Topic
Standard molar entropy
About: Standard molar entropy is a research topic. Over the lifetime, 1586 publications have been published within this topic receiving 29886 citations.
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TL;DR: In this paper, the thermodynamics of micelle formation by polystyrene-b-polyisoprene block copolymer in n-hexadecane, which is a selectively bad solvent for poly styrene, has been investigated.
20 citations
TL;DR: The heat capacity of 4,4′-difluorobiphenyl has been measured by adiabatic calorimetry between 3 and 300 K.
20 citations
TL;DR: In this paper, the growth rate vs. temperature relation of Na 2 O · 3SiO 2 has been determined over the temperature range between 600°C and 800°C, with the maximum growth rate (3.3 x 10 -6 cm sec -1 ) observed at 735 °C.
20 citations
TL;DR: In this article, the experimental value of the excess partial molar entropy of hydrogen dissolved in transition metals should include a contribution arising from the partial-molar electronic heat capacity of the hydrogen within the metal.
20 citations
TL;DR: In this paper, the energy dependence of chemical and ionic reactions is examined and a new model is developed for the calculation of reaction probability and postreaction energy disposal for exchange reactions.
Abstract: In this article the energy dependence of chemical and ionic reactions is examined and a new model is developed for the calculation of reaction probability and postreaction energy disposal for exchange reactions. The new model is based on the principles of the maximum entropy method. For the exchange reactions the reaction probability is based on either the translational or the vibrational energy of the reagents as appropriate, whereas for dissociation the vibrational energy is used as the controlling factor. The new method is compared with other methods used for direct simulation Monte Carlo calculations. Examples of flowfield solutions are presented and the differences between the results of the new method, those using Bird's method, and continuum solvers are discussed and evaluated.
20 citations