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Showing papers on "Solar energy published in 2016"


Journal ArticleDOI
22 Jan 2016-Science
TL;DR: Lewis reviews the status of solar thermal and solar fuels approaches for harnessing solar energy, as well as technology gaps for achieving cost-effective scalable deployment combined with storage technologies to provide reliable, dispatchable energy.
Abstract: Major developments, as well as remaining challenges and the associated research opportunities, are evaluated for three technologically distinct approaches to solar energy utilization: solar electricity, solar thermal, and solar fuels technologies. Much progress has been made, but research opportunities are still present for all approaches. Both evolutionary and revolutionary technology development, involving foundational research, applied research, learning by doing, demonstration projects, and deployment at scale will be needed to continue this technology-innovation ecosystem. Most of the approaches still offer the potential to provide much higher efficiencies, much lower costs, improved scalability, and new functionality, relative to the embodiments of solar energy-conversion systems that have been developed to date.

1,416 citations


Journal ArticleDOI
TL;DR: In this paper, the photocatalyst sheet design enables efficient and scalable water splitting using particulate semiconductors, which is a potentially scalable and economically feasible technology for converting solar energy into hydrogen.
Abstract: Photocatalytic water splitting using semiconductors is attractive for converting solar energy into hydrogen. An efficient and scalable system based on particulate photocatalyst sheets is now shown to exhibit energy conversion efficiency exceeding 1%. Photocatalytic water splitting using particulate semiconductors is a potentially scalable and economically feasible technology for converting solar energy into hydrogen1,2,3. Z-scheme systems based on two-step photoexcitation of a hydrogen evolution photocatalyst (HEP) and an oxygen evolution photocatalyst (OEP) are suited to harvesting of sunlight because semiconductors with either water reduction or oxidation activity can be applied to the water splitting reaction4,5. However, it is challenging to achieve efficient transfer of electrons between HEP and OEP particles6,7. Here, we present photocatalyst sheets based on La- and Rh-codoped SrTiO3 (SrTiO3:La, Rh; ref. 8) and Mo-doped BiVO4 (BiVO4:Mo) powders embedded into a gold (Au) layer. Enhancement of the electron relay by annealing and suppression of undesirable reactions through surface modification allow pure water (pH 6.8) splitting with a solar-to-hydrogen energy conversion efficiency of 1.1% and an apparent quantum yield of over 30% at 419 nm. The photocatalyst sheet design enables efficient and scalable water splitting using particulate semiconductors.

1,190 citations


Journal ArticleDOI
TL;DR: A self-assembling plasmonic absorber which can enable an average measured absorbance of ~99% across the wavelengths from 400 nm to 10 μm is reported, the most efficient and broadband plas Monte Carlo absorber reported to date.
Abstract: The study of ideal absorbers, which can efficiently absorb light over a broad range of wavelengths, is of fundamental importance, as well as critical for many applications from solar steam generation and thermophotovoltaics to light/thermal detectors. As a result of recent advances in plasmonics, plasmonic absorbers have attracted a lot of attention. However, the performance and scalability of these absorbers, predominantly fabricated by the top-down approach, need to be further improved to enable widespread applications. We report a plasmonic absorber which can enable an average measured absorbance of ~99% across the wavelengths from 400 nm to 10 μm, the most efficient and broadband plasmonic absorber reported to date. The absorber is fabricated through self-assembly of metallic nanoparticles onto a nanoporous template by a one-step deposition process. Because of its efficient light absorption, strong field enhancement, and porous structures, which together enable not only efficient solar absorption but also significant local heating and continuous stream flow, plasmonic absorber–based solar steam generation has over 90% efficiency under solar irradiation of only 4-sun intensity (4 kW m−2). The pronounced light absorption effect coupled with the high-throughput self-assembly process could lead toward large-scale manufacturing of other nanophotonic structures and devices.

946 citations


Journal ArticleDOI
TL;DR: In this paper, a review gives an overview of fundamental aspects and recent research advances of heterogeneous photocatalytic CO2 conversion systems in the last 3 years, and the catalysts are categorized as one-step excitation semiconductor systems, one-stage excitation photosensitized semiconductor system, and two-step hybrid systems such as semiconductor heterojunction and Z-scheme systems.
Abstract: As a promising approach to achieving two objectives with one strategy, photocatalytic CO2 conversion for C1/C2 “solar fuels” production can provide a package solution to the current global warming and growing energy demand by using inexhaustible solar energy and increasing atmospheric CO2. Although numerous efforts have been made to enhance the CO2 conversion efficiency through developing photocatalysts and CO2 reduction systems in recent years, some challenges still remain in improving the activity and selectivity of the CO2 photoreduction reactions. This review gives an overview of fundamental aspects and recent research advances of heterogeneous photocatalytic CO2 conversion systems in the last 3 years, and the catalysts are categorized as one-step excitation semiconductor systems, one-step excitation photosensitized semiconductor systems, and two-step excitation hybrid systems such as semiconductor heterojunction and Z-scheme systems. Also, some suggestions are given for further confirming that the ca...

927 citations


Journal ArticleDOI
TL;DR: The results showed that a 17.8 % increase in the harvest and utilization of solar thermal energy could be achieved using a silicon nanowire array on silicon substrate as compared to that obtained with a plain silicon wafer.
Abstract: Silicon nanowire possesses great potential as the material for renewable energy harvesting and conversion. The significantly reduced spectral reflectivity of silicon nanowire to visible light makes it even more attractive in solar energy applications. However, the benefit of its use for solar thermal energy harvesting remains to be investigated and has so far not been clearly reported. The purpose of this study is to provide practical information and insight into the performance of silicon nanowires in solar thermal energy conversion systems. Spectral hemispherical reflectivity and transmissivity of the black silicon nanowire array on silicon wafer substrate were measured. It was observed that the reflectivity is lower in the visible range but higher in the infrared range compared to the plain silicon wafer. A drying experiment and a theoretical calculation were carried out to directly evaluate the effects of the trade-off between scattering properties at different wavelengths. It is clearly seen that silicon nanowires can improve the solar thermal energy harnessing. The results showed that a 17.8 % increase in the harvest and utilization of solar thermal energy could be achieved using a silicon nanowire array on silicon substrate as compared to that obtained with a plain silicon wafer.

895 citations


Journal ArticleDOI
TL;DR: The need of solar industry with its fundamental concepts, worlds energy scenario, highlights of researches done to upgrade solar industry, its potential applications and barriers for better solar industry in future in order to resolve energy crisis as mentioned in this paper.
Abstract: World׳s energy demand is growing fast because of population explosion and technological advancements. It is therefore important to go for reliable, cost effective and everlasting renewable energy source for energy demand arising in future. Solar energy, among other renewable sources of energy, is a promising and freely available energy source for managing long term issues in energy crisis. Solar industry is developing steadily all over the world because of the high demand for energy while major energy source, fossil fuel, is limited and other sources are expensive. It has become a tool to develop economic status of developing countries and to sustain the lives of many underprivileged people as it is now cost effective after a long aggressive researches done to expedite its development. The solar industry would definitely be a best option for future energy demand since it is superior in terms of availability, cost effectiveness, accessibility, capacity and efficiency compared to other renewable energy sources. This paper therefore discusses about the need of solar industry with its fundamental concepts, worlds energy scenario, highlights of researches done to upgrade solar industry, its potential applications and barriers for better solar industry in future in order to resolve energy crisis.

894 citations


Journal ArticleDOI
Xiuqiang Li1, Weichao Xu1, Mingyao Tang1, Lin Zhou1, Bin Zhu1, Shining Zhu1, Jia Zhu1 
TL;DR: The energy transfer efficiency of this foldable graphene oxide film-based device fabricated by a scalable process is independent of water quantity and can be achieved without optical or thermal supporting systems, therefore significantly improving the scalability and feasibility of this technology toward a complementary portable and personalized water solution.
Abstract: Because it is able to produce desalinated water directly using solar energy with minimum carbon footprint, solar steam generation and desalination is considered one of the most important technologies to address the increasingly pressing global water scarcity. Despite tremendous progress in the past few years, efficient solar steam generation and desalination can only be achieved for rather limited water quantity with the assistance of concentrators and thermal insulation, not feasible for large-scale applications. The fundamental paradox is that the conventional design of direct absorber−bulk water contact ensures efficient energy transfer and water supply but also has intrinsic thermal loss through bulk water. Here, enabled by a confined 2D water path, we report an efficient (80% under one-sun illumination) and effective (four orders salinity decrement) solar desalination device. More strikingly, because of minimized heat loss, high efficiency of solar desalination is independent of the water quantity and can be maintained without thermal insulation of the container. A foldable graphene oxide film, fabricated by a scalable process, serves as efficient solar absorbers (>94%), vapor channels, and thermal insulators. With unique structure designs fabricated by scalable processes and high and stable efficiency achieved under normal solar illumination independent of water quantity without any supporting systems, our device represents a concrete step for solar desalination to emerge as a complementary portable and personalized clean water solution.

888 citations


Journal ArticleDOI
TL;DR: In this article, a low-cost solar receiver based on thermal concentration that generates steam at 100 ǫ∘C without the need for optical concentration is presented, which can be used to evaporate water and generate steam without expensive optical concentrators.
Abstract: Solar energy can be used to evaporate water and generate steam, however this usually requires expensive optical concentrators. Ni et al. demonstrate a low-cost solar receiver based on thermal concentration that generates steam at 100 ∘C without the need for optical concentration.

809 citations


Journal ArticleDOI
TL;DR: A hybridized self-powered textile for simultaneously collecting solar energy and random body motion energy was demonstrated and can be easily woven into electronic textiles to fabricate smart clothes to sustainably operate mobile or wearable electronics.
Abstract: Wearable electronics fabricated on lightweight and flexible substrate are believed to have great potential for portable devices, but their applications are limited by the life span of their batteries We propose a hybridized self-charging power textile system with the aim of simultaneously collecting outdoor sunshine and random body motion energies and then storing them in an energy storage unit Both of the harvested energies can be easily converted into electricity by using fiber-shaped dye-sensitized solar cells (for solar energy) and fiber-shaped triboelectric nanogenerators (for random body motion energy) and then further stored as chemical energy in fiber-shaped supercapacitors Because of the all–fiber-shaped structure of the entire system, our proposed hybridized self-charging textile system can be easily woven into electronic textiles to fabricate smart clothes to sustainably operate mobile or wearable electronics

678 citations


Journal ArticleDOI
TL;DR: In this paper, the authors discuss various forms of perovskite materials produced via various deposition procedures and discuss current challenges and possible solutions, with the aim of stimulating potential new applications.
Abstract: Exploring prospective materials for energy production and storage is one of the biggest challenges of this century. Solar energy is one of the most important renewable energy resources, due to its wide availability and low environmental impact. Metal halide perovskites have emerged as a class of semiconductor materials with unique properties, including tunable bandgap, high absorption coefficient, broad absorption spectrum, high charge carrier mobility and long charge diffusion lengths, which enable a broad range of photovoltaic and optoelectronic applications. Since the first embodiment of perovskite solar cells showing a power conversion efficiency of 3.8%, the device performance has been boosted up to a certified 22.1% within a few years. In this Perspective, we discuss differing forms of perovskite materials produced via various deposition procedures. We focus on their energy-related applications and discuss current challenges and possible solutions, with the aim of stimulating potential new applications.

676 citations



Journal ArticleDOI
TL;DR: In this paper, the structural order of the electron transport layers of perovskite solar cells has been shown to have a significant impact on solar cell performance, and the power conversion efficiency of CH3NH3PbII3 planar heterojunction photovoltaic cells increases from 17.1% to 19.4%.
Abstract: Organometal trihalide perovskites have been demonstrated as excellent light absorbers for high-efficiency photovoltaic applications. Previous approaches to increasing the solar cell efficiency have focused on optimization of the grain morphology of perovskite thin films. Here, we show that the structural order of the electron transport layers also has a significant impact on solar cell performance. We demonstrate that the power conversion efficiency of CH3NH3PbI3 planar heterojunction photovoltaic cells increases from 17.1 to 19.4% when the energy disorder in the fullerene electron transport layer is reduced by a simple solvent annealing process. The increase in efficiency is the result of the enhancement in open-circuit voltage from 1.04 to 1.13 V without sacrificing the short-circuit current and fill factor. These results shed light on the origin of open-circuit voltage in perovskite solar cells, and provide a path to further increase their efficiency. Ongoing efforts are devoted to raising the efficiency of solar cells in converting energy from solar radiation. Now, improved structural order in the charge transport layers of perovskite solar cells is shown to increase the efficiency from 17.1% to 19.4%.

Journal ArticleDOI
TL;DR: In this paper, a comparison between photoelectrochemical (PEC) and photovoltaic-electrolytic (PV-E) solar-hydrogen production of 3.65 kilotons H2 per year was performed to assess the economics of each technology, and to provide a basis for comparison within the broader energy landscape.
Abstract: A technoeconomic analysis of photoelectrochemical (PEC) and photovoltaic-electrolytic (PV-E) solar-hydrogen production of 10000 kg H2 day−1 (3.65 kilotons per year) was performed to assess the economics of each technology, and to provide a basis for comparison between these technologies as well as within the broader energy landscape. Two PEC systems, differentiated primarily by the extent of solar concentration (unconcentrated and 10× concentrated) and two PV-E systems, differentiated by the degree of grid connectivity (unconnected and grid supplemented), were analyzed. In each case, a base-case system that used established designs and materials was compared to prospective systems that might be envisioned and developed in the future with the goal of achieving substantially lower overall system costs. With identical overall plant efficiencies of 9.8%, the unconcentrated PEC and non-grid connected PV-E system base-case capital expenses for the rated capacity of 3.65 kilotons H2 per year were $205 MM ($293 per m2 of solar collection area (mS−2), $14.7 WH2,P−1) and $260 MM ($371 mS−2, $18.8 WH2,P−1), respectively. The untaxed, plant-gate levelized costs for the hydrogen product (LCH) were $11.4 kg−1 and $12.1 kg−1 for the base-case PEC and PV-E systems, respectively. The 10× concentrated PEC base-case system capital cost was $160 MM ($428 mS−2, $11.5 WH2,P−1) and for an efficiency of 20% the LCH was $9.2 kg−1. Likewise, the grid supplemented base-case PV-E system capital cost was $66 MM ($441 mS−2, $11.5 WH2,P−1), and with solar-to-hydrogen and grid electrolysis system efficiencies of 9.8% and 61%, respectively, the LCH was $6.1 kg−1. As a benchmark, a proton-exchange membrane (PEM) based grid-connected electrolysis system was analyzed. Assuming a system efficiency of 61% and a grid electricity cost of $0.07 kWh−1, the LCH was $5.5 kg−1. A sensitivity analysis indicated that, relative to the base-case, increases in the system efficiency could effect the greatest cost reductions for all systems, due to the areal dependencies of many of the components. The balance-of-systems (BoS) costs were the largest factor in differentiating the PEC and PV-E systems. No single or combination of technical advancements based on currently demonstrated technology can provide sufficient cost reductions to allow solar hydrogen to directly compete on a levelized cost basis with hydrogen produced from fossil energy. Specifically, a cost of CO2 greater than ∼$800 (ton CO2)−1 was estimated to be necessary for base-case PEC hydrogen to reach price parity with hydrogen derived from steam reforming of methane priced at $12 GJ−1 ($1.39 (kg H2)−1). A comparison with low CO2 and CO2-neutral energy sources indicated that base-case PEC hydrogen is not currently cost-competitive with electrolysis using electricity supplied by nuclear power or from fossil-fuels in conjunction with carbon capture and storage. Solar electricity production and storage using either batteries or PEC hydrogen technologies are currently an order of magnitude greater in cost than electricity prices with no clear advantage to either battery or hydrogen storage as of yet. Significant advances in PEC technology performance and system cost reductions are necessary to enable cost-effective PEC-derived solar hydrogen for use in scalable grid-storage applications as well as for use as a chemical feedstock precursor to CO2-neutral high energy-density transportation fuels. Hence such applications are an opportunity for foundational research to contribute to the development of disruptive approaches to solar fuels generation systems that can offer higher performance at much lower cost than is provided by current embodiments of solar fuels generators. Efforts to directly reduce CO2 photoelectrochemically or electrochemically could potentially produce products with higher value than hydrogen, but many, as yet unmet, challenges include catalytic efficiency and selectivity, and CO2 mass transport rates and feedstock cost. Major breakthroughs are required to obtain viable economic costs for solar hydrogen production, but the barriers to achieve cost-competitiveness with existing large-scale thermochemical processes for CO2 reduction are even greater.

Journal ArticleDOI
TL;DR: In this paper, the authors present a comprehensive review of various aspects of hybrid renewable energy system (HRES) including prefeasibility analysis, optimum sizing, modeling, control aspects and reliability issues.
Abstract: The demand for electricity is increasing day by day, which cannot be fulfilled by non-renewable energy sources alone. Renewable energy sources such as solar and wind are omnipresent and environmental friendly. The renewable emulnergy sources are emerging options to fulfill the energy demand, but unreliable due to the stochastic nature of their occurrence. Hybrid renewable energy system (HRES) combines two or more renewable energy sources like wind turbine and solar system. The objective of this paper is to present a comprehensive review of various aspects of HRES. This paper discusses prefeasibility analysis, optimum sizing, modeling, control aspects and reliability issues. The application of evolutionary technique and game theory in hybrid renewable energy is also presented in this paper.

Journal ArticleDOI
TL;DR: A photovoltaic-electrolysis system with the highest STH efficiency for any water splitting technology to date, to the best of the knowledge, is reported.
Abstract: Hydrogen production via electrochemical water splitting is a promising approach for storing solar energy For this technology to be economically competitive, it is critical to develop water splitting systems with high solar-to-hydrogen (STH) efficiencies Here we report a photovoltaic-electrolysis system with the highest STH efficiency for any water splitting technology to date, to the best of our knowledge Our system consists of two polymer electrolyte membrane electrolysers in series with one InGaP/GaAs/GaInNAsSb triple-junction solar cell, which produces a large-enough voltage to drive both electrolysers with no additional energy input The solar concentration is adjusted such that the maximum power point of the photovoltaic is well matched to the operating capacity of the electrolysers to optimize the system efficiency The system achieves a 48-h average STH efficiency of 30% These results demonstrate the potential of photovoltaic-electrolysis systems for cost-effective solar energy storage

Journal ArticleDOI
TL;DR: In this paper, the existing research works on PV cell model parameter estimation problem are classified into three categories and the research works of those categories are reviewed based on the conducted review, some recommendations for future research are provided.
Abstract: The contribution of solar photovoltaics (PV׳s) in generation of electric power is continually increasing. PV cells are commonly modelled as circuits. Finding appropriate circuit model parameters of PV cells is crucial for performance evaluation, control, efficiency computations and maximum power point tracking of solar PV systems. The problem of finding circuit model parameters of solar PV cells is referred to as “PV cell model parameter estimation problem,” and is highly attracted by researchers. In this paper, the existing research works on PV cell model parameter estimation problem are classified into three categories and the research works of those categories are reviewed. Based on the conducted review, some recommendations for future research are provided.

Journal ArticleDOI
Sarat Kumar Sahoo1
TL;DR: In this article, the progress of current solar photovoltaic energy in India is discussed and the Indian government policies and initiatives to promote solar energy in the country are discussed. And the authors highlight the renewable energy trend in India with major achievements, state wise analysis of solar parks and industrial applications.
Abstract: The mitigation of global energy demands and climate change are the most important factors in the modern days. Development and application of solar energy have been regarded by the government of India and common people, and they thought that solar photo voltaic energy can provide more energy in future compare to other renewable energies. In the last decade, solar photovoltaic energy research and development has supported by the central government and state governments. This paper discusses the progress of current solar photovoltaic energy in India. It highlights the renewable energy trend in India with major achievements, state wise analysis of solar parks and industrial applications. Finally, it discusses the Indian government policies and initiatives to promote solar energy in India. This review on solar photovoltaic energy will help decision makers and various stakeholders to understand the current status, barriers and challenges for better planning and management in this field.

Journal ArticleDOI
TL;DR: In this article, different solar power technologies have been reviewed which can be utilized for the global sustainable electric power generation, including solar photovoltaic (PV) and concentrated solar power (CSP) technologies.
Abstract: Most of the energy generated globally utilize fossil fuels involving the emission of environmentally hazardous carbon dioxide and depletion of fossil fuel resources. The continuous variation in fuel prices has added a major concern on its sustainable use for future energy requirements. In order to minimize the environmental degradation during energy production process due to emissions of hazardous gases, the utilization of renewable energy resources can make the energy use clean as well as sustainable. Due to an ever increasing demand of clean energy, a sharp rise in the utilization of naturally available solar energy has been observed. Currently, there are several possible routes for solar energy technological developments. In order to effectively utilize the solar power system, one needs to know the technology and its suitability according to the requirements and nature of usage. In this article, different solar power technologies have been reviewed which can be utilized for the global sustainable electric power generation. Major emphasize has been on solar photovoltaic (PV) and concentrated solar power (CSP) technologies. Their types, mechanism, efficiency and cost factors have been discussed. It has been observed that solar PV being more commercially developed and mature technology is suited for both small and large scale applications while CSP technology despite being expensive yield higher economic returns and is suited for large scale applications. Every solar power technology has its own advantage and disadvantage and their preferred usage is basically dependent on the specific case and given conditions. It has also been observed that solar energy, which is a fairly stable and consistently available source of clean energy has the significant potential to cater ever increasing world electricity requirements.

Journal ArticleDOI
TL;DR: In this paper, the authors investigated the possibility of charging battery electric vehicles at workplace in Netherlands using solar energy and proposed a priority mechanism to facilitate the charging of multiple EVs from a single EV-PV charger.

Journal ArticleDOI
TL;DR: In this article, a 1 cm2 near-infrared transparent perovskite solar cell with 14.5% steady-state efficiency was presented, as compared to 16.4% on 0.25 cm2.
Abstract: Combining market-proven silicon solar cell technology with an efficient wide band gap top cell into a tandem device is an attractive approach to reduce the cost of photovoltaic systems. For this, perovskite solar cells are promising high-efficiency top cell candidates, but their typical device size (<0.2 cm2), is still far from standard industrial sizes. We present a 1 cm2 near-infrared transparent perovskite solar cell with 14.5% steady-state efficiency, as compared to 16.4% on 0.25 cm2. By mechanically stacking these cells with silicon heterojunction cells, we experimentally demonstrate a 4-terminal tandem measurement with a steady-state efficiency of 25.2%, with a 0.25 cm2 top cell. The developed top cell processing methods enable the fabrication of a 20.5% efficient and 1.43 cm2 large monolithic perovskite/silicon heterojunction tandem solar cell, featuring a rear-side textured bottom cell to increase its near-infrared spectral response. Finally, we compare both tandem configurations to identify effic...

Journal ArticleDOI
TL;DR: In this article, a state-of-the-art analysis of the available maximum power point tracking (MPPT) techniques and their comprehensive comparative analysis based on 110 standard research articles is presented.
Abstract: Unfilled gap of prolonged energy demand by conventional energy sources and consent of global warming as its vulnerable outcome provides a vent to search compatible option. Augmentation in use of solar energy reveled through last 3 decades portrays its heterogeneous rewards in the prevailing energy scenario. Nevertheless solar PV system arises as viable option in the critical power system era its low efficiency energy conversion attribute necessitates an efficient power conversion system. The nonlinearity of I–V (current–voltage) characteristic and its alteration for an assorted insolation and temperature values may enable the alteration in terminal voltage. This may deviates maximum power point due to which the available maximum power delivery to load can be differed. Literature of this field reiterated that the uniform insolation and partial shading condition demands undeniable need of maximum power point tracking. Nonetheless through investigation in this direction furnishes the availability of a bunch of such techniques; each of them posses its own pros and cones. This ubiquitous trait of available maximum power point tracking (MPPT) techniques unfolds the complexity in its precise selection. To diminish such complexity this paper offers a state of art of various MPPT technique and their comprehensive comparative analysis based on 110 standard research articles. The focus of this paper is to offer a better commencement and to furnish valued information for investigators of this field.

Journal ArticleDOI
TL;DR: In this paper, the lifetime of single-crystal CdTe solar cells was shown to be comparable to those in GaAs over a hole density range relevant for solar applications.
Abstract: CdTe solar cells have the potential to undercut the costs of electricity generated by other technologies, if the open-circuit voltage can be increased beyond 1 V without significant decreases in current. However, in the past decades, the open-circuit voltage has stagnated at around 800–900 mV. This is lower than in GaAs solar cells, even though GaAs has a smaller bandgap; this is because it is more difficult to achieve simultaneously high hole density and lifetime in II–VI materials than in III–V materials. Here, by doping the CdTe with a Group V element, we report lifetimes in single-crystal CdTe that are nearly radiatively limited and comparable to those in GaAs over a hole density range relevant for solar applications. Furthermore, the deposition on CdTe of nanocrystalline CdS layers that form non-ideal heterointerfaces with 10% lattice mismatch impart no damage to the CdTe surface and show excellent junction transport properties. These results enable the fabrication of CdTe solar cells with open-circuit voltage greater than 1 V. Solar cells based on CdTe are a promising low-cost alternative to mainstream Si devices, but they usually produce voltages below 900 mV. Burst et al. now show that open-circuit voltages greater than 1 V can be achieved by doping the CdTe with a group V element.

Journal ArticleDOI
TL;DR: In this article, the authors investigated the thermal efficiency enhancement of the commercial parabolic collector by increasing the convective heat transfer coefficient between the working fluid and the absorber, and showed that the use of nanofluids increases the collector efficiency by 4.25% while the geometry improvement increases the efficiency by4.55%.

Journal ArticleDOI
TL;DR: Major aspects of the film morphology through the development of intermediate chemistry retarding the rapid reaction between methylammonium or formamidinium iodide and lead halide (PbI2) for improved perovskite film formation are described and the recent incredible achievements in PSCs are summarized, and challenges facing the future development and commercialization are provided.
Abstract: ConspectusA long-standing dream in the large scale application of solar energy conversion is the fabrication of solar cells with high-efficiency and long-term stability at low cost. The realization of such practical goals depends on the architecture, process and key materials because solar cells are typically constructed from multilayer heterostructures of light harvesters, with electron and hole transporting layers as a major component. Recently, inorganic–organic hybrid lead halide perovskites have attracted significant attention as light absorbers for the fabrication of low-cost and high-efficiency solar cells via a solution process. This mainly stems from long-range ambipolar charge transport properties, low exciton binding energies, and suitable band gap tuning by managing the chemical composition. In our pioneering work, a new photovoltaic platform for efficient perovskite solar cells (PSCs) was proposed, which yielded a high power conversion efficiency (PCE) of 12%. The platform consisted of a pill...

Journal ArticleDOI
TL;DR: In this paper, a coupled simulation model is developed for both PV production and agricultural production to evaluate the technical potential of scaling agrivoltaic systems, and the results showed that the value of solar generated electricity coupled to shade-tolerant crop production created an over 30% increase in economic value.
Abstract: In order to meet global energy demands with clean renewable energy such as with solar photovoltaic (PV) systems, large surface areas are needed because of the relatively diffuse nature of solar energy. Much of this demand can be matched with aggressive building integrated PV and rooftop PV, but the remainder can be met with land-based PV farms. Using large tracts of land for solar farms will increase competition for land resources as food production demand and energy demand are both growing and vie for the limited land resources. This land competition is exacerbated by the increasing population. These coupled land challenges can be ameliorated using the concept of agrivoltaics or co-developing the same area of land for both solar PV power as well as for conventional agriculture. In this paper, the agrivoltaic experiments to date are reviewed and summarized. A coupled simulation model is developed for both PV production (PVSyst) and agricultural production (Simulateur mulTIdisciplinaire les Cultures Standard (STICS) crop model), to gauge the technical potential of scaling agrivoltaic systems. The results showed that the value of solar generated electricity coupled to shade-tolerant crop production created an over 30% increase in economic value from farms deploying agrivoltaic systems instead of conventional agriculture. Utilizing shade tolerant crops enables crop yield losses to be minimized and thus maintain crop price stability. In addition, this dual use of agricultural land can have a significant effect on national PV production. The results showed an increase in PV power between over 40 and 70 GW if lettuce cultivation alone is converted to agrivoltaic systems in the U.S. It is clear, further work is warranted in this area and that the outputs for different crops and geographic areas should be explored to ascertain the potential of agrivoltaic farming throughout the globe.

Journal ArticleDOI
TL;DR: The interconversion between electricity and hydrogen, two energy carriers directly produced by sunlight, will be a key tool to distribute renewable energies with the highest flexibility.
Abstract: The energy transition from fossil fuels to renewables is already ongoing, but it will be a long and difficult process because the energy system is a gigantic and complex machine. Key renewable energy production data show the remarkable growth of solar electricity technologies and indicate that crystalline silicon photovoltaics (PV) and wind turbines are the workhorses of the first wave of renewable energy deployment on the TW scale around the globe. The other PV alternatives (e.g., copper/indium/gallium/selenide (CIGS) or CdTe), along with other less mature options, are critically analyzed. As far as fuels are concerned, the situation is significantly more complex because making chemicals with sunshine is far more complicated than generating electric current. The prime solar artificial fuel is molecular hydrogen, which is characterized by an excellent combination of chemical and physical properties. The routes to make it from solar energy (photoelectrochemical cells (PEC), dye-sensitized photoelectrochemical cells (DSPEC), PV electrolyzers) and then synthetic liquid fuels are presented, with discussion on economic aspects. The interconversion between electricity and hydrogen, two energy carriers directly produced by sunlight, will be a key tool to distribute renewable energies with the highest flexibility. The discussion takes into account two concepts that are often overlooked: the energy return on investment (EROI) and the limited availability of natural resources-particularly minerals-which are needed to manufacture energy converters and storage devices on a multi-TW scale.

Journal ArticleDOI
TL;DR: A four-terminal all-perovskite tandem solar cell is demonstrated by combining this low-bandgap cell with a semitransparent MAPbI3 cell to achieve a high efficiency of 19.08%.
Abstract: A low-bandgap (1.33 eV) Sn-based MA0.5 FA0.5 Pb0.75 Sn0.25 I3 perovskite is developed via combined compositional, process, and interfacial engineering. It can deliver a high power conversion efficiency (PCE) of 14.19%. Finally, a four-terminal all-perovskite tandem solar cell is demonstrated by combining this low-bandgap cell with a semitransparent MAPbI3 cell to achieve a high efficiency of 19.08%.

Journal ArticleDOI
TL;DR: In this article, a review of the development in the field of solar thermochemical processing by considering experimental demonstrations, reactor technology development, thermodynamic, economic and life cycle analyses is presented.
Abstract: This paper reviews development in the field of solar thermochemical processing by considering experimental demonstrations, reactor technology development, thermodynamic, economic and life cycle analyses. The review then builds on these aspects and compares various solar thermochemical processes. Solar upgrading of carbon feed has been demonstrated on pilot scale. It is observed that for the thermochemical cycles, only iron and ceria based redox pair have been demonstrated on pilot scale. For industrial applications, solar thermochemical production of zinc, upgrading of landfill gas and organic waste have been demonstrated on pilot scale. However, long term performance data of these pilot plants is not reported in literature. Thermodynamic comparison reveals that the processes involving upgrading of carbon feed have energy and exergy efficiency at 50–90% and 46–48% respectively. Multistep thermochemical cycles operating at 900–1200 K have energy efficiency of 34–38%. Metal oxide redox pair based thermochemical cycles operating at 1900–2300 K have energy and exergy efficiencies of 12–32% and 20–36% respectively. Methane reforming and lime production processes have chemical efficiencies of 55% and 35% respectively and have demonstrated better performance than other solar thermochemical processes. A few processes like solar gasification of solid carbon feed have demonstrated lower chemical efficiency of around 10% even at pilot scale. The hydrogen production cost for solar upgrading of fossil fuels is estimated at 3.21–6.10$/kg and is lower than thermochemical cycles at 7.17–19.26$/kg and CSP driven electrolysis at 3.15–10.23$/kg. It is observed that there is limited actual data and significant uncertainty in cost. Under these circumstances, it is recommended that initial screening of processes be done by net energy, material and life cycle analysis.

Journal ArticleDOI
TL;DR: In this article, the photothermic effect arising from plasmonic metal nanoparticles causes localized interfacial heating which directly triggers surface-dominated catalysis and steam generation processes, with minimal heat losses, reduced thermal masses and optics implementation.
Abstract: Using readily available renewable resources, i.e. solar energy and seawater, to secure sustainable fuel and freshwater for humanity is an impactful quest. Here, we have designed solar thermal collector nanocomposites (SiO2/Ag@TiO2 core–shell) that possess efficient photothermic properties for highly targeted interfacial phase transition reactions that are synergistically favorable for both seawater catalysis and desalination reactions. The photothermic effect arising from plasmonic metal nanoparticles causes localized interfacial heating which directly triggers surface-dominated catalysis and steam generation processes, with minimal heat losses, reduced thermal masses and optics implementation. The solar thermal collector nanocomposites are seawater/photo stable for practical solar conversion of seawater to simultaneously produce clean energy and water. Finally, a proof-of-concept all-in-one compact solar hydrogen and distillate production prototype demonstrates the viability of sustainable photothermic driven catalysis and desalination of seawater under natural sunlight. Importantly, this approach holds great promise for enhancing energy and water productivity without considerable capital, infrastructure and environmental ramifications.

Journal ArticleDOI
TL;DR: A high-performance, cotton-textile-enabled asymmetric supercapacitor is integrated with a flexible solar cell via a scalable roll-to-roll manufacturing approach to fabricate a self-sustaining power pack, demonstrating its potential to continuously power future electronic devices.
Abstract: With rising energy concerns, efficient energy conversion and storage devices are required to provide a sustainable, green energy supply. Solar cells hold promise as energy conversion devices due to their utilization of readily accessible solar energy; however, the output of solar cells can be non-continuous and unstable. Therefore, it is necessary to combine solar cells with compatible energy storage devices to realize a stable power supply. To this end, supercapacitors, highly efficient energy storage devices, can be integrated with solar cells to mitigate the power fluctuations. Here, we report on the development of a solar cell-supercapacitor hybrid device as a solution to this energy requirement. A high-performance, cotton-textile-enabled asymmetric supercapacitor is integrated with a flexible solar cell via a scalable roll-to-roll manufacturing approach to fabricate a self-sustaining power pack, demonstrating its potential to continuously power future electronic devices.