Solid-state battery

About: Solid-state battery is a research topic. Over the lifetime, 912 publications have been published within this topic receiving 13224 citations.

Solid Electrolyte: the Key for High‐Voltage Lithium Batteries

Abstract: A solid-state high-voltage (5 V) lithium battery is demonstrated to deliver a cycle life of 10 000 with 90% capacity retention. Furthermore, the solid electrolyte enables the use of high-voltage cathodes and Li anodes with minimum side reactions, leading to a high Coulombic efficiency of 99.98+%.

Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries

Abstract: Solid state electrolyte systems boasting Li+ conductivity of >10 mS cm−1 at room temperature have opened the potential for developing a solid state battery with power and energy densities that are competitive with conventional liquid electrolyte systems. The primary focus of this review is twofold. First, differences in Li penetration resistance in solid state systems are discussed, and kinetic limitations of the solid state interface are highlighted. Second, technological challenges associated with processing such systems in relevant form factors are elucidated, and architectures needed for cell level devices in the context of product development are reviewed. Specific research vectors that provide high value to advancing solid state batteries are outlined and discussed.

Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries

Abstract: Solid state electrolyte systems boasting Li+ conductivity of >10 mS cm−1 at room temperature have opened the potential for developing a solid state battery with power and energy densities that are competitive with conventional liquid electrolyte systems. The primary focus of this review is twofold. First, differences in Li penetration resistance in solid state systems are discussed, and kinetic limitations of the solid state interface are highlighted. Second, technological challenges associated with processing such systems in relevant form factors are elucidated, and architectures needed for cell level devices in the context of product development are reviewed. Specific research vectors that provide high value to advancing solid state batteries are outlined and discussed.

Toward a Fundamental Understanding of the Lithium Metal Anode in Solid-State Batteries-An Electrochemo-Mechanical Study on the Garnet-Type Solid Electrolyte Li6.25Al0.25La3Zr2O12.

Abstract: For the development of next-generation lithium batteries, major research effort is made to enable a reversible lithium metal anode by the use of solid electrolytes. However, the fundamentals of the solid-solid interface and especially the processes that take place under current load are still not well characterized. By measuring pressure-dependent electrode kinetics, we explore the electrochemo-mechanical behavior of the lithium metal anode on the garnet electrolyte Li6.25Al0.25La3Zr2O12. Because of the stability against reduction in contact with the lithium metal, this serves as an optimal model system for kinetic studies without electrolyte degradation. We show that the interfacial resistance becomes negligibly small and converges to practically 0 Ω·cm2 at high external pressures of several 100 MPa. To the best of our knowledge, this is the smallest reported interfacial resistance in the literature without the need for any interlayer. We interpret this observation by the concept of constriction resistance and show that the contact geometry in combination with the ionic transport in the solid electrolyte dominates the interfacial contributions for a clean interface in equilibrium. Furthermore, we show that-under anodic operating conditions-the vacancy diffusion limitation in the lithium metal restricts the rate capability of the lithium metal anode because of contact loss caused by vacancy accumulation and the resulting pore formation near the interface. Results of a kinetic model show that the interface remains morphologically stable only when the anodic load does not exceed a critical value of approximately 100 μA·cm-2, which is not high enough for practical cell setups employing a planar geometry. We highlight that future research on lithium metal anodes on solid electrolytes needs to focus on the transport within and the morphological instability of the metal electrode. Overall, the results help to develop a deeper understanding of the lithium metal anode on solid electrolytes, and the major conclusions are not limited to the Li|Li6.25Al0.25La3Zr2O12 interface.