Stress corrosion cracking

About: Stress corrosion cracking is a research topic. Over the lifetime, 11340 publications have been published within this topic receiving 138157 citations.

Compaction of a Rock Fracture Moderated by Competing Roles of Stress Corrosion and Pressure Solution

Abstract: Unusually rapid closure of stressed fractures, observed in the initial stages of loading and at low temperatures, is examined using models for subcritical crack growth and pressure solution. The model for stress corrosion examines tensile stress concentrations induced at the Hertzian contact of propping fracture asperities, and mediates fracture growth according to a kinetic rate law. Conversely, pressure solution is described by the rate-limiting process of dissolution, resulting from the elevated stresses realized at the propping asperity contact. Both models are capable of following the observed compaction of fractures in novaculite. However, closure rates predicted for stress corrosion cracking are orders of magnitudes faster than those predicted for pressure dissolution. For consistent kinetic parameters, predictions from stress corrosion better replicate experimental observations, especially in the short-term and at low temperature when mechanical effects are anticipated to dominate. Rates and magnitudes of both stress corrosion and pressure solution are dependent on stresses exerted over propping asperities. Rates of closure due to stress corrosion cracking are shown to be always higher than for pressure solution, except where stress corrosion ceases as contact areas grow, and local stresses drop below an activation threshold. A simple rate law is apparent for the progress of fracture closure, defined in terms of a constant and an exponent applied to the test duration. For current experimental observations, this rate law is shown to replicate early progress data, and shows promise to define the evolution of transport properties of fractures over extended durations.

Influence of metallurgical variables on sensitisation kinetics in austenitic stainless steels

Abstract: Austenitic stainless steels are the most favoured construction materials for various components required in chemical, petrochemical, fertiliser and nuclear industries. However, these steels are prone to sensitisation. In the sensitised condition, the steels are quite susceptible to intergranular corrosion and intergranular stress corrosion cracking in chloride and caustic environments resulting in the premature failure of the fabricated components during precommissioning and service periods. The topic of sensitisation has been of interest in studies worldwide. The studies included mechanism of sensitisation, test methods, data generation, and influence of several variables and protection methods. This article covers a review of important contributions to this topic with special emphasis on the influence of metallurgical variables. The present state of understanding is discussed in the following areas: mechanisms, test methods, sensitisation diagrams, influence of chemical composition, cold work and grain size, low temperature sensitisation, modelling and laser surface treatment. The need for further investigation in certain areas is highlighted.

Corrosion of Magnesium and its Alloys

Abstract: Magnesium alloys generally have a fairly good corrosion resistance, but as the most electrochemically active engineering materials, they require corrosion protective measures if they are used in aggressive environments and/or in contact with other materials. Another large concern is stress corrosion cracking. The combination of mechanical stresses and corrosive attack can promote the initiation and growth of cracks which may result in abrupt failure without preceding plastic deformation. After a basic introduction to magnesium and magnesium processing, the major corrosion problems and their mechanisms are discussed in this chapter. This is followed by a summary of corrosion prevention strategies and examples of typical applications.

Mechanistic and fractographic aspects of stress corrosion cracking

Abstract: Basic aspects of stress-corrosion cracking (SCC) in metallic materials are outlined, followed by a summary of the numerous mechanisms that have been proposed for SCC. The characteristics of transgranular and intergranular SCC in model systems, e.g. pure metal and single-phase alloy single crystals and bi-crystals under testing conditions that facilitate discrimination between mechanisms, are then described. The applicability of the various proposed mechanisms, such as those based on dissolution, hydrogen embrittlement, film-induced cleavage, and adsorption, are discussed in detail for these systems. Mechanisms of SCC in complex commercial alloys are then considered in the light of these studies on model systems.