is predominately based on crystalline and polycrystalline Si and is growing at >40% per year with production rapidly approaching 3 gigawatts/year with PV installations supplying <1% of energy used in the world. Increased cell efficiency and reduced manufacturing expenses are critical in achieving reasonable costs for PV and solarthermal. CdTe thin-film solar cells have reported a manufactured cost of $1.25/watt. There is also the promise of increased efficiency by use of multijunction cells or hybrid devices organized at the nanoscale. This could lead to conversion efficiencies of greater than 50%. Solar energy conversion increasingly represents one of the largest new businesses currently emerging in any sector of the economy.

Journal ArticleDOI
01 Feb 2008-Energy
TL;DR: In this article, the authors presented the results of a life cycle assessment (LCA) of the electric generation by means of photovoltaic panels, considering mass and energy flows over the whole production process starting from silica extraction to the final panel assembling, considering the most advanced and consolidate technologies for polycrystalline silicon panel production.

Journal ArticleDOI
TL;DR: In this article, several mature photovoltaic technologies, ranging from silicon to thin films, and solar concentrator systems are analyzed, and the estimates of the energy production limits are established for each technology, based on available global material reserves.

Journal ArticleDOI
TL;DR: In this article, the authors outline the loss mechanisms that limit conversion efficiency of a luminescent solar concentrator and highlight the role that advanced materials can play in reducing these losses, including nonunity fluorescence quantum yield (FQY), reabsorption losses, incomplete utilization of the solar spectrum and escape cone losses.
Abstract: Sunlight that is incident on the front surface of a luminescent solar concentrator (LSC) is absorbed and subsequently re-emitted by luminescent materials. The resulting luminescence is transported to the edge of the LSC sheet and concentrated onto photovoltaic devices. Despite its potential for generating low-cost solar power, LSC development faces numerous challenges, the majority of which are related to the luminescent materials used in their design. Earlier LSC research focused on organic dyes, and while several of the shortcomings with these materials have been solved over time, some major challenges remain. This paper outlines the loss mechanisms that limit conversion efficiency of the LSC and highlights the role that advanced materials can play. Losses include nonunity fluorescence quantum yield (FQY), reabsorption losses, incomplete utilization of the solar spectrum, and escape cone losses. Long-term photostability is also discussed as it is essential for commercial feasibility of any solar technology. Past and current techniques, designed to reduce these losses, are described and their experimental achievements are discussed.

Journal ArticleDOI
TL;DR: This Minireview highlights the current state of the art and future directions of solid-state dye-sensitized solar cell technology.
Abstract: The dye-sensitized solar cell, developed in the 1990s, is a non-conventional solar technology that has attracted much attention owing to its stability, low cost, and device efficiency. Power-conversion efficiencies of over 11% have been achieved for devices that contain liquid electrolytes, whereas solid-state devices that do not require a liquid electrolyte display an overall efficiency of 5%. Improvement of the efficiency of solid-state dye-sensitized solar cells requires optimization of their various components, such as the hole-transport material, sensitizer, mesoporous TiO2 film, and the blocking layer. This Minireview highlights the current state of the art and future directions of solid-state dye-sensitized solar cell technology.

Journal ArticleDOI
TL;DR: In this paper, a dye-sensitized bifacial solar cell was proposed to provide high photo-energy conversion efficiency (∼6%) for incident light striking its front or rear surfaces.
Abstract: Solar energy is a promising solution to global energy-related problems because it is clean, inexhaustible and readily available. However, the deployment of conventional photovoltaic cells based on silicon is still limited by cost, so alternative, more cost-effective approaches are sought. Here we report a bifacial dye-sensitized solar cell structure that provides high photo-energy conversion efficiency (∼6%) for incident light striking its front or rear surfaces. The design comprises a highly stable ruthenium dye (Z907Na) in combination with an ionic-liquid electrolyte and a porous TiO2 layer. The inclusion of a SiO2 layer between the electrodes to prevent generation of unwanted back current and optimization of the thickness of the TiO2 layer are responsible for the enhanced performance. Low-cost, efficient solar cells are sought as an alternative to silicon photovoltaics. Here a dye-based bifacial solar cell that is capable of efficient generation of electricity for light incident on either its front or rear face is demonstrated.

Journal ArticleDOI
02 May 2008-ACS Nano
TL;DR: Simulations show that, with currently available materials, nanocrystalline network solar cells optimize both exciton diffusion and carrier collection, thus providing for highly efficient solar energy conversion.
Abstract: Photocurrent generation in nanostructured organic solar cells is simulated using a dynamical Monte Carlo model that includes the generation and transport properties of both excitons and free charges. Incorporating both optical and electrical properties, we study the influence of the heterojunction nanostructure (e.g., planar vs bulk junctions) on donor-acceptor organic solar cell efficiencies based on the archetype materials copper phthalocyanine (CuPc) and C(60). Structures considered are planar and planar-mixed heterojunctions, homogeneous and phase-separated donor-acceptor (DA) mixtures, idealized structures composed of DA pillars, and nanocrystalline DA networks. The thickness dependence of absorption, exciton diffusion, and carrier collection efficiencies is studied for different morphologies, yielding results similar to those experimentally observed. The influences of charge mobility and exciton diffusion length are studied, and optimal device thicknesses are proposed for various structures. Simulations show that, with currently available materials, nanocrystalline network solar cells optimize both exciton diffusion and carrier collection, thus providing for highly efficient solar energy conversion. Estimations of achievable energy conversion efficiencies are made for the various nanostructures based on current simulations used in conjunction with experimentally obtained fill factors and open-circuit voltages for conventional small molecular weight materials combinations.

Book
01 Jan 2008
TL;DR: This Review focuses on recent achievements in the area of flexible solar cells, highlights the principles behind the main technologies, and discusses future challenges in this area.
Abstract: Thin-film flexible photovoltaics are paving the way to low-cost electricity. Organic, inorganic and organic-inorganic solar cells are deposited over flexible substrates by high-throughput (often roll-to-roll printing) technologies to afford lightweight, economic solar modules that can be integrated into, not installed on, various surfaces. Current conversion efficiencies under standard conditions are in the 3-15 % range, but in real applications the overall productivity is high. These new photovoltaic technologies are ready to provide cheap, clean electricity to the 2 billion people who lack access to the grid as well as to energy-eager companies and families in the developed world facing the increasing costs of electricity generated using fossil fuel resources. This Review focuses on recent achievements in the area of flexible solar cells, highlights the principles behind the main technologies, and discusses future challenges in this area.

Proceedings ArticleDOI
20 Jul 2008
TL;DR: In this article, a comparative study of ten widely-adopted maximum power point tracking (MPPT) algorithms is presented, and their performance is evaluated using the simulation tool Simulinkreg.
Abstract: In the future solar energy will be very important energy source. More than 45% of necessary energy in the world will be generated by photovoltaic array. Therefore it is necessary to concentrate our forces in order to reduce the application costs and to increment their performances. In order to reach this last aspect, it is important to note that the output characteristic of a photovoltaic array is nonlinear and changes with solar irradiation and the cellpsilas temperature. Therefore a maximum power point tracking (MPPT) technique is needed to draw peak power from the solar array in order to maximize the produced energy. This paper presents a comparative study of ten widely-adopted MPPT algorithms; their performance is evaluated using the simulation tool Simulinkreg. In particular, this study compares the behaviors of each technique in presence of solar irradiation variations.