scispace - formally typeset
Search or ask a question

Showing papers on "State of charge published in 2019"


Journal ArticleDOI
TL;DR: This paper presents a concise, understandable overview of existing methods, key issues, technical challenges, and future trends of the battery state estimation domain, for the first time, in SOC/SOE/SOH/SOP/SOT/SOS estimation.
Abstract: Batteries are presently pervasive in portable electronics, electrified vehicles, and renewable energy storage. These indispensable engineering applications are all safety-critical and energy efficiency-demanding such that batteries must be meticulously monitored and manipulated, where effectively estimating the internal battery states is a key enabler. The primary goal of this paper is to present a concise, understandable overview of existing methods, key issues, technical challenges, and future trends of the battery state estimation domain. More specifically, for the first time, the state of the art in State of Charge (SOC), State of Energy (SOE), State of Health (SOH), State of Power (SOP), State of Temperature (SOT), and State of Safety (SOS) estimation is all elucidated in a tutorial yet systematical way, along with existing issues exposed. In addition, from six different viewpoints, some future important research opportunities and evolving trends of this prosperous field are disclosed, in order to stimulate more technologically innovative breakthroughs in SOC/SOE/SOH/SOP/SOT/SOS estimation.

418 citations


Journal ArticleDOI
TL;DR: A brief review on several key technologies of BMS, including battery modelling, state estimation and battery charging, followed by the introduction of key technologies used in BMS.
Abstract: Batteries have been widely applied in many high-power applications, such as electric vehicles (EVs) and hybrid electric vehicles, where a suitable battery management system (BMS) is vital in ensuring safe and reliable operation of batteries. This paper aims to give a brief review on several key technologies of BMS, including battery modelling, state estimation and battery charging. First, popular battery types used in EVs are surveyed, followed by the introduction of key technologies used in BMS. Various battery models, including the electric model, thermal model and coupled electro-thermal model are reviewed. Then, battery state estimations for the state of charge, state of health and internal temperature are comprehensively surveyed. Finally, several key and traditional battery charging approaches with associated optimization methods are discussed.

338 citations


Journal ArticleDOI
TL;DR: Challenge steps in the implementation of KF family algorithms in model-based online SOC estimation processes, such as selection of battery model, initial SOC and filter tuning, are elaborated for the efficient development of a battery management system, especially for EV application.
Abstract: Carbon impression and the growing reliance on fossil fuels are two unique concerns for world emission regulatory agencies. These issues have placed electric vehicles (EVs) powered by lithium-ion batteries (LIBs) on the forefront as alternative vehicles. The LIB has noticeable features, including high energy and power density, compared with other accessible electrochemical energy storage systems. However, LIB is exceedingly nonlinear and dynamic; therefore, it generally requires an accurate online state-of-charge (SOC) estimation algorithm for real-time applications. Accurate battery modelling is an essential and primary requirement of online SOC estimation to simulate the dynamics. In this paper, different modelling methods suitable for online SOC estimation are discussed, and four groups of available online SOC estimation approaches are reviewed. After the general survey, the study explores the available Kalman filter (KF) family algorithms suitable for model-based online SOC estimation. The mathematical process and limitations of different KF family algorithms are analysed in depth and discussed. Moreover, challenging steps in the implementation of KF family algorithms in model-based online SOC estimation processes, such as selection of battery model, initial SOC and filter tuning, are elaborated for the efficient development of a battery management system, especially for EV application. The on-going research is propelled by KF-based online SOC estimation approaches distinctly emphasised through reviewing various studies for future research progression.

314 citations


Journal ArticleDOI
TL;DR: Short term power forecast of wind and solar power is proposed to evaluate the available output power of each production component and includes a feature selection filter and hybrid forecast engine based on neural network and an intelligent evolutionary algorithm.
Abstract: In this paper short term power forecast of wind and solar power is proposed to evaluate the available output power of each production component. In this model, lead acid batteries used in proposed hybrid power system based on wind-solar power system. So, before the predicting of power output, a simple mathematical approach to simulate the lead–acid battery behaviors in stand-alone hybrid wind-solar power generation systems will be introduced. Then, the proposed forecast problem will be evaluated which is taken as constraint status through state of charge (SOC) of the batteries. The proposed forecast model includes a feature selection filter and hybrid forecast engine based on neural network (NN) and an intelligent evolutionary algorithm. This method not only could maintain the SOC of batteries in suitable range, but also could decrease the on-or-off switching number of wind turbines and PV modules. Effectiveness of the proposed method has been applied over real world engineering data. Obtained numerical analysis, demonstrate the validity of proposed method.

312 citations


Journal ArticleDOI
TL;DR: This review presents the recent SOC estimation methods highlighting the model-based and data-driven approaches and delivers potential recommendations for the development of SOC estimation method of lithium-ion battery in EV applications.
Abstract: Lithium-ion battery is an appropriate choice for electric vehicle (EV) due to its promising features of high voltage, high energy density, low self-discharge and long lifecycles. The successful operation of EV is highly dependent on the operation of battery management system (BMS). State of charge (SOC) is one of the vital paraments of BMS which signifies the amount of charge left in a battery. A good estimation of SOC leads to long battery life and prevention of catastrophe from battery failure. Besides, an accurate and robust SOC estimation has great significance towards an efficient EV operation. However, SOC estimation is a complex process due to its dependency on various factors such as battery age, ambient temperature, and many unknown factors. This review presents the recent SOC estimation methods highlighting the model-based and data-driven approaches. Model-based methods attempt to model the battery behavior incorporating various factors into complex mathematical equations in order to accurately estimate the SOC while the data-driven methods adopt an approach of learning the battery's behavior by running complex algorithms with a large amount of measured battery data. The classifications of model-based and data-driven based SOC estimation are explained in terms of estimation model/algorithm, benefits, drawbacks, and estimation error. In addition, the review highlights many factors and challenges and delivers potential recommendations for the development of SOC estimation methods in EV applications. All the highlighted insights of this review will hopefully lead to increased efforts toward the enhancement of SOC estimation method of lithium-ion battery for the future high-tech EV applications.

289 citations


Journal ArticleDOI
15 May 2019-Energy
TL;DR: A recurrent neural network with gated recurrent unit is proposed to estimate the battery SOC from measured current, voltage, and temperature signals, which exploits information of the previous SOCs and measurements and yields better estimation accuracy.

248 citations


Journal ArticleDOI
30 Jan 2019-Energies
TL;DR: In this paper, Li-ion batteries have attracted considerable attention in the EV industry owing to their high energy density, lifespan, nominal voltage, power density, and cost, and a smart battery management system is one of the essential components; it not only measures the states of battery accurately, but also ensures safe operation and prolongs the battery life.
Abstract: Energy storage system (ESS) technology is still the logjam for the electric vehicle (EV) industry. Lithium-ion (Li-ion) batteries have attracted considerable attention in the EV industry owing to their high energy density, lifespan, nominal voltage, power density, and cost. In EVs, a smart battery management system (BMS) is one of the essential components; it not only measures the states of battery accurately, but also ensures safe operation and prolongs the battery life. The accurate estimation of the state of charge (SOC) of a Li-ion battery is a very challenging task because the Li-ion battery is a highly time variant, non-linear, and complex electrochemical system. This paper explains the workings of a Li-ion battery, provides the main features of a smart BMS, and comprehensively reviews its SOC estimation methods. These SOC estimation methods have been classified into four main categories depending on their nature. A critical explanation, including their merits, limitations, and their estimation errors from other studies, is provided. Some recommendations depending on the development of technology are suggested to improve the online estimation.

237 citations


Journal ArticleDOI
TL;DR: Train, validation, and test are conducted for two commercial Li-ion batteries with Li(NiCoMn)1/3O2 cathode and graphite anode, indicating that the algorithm can estimate the battery SOH with less than 2% error for 80% of all the cases, and less than 3%error for 95% ofall the cases.
Abstract: The online estimation of battery state-of-health (SOH) is an ever significant issue for the intelligent energy management of the autonomous electric vehicles. Machine-learning based approaches are promising for the online SOH estimation. This paper proposes a machine-learning based algorithm for the online SOH estimation of Li-ion battery. A predictive diagnosis model used in the algorithm is established based on support vector machine (SVM). The support vectors, which reflects the intrinsic characteristics of the Li-ion battery, are determined from the charging data of fresh cells. Furthermore, the coefficients of the SVMs for cells at different SOH are identified once the support vectors are determined. The algorithm functions by comparing partial charging curves with the stored SVMs. Similarity factor is defined after comparison to quantify the SOH of the data under evaluation. The operation of the algorithm only requires partial charging curves, e.g., 15 min charging curves, making fast on-board diagnosis of battery SOH into reality. The partial charging curves can be intercepted from a wide range of voltage section, thereby relieving the pain that there is little chance that the driver charges the battery pack from a predefined state-of-charge. Train, validation, and test are conducted for two commercial Li-ion batteries with Li(NiCoMn)1/3O2 cathode and graphite anode, indicating that the algorithm can estimate the battery SOH with less than 2% error for 80% of all the cases, and less than 3% error for 95% of all the cases.

222 citations


Journal ArticleDOI
TL;DR: A novel SOH estimation method by using a prior knowledge-based neural network (PKNN) and the Markov chain for a single LIB and the maximum estimation error of the SOH is reduced to less than 1.7% by adopting the proposed method.
Abstract: The state of health (SOH) of lithium-ion batteries (LIBs) is a critical parameter of the battery management system. Because of the complex internal electrochemical properties of LIBs and uncertain external working environment, it is difficult to achieve an accurate SOH determination. In this paper, we have proposed a novel SOH estimation method by using a prior knowledge-based neural network (PKNN) and the Markov chain for a single LIB. First, we extract multiple features to capture the battery aging process. Due to its effective fitting ability for complex nonlinear problems, the neural network with a prior knowledge-based optimization strategy is adopted for the battery SOH prediction. The Markov chain, with the advantageous prediction performance for the long-term system, is established to modify the PKNN estimation results based on the prediction error. Experimental results show that the maximum estimation error of the SOH is reduced to less than 1.7% by adopting the proposed method. By comparing with the group method of data handling and the back-propagation neural network in conjunction with the Levenberg–Marquardt algorithm, the proposed estimation method obtains the highest SOH accuracy.

189 citations


Journal ArticleDOI
TL;DR: A novel fractional-order model for a battery, which considers both Butler–Volmer equation and fractional calculus of constant phase element is proposed, which has higher estimation accuracy in battery terminal voltage and SOC than the traditional model over wide range of temperature and ageing level under electric vehicle operation conditions.
Abstract: Battery models are the cornerstone to battery state of charge (SOC) estimation and battery management systems in electric vehicles. This paper proposes a novel fractional-order model for a battery, which considers both Butler–Volmer equation and fractional calculus of constant phase element. The structure characteristics of the proposed model are then analyzed, and a novel identification method, which combines least squares and nonlinear optimization algorithm, is proposed. The method is proven to be efficient and accurate. Based on the proposed model, a fractional-order unscented Kalman filter is developed to estimate SOC, while singular value decomposition is applied to tackle the nonlinearity of Butler–Volmer equation and fractional calculus of constant phase element. The systematic comparison between the proposed model and traditional fractional order model is carried out on two LiNiMnCo lithium-ion batteries at different temperatures, ageing levels, and electric vehicle current profiles. The comparison results show that the proposed model has higher estimation accuracy in battery terminal voltage and SOC than the traditional model over wide range of temperature and ageing level under electric vehicle operation conditions. Furthermore, the hardware-in-the-loop test validates that the proposed SOC estimation method is suitable for SOC estimation in electric vehicles.

179 citations


Journal ArticleDOI
TL;DR: In this article, a cost-optimal autonomous hybrid renewable energy system is developed and comparatively analyzed, considering the saturation level of each involved renewable energy source based on various technical and economic key indicators.

Journal ArticleDOI
TL;DR: A novel SOH estimation and aging mechanism identification method that is validated by batteries aged at different conditions based on the idea of cross validation, and the estimation error of the remaining capacity can be reduced within 3.1%.
Abstract: State of health (SOH) estimation of lithium-ion batteries is a key but challengeable technique for the application of electric vehicles Due to the ambiguous aging mechanisms and sensitivity to the applied conditions of lithium-ion batteries, the recognition of aging mechanisms and SOH monitoring of the battery might be difficult A novel SOH estimation and aging mechanism identification method is presented in this paper First, considering the dispersion effect, a fractional-order model is constructed, and the parameter identification approach is proposed, and a comparison between integer-order model and fractional-order model has been done from the prospect of predicting accuracy Then, based on the identified open-circuit voltage, the battery aging mechanism can be analyzed by the means of an incremental capacity analysis method Moreover, the normalized incremental capacity peak is used to estimate the remaining capacity Finally, the robustness of the SOH estimation method is validated by batteries aged at different conditions based on the idea of cross validation, and the estimation error of the remaining capacity can be reduced within 31%

Journal ArticleDOI
TL;DR: A model predictive control strategy without using any proportional–integral–derivative (PID) regulators is proposed and shows better performance, which is validated in simulation based on a 3.5-MW PV-wind-battery system with real-world solar and wind profiles.
Abstract: In renewable energy systems, fluctuating outputs from energy sources and variable power demand may deteriorate the voltage quality. In this paper, a model predictive control strategy without using any proportional–integral–derivative (PID) regulators is proposed. The proposed strategy consists of a model predictive current and power (MPCP) control scheme and a model predictive voltage and power (MPVP) control method. By controlling the bidirectional dc–dc converter of the battery energy storage system based on the MPCP algorithm, the fluctuating output from the renewable energy sources can be smoothed while stable dc-bus voltage can be maintained. Meanwhile, the ac/dc interlinking converter is controlled by using the MPVP scheme to ensure stable ac voltage supply and proper power flow between the microgrid and the utility grid. Then, a system-level energy management scheme is developed to ensure stable operation under different operation modes by considering fluctuating power generation, variable power demand, battery state of charge, and electricity price. Compared with the traditional cascade control, the proposed method is simpler and shows better performance, which is validated in simulation based on a 3.5-MW PV-wind-battery system with real-world solar and wind profiles.

Journal ArticleDOI
01 May 2019-Energy
TL;DR: A co-estimation scheme for battery capacity and SOC estimations is proposed, in which an equivalent circuit model (ECM) is used to represent battery dynamics and the recursive least squares (RLS) method and adaptive extended Kalman filter (AEKF) are leveraged simultaneously to achieve online model parameters identification and SOC estimation.

Journal ArticleDOI
TL;DR: A combined method using the battery energy management of plug-in electric vehicles (PEVs) and the active power curtailment of PV arrays is proposed to regulate voltage in LVDNs with high penetration level of PV resources.
Abstract: The rapid growth of rooftop photovoltaic (PV) arrays installed in residential houses leads to serious voltage quality problems in low voltage distribution networks (LVDNs). In this paper, a combined method using the battery energy management of plug-in electric vehicles (PEVs) and the active power curtailment of PV arrays is proposed to regulate voltage in LVDNs with high penetration level of PV resources. A distributed control strategy composed of two consensus algorithms is used to reach an effective utilization of limited storage capacity of PEV battery considering its power/capacity and state of charge. A consensus control algorithm is also developed to fairly share the required power curtailment among PVs during overvoltage periods. The main objective is to mitigate the voltage rise due to the reverse power flow and to compensate the voltage drop resulting from the peak load. Overall, the proposed algorithm contributes to a coordinated charging/discharging control of PEVs battery which provides a maximum utilization of available storage capacity throughout the network. In addition, the coordinated operation minimizes the required active power which is going to be curtailed from PV arrays. The effectiveness of the proposed control scheme is investigated on a typical three-phase four-wire LVDN in presence of PV resources and PEVs.

Journal ArticleDOI
TL;DR: An RUL prediction method based on the Box–Cox transformation (BCT) and Monte Carlo simulation that can reduce the required online training data and, thus, the acceleration aging test time of lithium-ion batteries.
Abstract: The current lithium-ion battery remaining useful life (RUL) prediction techniques are mainly developed dependent on offline training data. The loaded current, temperature, and state of charge of lithium-ion batteries used for electric vehicles (EVs) change dramatically under the working conditions. Therefore, it is difficult to design acceleration aging tests of lithium-ion batteries under similar working conditions as those for EVs and to collect effective offline training data. To address this problem, this paper developed an RUL prediction method based on the Box–Cox transformation (BCT) and Monte Carlo (MC) simulation. This method can be implemented independent of offline training data. In the method, the BCT was used to transform the available capacity data and to construct a linear model between the transformed capacities and cycles. The constructed linear model using the BCT was extrapolated to predict the battery RUL, and the RUL prediction uncertainties were generated using the MC simulation. Experimental results showed that accurate and precise RULs were predicted with errors and standard deviations within, respectively, [-20, 10] cycles and [1.8, 7] cycles. If some offline training data are available, the method can reduce the required online training data and, thus, the acceleration aging test time of lithium-ion batteries. Experimental results showed that the acceleration time of the tested cells can be reduced by 70%–85% based on the developed method, which saved one to three months’ acceleration test time compared to the particle filter method.

Journal ArticleDOI
TL;DR: A simple and effective model-based sensor fault diagnosis scheme is developed to detect and isolate the fault of a current or voltage sensor for a series-connected lithium-ion battery pack and the experimental and simulation results validate the effectiveness of the proposed sensor fault diagnosed scheme.
Abstract: In electric vehicles, a battery management system highly relies on the measured current, voltage, and temperature to accurately estimate state of charge (SOC) and state of health. Thus, the normal operation of current, voltage, and temperature sensors is of great importance to protect batteries from running outside their safe operating area. In this paper, a simple and effective model-based sensor fault diagnosis scheme is developed to detect and isolate the fault of a current or voltage sensor for a series-connected lithium-ion battery pack. The difference between the true SOC and estimated SOC of each cell in the pack is defined as a residual to determine the occurrence of the fault. The true SOC is calculated by the coulomb counting method and the estimated SOC is obtained by the recursive least squares and unscented Kalman filter joint estimation method. In addition, the difference between the capacity used in SOC estimation and the estimated capacity based on the ratio of the accumulated charge to the SOC difference at two nonadjacent sampling times can also be defined as a residual for fault diagnosis. The temperature sensor which is assumed to be fault-free is used to distinguish the fault of a current or voltage sensor from the fault of a battery cell. Then, the faulty current or voltage sensor can be isolated by comparing the residual and the predefined threshold of each cell in the pack. The experimental and simulation results validate the effectiveness of the proposed sensor fault diagnosis scheme.

Journal ArticleDOI
TL;DR: The results show that variations in critical parameters, such as battery minimum state of charge, time step, solar radiation, diesel price, and load growth, exert considerable effects on the performance of the proposed system.
Abstract: In recent years, the concept of hybrid energy systems (HESs) is drawing more attention for electrification of isolated or energy-deficient areas. When optimally designed, HESs prove to be more reliable and economical than single energy source systems. This study examines the feasibility of a combined dispatch (CD) control strategy for a photovoltaic (PV)/diesel/battery HES by combining the load following (LF) strategy and cycle charging (CC) strategy. HOMER software is used as a tool for optimization analysis by investigating the techno-economic and environmental performance of the proposed system under the LF strategy, CC strategy, and combined dispatch CD strategy. The simulation results reveal that the CD strategy has a net present cost (NPC) and cost of energy (COE) values of $110,191 and $0.21/kWh, which are 20.6% and 4.8% lower than those of systems utilizing the LF and CC strategies, respectively. From an environmental point of view, the CD strategy also offers the best performance, with CO2 emissions of 27,678 kg/year. Moreover, the results show that variations in critical parameters, such as battery minimum state of charge, time step, solar radiation, diesel price, and load growth, exert considerable effects on the performance of the proposed system.

Journal ArticleDOI
TL;DR: An MSC diagnostic method is developed by employing recursive least squares filter and it is demonstrated to examine the short-circuit resistance accurately, and shows that the proposed method requires low computational load for the SOC difference and short- circuit resistance diagnosis.
Abstract: Micro-short-circuit (MSC) is a latent risk in power batteries, which may give rise to thermal runaway and even catastrophic safety hazards. The motivation of this paper is to quantitatively analyze MSC in an initial stage, particularly for lithium-ion batteries. To verify the feasibility of the proposed method, an equivalent MSC experiment is carried out. Based on a cell difference model, the cell state of charge (SOC) differences with the mean SOC for a battery pack are estimated by extended Kalman filter. The evaluated SOC difference can track the actual value well. Furthermore, an MSC diagnostic method is developed by employing recursive least squares filter. The method is demonstrated to examine the short-circuit resistance accurately. The results also show that the proposed method requires low computational load for the SOC difference and short-circuit resistance diagnosis.

Journal ArticleDOI
TL;DR: Modeling approaches for parameter inconsistency available in the existing literature are comprehensively surveyed, with the purpose of spurring innovative ideas for establishing new models and catalyzing the development of new diagnostic algorithms.
Abstract: Traction batteries constitute a core technology for electric vehicles. The cells used in such batteries are usually connected in a series-parallel structure. Significant degradation in energy density, cycle life, and safety occurs with battery usage, thanks to discrepancies among cell parameters, such as resistance, capacity, and State of Charge. Hence, it is imperative to explore propagation mechanisms of parameter inconsistency and develop methods to diagnose them. The state of the art in the two aspects are elaborated from three perspectives of internal, external, and coupling effects. Modeling approaches for parameter inconsistency available in the existing literature are comprehensively surveyed, with the purpose of spurring innovative ideas for establishing new models. Methods of data processing and feature extraction are systematically summarized in order to promote diagnostic efficiency and credibility. Moreover, methods of battery inconsistency evaluation and diagnosis are reviewed with the aim of catalyzing the development of new diagnostic algorithms. Finally, existing problems and future trends in the field of battery pack inconsistency research are elucidated.

Journal ArticleDOI
TL;DR: In this article, the authors presented a techno-economic and environmental analysis of different hybrid systems to supply electricity to a typical Iraqi rural village using the HOMER software for the optimization of the systems using the multi-year module.

Journal ArticleDOI
TL;DR: A combined convolutional neural network – long short-term memory (LSTM) network to infer battery SOC from measurable data, such as current, voltage, and temperature, and shows better tracking performance than the LSTM and CNN networks.
Abstract: State-of-charge (SOC), which indicates the remaining capacity at the current cycle, is the key to the driving range prediction of electric vehicles and optimal charge control of rechargeable batteries. In this paper, we propose a combined convolutional neural network (CNN) - long short-term memory (LSTM) network to infer battery SOC from measurable data, such as current, voltage, and temperature. The proposed network shares the merits of both CNN and LSTM networks and can extract both spatial and temporal features from input data. The proposed network is trained using data collected from different discharge profiles, including a dynamic stress test, federal urban driving schedule, and US06 test. The performance of the proposed network is evaluated using data collected from a new combined dynamic loading profile in terms of estimation accuracy and robustness against the unknown initial state. The experimental results show that the proposed CNN-LSTM network well captures the nonlinear relationships between SOC and measurable variables and presents better tracking performance than the LSTM and CNN networks. In case of unknown initial SOCs, the proposed network fast converges to true SOC and, then, presents smooth and accurate results, with maximum mean average error under 1% and maximum root mean square error under 2%. Moreover, the proposed network well learns the influence of ambient temperature and can estimate battery SOC under varying temperatures with maximum mean average error under 1.5% and maximum root mean square error under 2%.

Journal ArticleDOI
TL;DR: In this paper, the authors investigated the thermal runaway and its propagation behavior in the large format lithium-ion battery (LIB) with various states of charge (SOC) and found that the TR is firstly triggered on the layer near the front surface of the LIB, and then spread to the whole battery.

Journal ArticleDOI
TL;DR: A new approach forming a dynamic linear battery model is proposed in this paper, which enables the application of the linear Kalman filter for SOC estimation and also avoids the usage of online parameter identification methods.
Abstract: The performance of model-based state-of-charge (SOC) estimation method relies on an accurate battery model. Nonlinear models are thus proposed to accurately describe the external characteristics of the lithium-ion battery. The nonlinear estimation algorithms and online parameter identification methods are needed to guarantee the accuracy of the model-based SOC estimation with nonlinear battery models. A new approach forming a dynamic linear battery model is proposed in this paper, which enables the application of the linear Kalman filter for SOC estimation and also avoids the usage of online parameter identification methods. With a moving window technology, partial least squares regression is able to establish a series of piecewise linear battery models automatically. One element state-space equation is then obtained to estimate the SOC from the linear Kalman filter. The experiments on a LiFePO4 battery prove the effectiveness of the proposed method compared with the extended Kalman filter with two resistance and capacitance equivalent circuit model and the adaptive unscented Kalman filter with least squares support vector machines.

Journal ArticleDOI
TL;DR: A zinc-iodine single flow battery (ZISFB) with super high energy density, efficiency and stability was designed and presented for the first time in this paper, where an electrolyte with very high concentration (7.5 M KI and 3.75 M ZnBr2) was sealed at the positive side.
Abstract: A zinc–iodine single flow battery (ZISFB) with super high energy density, efficiency and stability was designed and presented for the first time. In this design, an electrolyte with very high concentration (7.5 M KI and 3.75 M ZnBr2) was sealed at the positive side. Thanks to the high solubility of KI, it fully meets the areal capacity of zinc deposition on the negative side. Most importantly, the ZISFB can be charged to nearly 100% state of charge (SOC) or I− can be fully charged to solid state I2 so as to get a maximum energy density. Besides, the blockage of the pump and pipelines on the positive side caused by solid I2 can be inhibited due to the avoidance of electrolyte circulation. Besides, the employment of a highly composite porous polyolefin ion conducting membrane with a super thin Nafion layer effectively improved the membrane selectivity. As a result, the ZISFB demonstrated a CE of 97% and an EE of 81% at a current density of 40 mA cm−2, and the battery could continuously run for more than 500 cycles. The battery demonstrated a high energy density of 205 W h L−1 (theoretical energy density is about 240 W h L−1) (7.5 M KI and 3.75 M ZnBr2 as the electrolyte), which is the highest cycling energy density ever reported. With super high energy density, long cycling life, and a simple structure, a ZISFB becomes a very promising candidate for large scale energy storage and even for power batteries.

Journal ArticleDOI
TL;DR: The results show that the FFNN-based method is an effective method to estimate SoC accurately in complex EV application environment and the SoC estimation errors can be stabilized within 2% after convergence, which applies to all the cases discussed in this paper.

Journal ArticleDOI
TL;DR: A new energy management scheme is proposed for the grid connected hybrid energy storage with the battery and the supercapacitor under different operating modes and the effectiveness of the proposed method is validated by both simulation and experimental studies.
Abstract: DC-coupled microgrids are simple as they do not require any synchronization when integrating different distributed energy generations. However, the control and energy management strategy between the renewable energy sources and the energy storages under different operating modes is a challenging task. In this paper, a new energy management scheme is proposed for the grid connected hybrid energy storage with the battery and the supercapacitor under different operating modes. The main advantages of the proposed energy management scheme are effective power sharing between the different energy storage systems, faster dc link voltage regulation to generation and load disturbances, dynamic power sharing between the battery and the grid based on the battery state of charge, reduced rate of charge/discharge of battery current during steady state and transient power fluctuations, improved power quality features in ac grid and seamless mode transitions. The effectiveness of the proposed method is validated by both simulation and experimental studies.

Journal ArticleDOI
TL;DR: A novel fusion algorithm that combines the direct configuration method and sequential quadratic programming is proposed to achieve optimal fuel cell life economy and energy consumption economy in the prediction horizon, proving the feasibility of the proposed strategy.

Journal ArticleDOI
TL;DR: In this paper, the charge transfer resistance of the battery is obtained by fitting the impedance spectroscopy with an equivalent impedance model to estimate state of health, and an analytical calculation model with temperature and state of charge as inputs is derived and verified considering their effect on the charge-transfer resistance.
Abstract: State of health diagnosis and estimation of lithium-ion batteries is a key feature of an advanced battery management system. Electrochemical impedance spectroscopy is frequently used for the state of health diagnosis and estimation. In the paper, the charge transfer resistance of the battery is obtained by fitting the impedance spectroscopy with an equivalent impedance model to estimate state of health. And an analytical calculation model with temperature and state of charge as inputs is derived and verified considering their effect on the charge transfer resistance. With the calculation model, the charge transfer resistance at randomly selected state of charge and temperature is converted to the standard state to be comparable for the state of health estimation. It is indicated that state of health estimated with the converted and the direct fitted charge transfer resistance agree well. The battery state of health estimation method with the converted charge transfer resistance eliminates the need to specifically control the temperature and state of charge during the impedance spectrum measurement. It benefits the practical application of the state of health estimation with electrochemical impedance spectroscopy.

Journal ArticleDOI
TL;DR: The results show that the LS-EKF-based algorithm has a good performance in SOH and SOC estimation and prediction in terms of accuracy and computation cost.
Abstract: The estimation and prediction of state-of-health (SOH) and state-of-charge (SOC) of Lithium-ion batteries are two main functions of the battery management system (BMS). In order to reduce the computation cost and enable deployment of the BMS on the low-cost hardware, a Lebesgue-sampling-based extended Kalman filter (LS-EKF) is developed to estimate the SOH and SOC. An LS-EKF is able to eliminate unnecessary computations, especially when the states change slowly. In this paper, the SOH is first estimated and the remaining useful life is predicted by the LS-EKF. Then, the estimated SOH is used as the initial battery capacity for SOC estimation and prediction. The SOH and SOC estimation and prediction are calculated repeatedly in the whole battery service life. The proposed method is verified with the application to the capacity degradation of the Lithium-ion battery. The results show that the LS-EKF-based algorithm has a good performance in SOH and SOC estimation and prediction in terms of accuracy and computation cost.