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Solubility

About: Solubility is a(n) research topic. Over the lifetime, 53643 publication(s) have been published within this topic receiving 1195130 citation(s).
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Book
01 Aug 1991-
Abstract: The Solubility of Hydrocarbons in Water. Solubility of Amphiphiles in Water and Organic Solvents. The Effect of Temperature: Anomalous Entropy and Heat Capacity. The Structure of Water. Micelles: Introduction. Thermodynamics of Micelle Formation. Micelle Size and Shape. Mixed Micelles. Monolayers. Biological Lipids. Motility and Order. Proteins: Hydrophobic Side Chains and Conformational Change. The Association of Hydrocarbons and Amphiphiles with Common Soluble Proteins. Serum Lipoproteins. Biological Membranes. Membrane Proteins. Author and Subject Indices.

3,356 citations


Journal ArticleDOI
01 Nov 1974-Marine Chemistry
Abstract: New measurements of the solubility of carbon dioxide in water and seawater confirm the accuracy of the measurements of Murray and Riley, as opposed to those of Li and Tsui. Corrections for non-ideal behavior in the gas phase and for dissociation in distilled water are required to calculate solubility coefficients from these sets of data. Equations for the solubilities of real gases are presented and discussed. Solubility coefficients for carbon dioxide in water and seawater are calculated for the data of Murray and Riley, and are fitted to equations in temperature and salinity of the form used previously to fit the solubilities of other gases.

2,509 citations


Book
17 Sep 1999-
Abstract: Solubility Parameters - An Introduction C.M. Hansen Hildebrand Parameters and Basic Polymer Solution Thermodynamics Hansen Solubility Parameters Methods and Problems in the Determination of Partial Solubility Parameters Calculation of the Dispersion Solubility Parameter deltad Calculation of the Polar Solubility Parameter deltap Calculation of the Hydrogen Bonding Solubility Parameter deltah Supplementary Calculations And Procedures Hansen Solubility Parameters for Water Theory - The Prigogine Corresponding States Theory, the c12 Interaction Parameter, and the Hansen Solubility Parameters C.M. Hansen Hansen Solubility Parameters (HSP) Resemblance Between Predictions of Hansen Solubility Parameters and Corresponding States Theories The c12Parameter and Hansen Solubility Parameters Comparison of Calculated and Experimental c12 Parameters General Discussion Postscript Statistical Thermodynamic Calculations of the Hydrogen Bonding, Dipolar, and Dispersion Solubility Parameters C. Panayiotou Theory Applications Discussion and Conclusions Appendix I: The Acid Dimerization Appendix II: An Alternative Form of the Polar Term Appendix III: A Group-Contribution Method for the Prediction of delta and deltaD Hansen Solubility Parameters (HSP) in Thermodynamic Models for Polymer Solutions G.M. Kontogeorgis Group Contribution Methods for Estimating Properties of Polymers Activity Coefficients Models Using the HSP Conclusions and Future Challenges Appendix I: An Expression of the FH Model for Multicomponent Mixture Methods of Characterization - Polymers C.M. Hansen Calculation of Polymer HSP Solubility - Examples Swelling - Examples Melting Point Determinations - Effect of Temperature Environmental Stress Cracking Intrinsic Viscosity Measurements Other Measurement Techniques Methods of Characterization - Surfaces C.M. Hansen Hansen Solubility Parameter Correlations with Surface Tension (Surface Free Energy) Method to Evaluate the Cohesion Energy Parameters for Surfaces A Critical View of the Critical Surface Tensions A Critical View of the Wetting Tension Additional Hansen Solubility Parameter Surface Characterizations and Comparisons Self-Stratifying Coatings Maximizing Physical Adhesion Methods of Characterization for Pigments, Fillers, and Fibers C.M. Hansen Methods to Characterize Pigment, Filler, and Fiber Surfaces Discussion - Pigments, Fillers, and Fibers Hansen Solubility Parameter Correlation of Zeta Potential for Blanc Fixe Carbon Fiber Surface Characterization Controlled Adsorption (Self-Assembly) Applications - Coatings and Other Filled Polymer Systems C.M. Hansen Solvents Techniques for Data Treatment Solvents and Surface Phenomena in Coatings (Self-Assembly) Polymer Compatibility Hansen Solubility Parameter Principles Applied to Understanding Other Filled Polymer Systems Hansen Solubility Parameters of Asphalt, Bitumen and Crude Oils P. Redelius Models of Bitumen Asphaltenes Molecular Weight Polarity Solubility Parameters of Bitumen Testing of Bitumen Solubility Hildebrand Solubility Parameters Hansen Solubility Parameters (HSP) The Solubility Sphere Computer Program for Calculation and Plotting of the Hansen 3D Pseudosphere Components of Bitumen Bitumen and Polymers Crude Oil Turbidimetric Titrations BISOM Test Determination of Hansen Solubility Parameter Values for Carbon Dioxide L.L. Williams Methodology One-Component Hildebrand Parameter as a Function of Temperature and Pressure Three-Component (Hansen) Solubility Parameters - Pure CO2 Temperature and Pressure Effects on HSPs: deltad Temperature and Pressure Effects on HSPs: deltap Temperature and Pressure Effects on HSPs: deltah Addendum Appendix I: Ideal Solubility of Gases in Liquids and Published CO2 Solubility Data Use of Hansen Solubility Parameters to Identify Cleaning Applications for "Designer" Solvents J. Durkee A Variety of Solvents Pathology of Soils HSP of Multiple-Component Soils Method for Calculating HSP of Composites (Soils or Solvents) More Realistic View About Evaluating HSP of Composite Soils Method for Choice of Suitable Solvents Reference Soils for Comparison Identification of Designer Solvents An Open Question - Answered Limiting RA Value For Expected Good Cleaning Performance Application of HSP Methodology to Cleaning Operations Analysis of Capability of Designer Solvents Applications - Chemical Resistance C.M. Hansen Chemical Resistance - Acceptable-or-Not Data Effects of Solvent Molecular Size Chemical Resistance - Examples Special Effects with Water Applications - Barrier Polymers C.M. Hansen Concentration-Dependent Diffusion Solubility Parameter Correlations Based on Permeation Phenomena Solubility Parameter Correlation of Polymer Swelling Solubility Parameter Correlation of Permeation Coefficients for Gases General Considerations Applications - Environmental Stress Cracking in Polymers C.M. Hansen ESC Interpreted Using HSP ESC With Nonabsorbing Stress Cracking Initiators Hansen Solubility Parameters - Biological Materials C.M. Hansen and T. Svenstrup Poulsen Hydrophobic Bonding and Hydrophilic Bonding (Self-Association) DNA Cholesterol Lard Human Skin Proteins - Blood Serum and Zein Chlorophyll and Lignin Wood Chemicals and Polymers Urea Water Surface Mobility Chiral Rotation, Hydrogen Bonding, and Nanoengineering Absorption and Diffusion in Polymers C.M. Hansen Steady State Permeation The Diffusion Equation Surface Resistance Side Effects Film Formation by Solvent Evaporation Anomalous Diffusion (Case II, Super Case II) Applications - Safety and Environment C.M. Hansen Substitution Alternative Systems Solvent Formulation And Personal Protection For Least Risk The Danish Mal System - The Fan Selection of Chemical Protective Clothing Uptake of Contents by a Plastic Container Skin Penetration Transport Phenomena The Future Hansen Solubility Parameter Data and Data Quality Group Contribution Methods Polymers as Points - Solvents as Spheres Characterizing Surfaces Materials and Processes Suggested for Further Attention Theoretical Problems Awaiting Future Resolution Appendices Hansen Solubility Parameters for Selected Solvents with the major contribution of Hanno Priebe Hansen Solubility Parameters for Selected Correlations Solubility Data for the Original 33 Polymers and 88 Solvents Index * Each Chapter contains an Abstract, an Introduction, and a Conclusion. Many chapters may also include Acknowledgements, Additional Discussions or General Comments/Considerations, and chapter-specific Key Words, Abbreviations, and Symbols

2,388 citations


01 Jan 1965-

2,363 citations


Book
29 Oct 1991-
Abstract: INTRODUCTION THERMODYNAMICS Cohesive Energy Cohesive Pressure and the Hildebrand Parameter Thermodynamic Equation of State Empirical Equations of State Units and Conversion Factors Mixtures Phase Separation MOLECULAR INTERACTIONS Electrical Properties Dipole-Dipole Interactions Dipole-Induced Dipole Interactions Induced Dipole-Induced Dipole Interactions Spectroscopic Studies Positron Annihilation REGULAR SOLUTIONS AND THE HILDEBRAND PARAMETER Geometric Mean Approximation Hildebrand-Scatchard Equation Limitations of the Hildebrand-Scatchard Equation Mixed Liquids and Multicomponent Systems Solvent Spectra Wilson Equation EXPANDED COHESION PARAMETERS Dispersion Orientation Induction Lewis Acid-Base Hydrogen-Bonding Association Combination of Component Cohesion Parameters Empirical Corrections for Geometric Mean Deviations Polar-Nonpolar Cohesion Parameters Hansen Parameters Fractional Three-Component Cohesion Parameters Other Two- and Three-Component Cohesion Parameters Other Multi-Component Cohesion Parameters Modified Separation of Cohesive Energy Density Liquid Metals CALCULATED COHESION PARAMETERS Group Molar Vaporization Enthalpy Group Molar Cohesive Energy Molar Additive Functions Group Molar Attraction Constants Group Molar Volumes Group Cohesion Parameters Homomorphs and Dispersion Cohesion Parameters Hansen Parameter Group Contributions Participating and Nonparticipating Groups Comparison of Methods LIQUID PHASES Vaporization Enthalpy Vapor Pressure Boiling Point Corresponding States Internal Pressure and Cohesive Pressure Liquid-Liquid Miscibility Binary Solvents Activity Coefficients in Liquid-Liquid Systems Complexes Solvent-Aided Separation Liquid Extraction Acidity-Basicity Linear Energy Scales SOLVENT SCALES Hydrogen Bonding Electrostatic Parameters and Empirical Relationships Single Component Donor-Acceptor Parameters Hybrid Cohesion Parameter Solvent Scales Practical Solvent Scales EFFECTS OF PHYSICAL CONDITIONS Temperature Density, Volume and Pressure Concentration KINETIC AND TRANSPORT PROCESSES Kinetic Solvent Effects Transition State Theory Rates and Mechanisms Polymerization and Polymer Reactions Viscosity Other Time-Dependent Properties GASES Nomenclature Hildebrand Parameters and Gas Solubilities Compressed Gases Supercritical Extraction Vapor-Liquid Equilibria in Mixtures Henry's Law SOLIDS Activities and Solubilities Cohesion Parameters for Nonionic Solid Solutes Ionic Systems POLYMER SOLUTIONS Physical Properties of Polymers The Polymer-Liquid Reference Solution Polymer-Liquid Interaction Parameters Limitations on Interaction Parameters Interaction Parameters and Cohesion Parameters Cosolvency and Co-Nonsolvency Theta Temperature and Theta Solvents Segment Interaction Equation DETERMINATION OF POLYMER COHESION PARAMETERS Hildebrand Parameter Values Hildebrand Parameters from Polymer-Liquid Interaction Parameters Solubility/Swelling Spectrum Methods Turbidimetric Titrations Hansen Parameters Other Cohesion Parameters Solution Viscosity Calculation of Polymer Cohesion Parameters Effects of Temperature, Concentration, Molecular Weight POLYMER MAPS AND MODELS Cohesion Parameter Maps and Models Hybrid Maps and Models CORRELATION OF POLYMER PROPERTIES WITH COHESION PARAMETERS Electrical Properties Mechanical Properties Thermal Transitions and Plasticization Environment-Induced Degradation Radiation Interactions With Gases and Liquids Permeation Interactions With Low Molecular Weight Solids Polymer-Polymer Interactions Copolymers Natural Polymers SURFACES AND INTERFACES Interfacial Free Energy Interfacial Free Energies and Cohesion Parameters Component Surface Free Energies and Cohesion Parameters Multicomponent Systems Wetting, Adhesion, Lubrication, Powders Adsorption Micelles, Colloids, Emulsions, Foams, Surfactants Dispersion of Pigments and Dyes Surface Contamination and Cleaning CHROMATOGRAPHY Component Cohesion Parameter Expressions GLC Interactions of Polymers and Plasticizers With Liquids GLC Studies of Nonpolymer Systems Liquid Chromatography Supercritical Fluid Chromatography Liquid-Solid Chromatography and Gel Chromatography BIOLOGICAL SYSTEMS Hansch Lipophilic Parameter Effects and Transmission Rates of Biologically-Active Materials Prosthetic Materials Other Biological Systems

1,926 citations


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Performance
Metrics
No. of papers in the topic in previous years
YearPapers
202259
20211,667
20201,890
20191,911
20181,762
20172,001

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Topic's top 5 most impactful authors

William E. Acree

390 papers, 7.1K citations

Abolghasem Jouyban

319 papers, 5.6K citations

Fleming Martínez

247 papers, 5K citations

Hongkun Zhao

223 papers, 1.9K citations

Junbo Gong

83 papers, 1.4K citations