Topic
Stress corrosion cracking
About: Stress corrosion cracking is a research topic. Over the lifetime, 11340 publications have been published within this topic receiving 138157 citations.
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TL;DR: In this article, the progress of Mg enrichment at grain boundaries was measured for increasing thermal-treatment times, using auger electron spectroscopy (AES) of grain boundaries exposed by fracture within the spectrometer and by analytical electron microscopy of thin foils.
Abstract: The corrosion and stress corrosion cracking (SCC) susceptibility of an Al-Mg alloy, AA5083, has been shown to depend on the precipitation of the Mg-rich β phase, (Al3Mg2), but not the enrichment of elemental Mg at grain boundaries to an enrichment ratio of 1.4. These results were determined by measuring the progress of Mg enrichment at grain boundaries, for increasing thermal-treatment times, using auger electron spectroscopy (AES) of grain boundaries exposed by fracture within the spectrometer and by analytical electron microscopy (AEM) of thin foils. The progress of the β phase precipitation was followed by AEM and scanning electron microscopy (SEM), for the same thermal-treatment times. The lack of a Mg-segregation effect on SCC was demonstrated by results obtained with X-ray photoelectron spectroscopy (XPS) analysis of Mg-implanted Al following in-situ electrochemical tests and SCC tests, while the dominance of β phase precipitation was demonstrated by electrochemical analysis and SCC testing. Crack-growth tests of alloy AA5083 demonstrated faster cracking at potentials anodic to the open circuit potential (OCP) with no increase at potentials cathodic to the OCP.
189 citations
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01 Jan 1970
TL;DR: In this article, it was pointed out that despite all that we may know about the materials science and mechanics of fracture on a macroscopic scale, we know little about the atomistics of fracture in the absence of environmental interactions and even less when embrittlement phe nomena such as those described above are involved.
Abstract: It is now more than 100 years since certain detrimental effects on the ductility of iron were first associated with the presence of hydrogen. Not only is hydrogen embrittlement still a major industri al problem, but it is safe to say that in a mechanistic sense we still do not know what hydrogen (but not nitrogen or oxygen, for example) does on an atomic scale to induce this degradation. The same applies to other examples of environmentally-induced fracture: what is it about the ubiquitous chloride ion that induces premature catastrophic fracture (stress corrosion cracking) of ordinarily ductile austenitic stainless steels? Why, moreover, are halide ions troublesome but the nitrate or sulfate anions not deleterious to such stainless steels? Likewise, why are some solid metals embrit tled catastrophically by same liquid metals (liquid metal embrit tlement) - copper and aluminum, for example, are embrittled by liquid mercury. In short, despite all that we may know about the materials science and mechanics of fracture on a macroscopic scale, we know little about the atomistics of fracture in the absence of environmental interactions and even less when embrittlement phe nomena such as those described above are involved. On the other hand, it is interesting to note that physical chemists and surface chemists also have interests in the same kinds of interactions that occur on an atomic scale when metals such as nickel or platinum are used, for example, as catalysts for chemical reactions."
187 citations
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TL;DR: In this paper, a mechanism for stress corrosion cracking (SCC) is developed from simple metallurgical principles and assuming that high surface mobility is present in the process, and an equation is found for crack velocity as a function of surface mobility and stress concentration at the tip of the crack.
183 citations
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TL;DR: In this paper, surface enhancement by low plasticity burnishing (LPB) was used to eliminate or reduce the surface tensile stresses necessary for corrosion fatigue failure in AA7075-T6, without alteration of environment, material or component design.
182 citations
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TL;DR: In this article, the influence of s-phase on the behavior of duplex stainless steels was evaluated using two tests: double loop electrochemical potentiodynamic reactivation (DLEPR) and slow strain rate test.
181 citations