Superheating

About: Superheating is a research topic. Over the lifetime, 4675 publications have been published within this topic receiving 86256 citations.

Phase behaviour of metastable water

Abstract: THE metastable extension of the phase diagram of liquid water exhibits rich features that manifest themselves in the equilibrium properties of water. For example, the density maximum at 4 °C and the minimum in the isothermal compressibility at 46 °C are thought to reflect the presence of singularities in the behaviour of thermodynamic quantities occurring in the supercooled region1 2. The 'stability–limit conjecture'3–5 suggests that these thermodynamic anomalies arise from a single limit of mechanical stability (spinodal line), originating at the liquid–gas critical point, which determines the limit of both superheating at high temperatures and supercooling at low temperatures. Here we present a comprehensive series of molecular dynamics simulations which suggest that, instead, the supercooling anomalies are caused by a newly identified critical point, above which the two metastable amorphous phases of ice (previously shown to be separated by a line of first-order transitions6,7) become indistinguishable. The two amorphous ice phases are thus incorporated into our understanding of the liquid state, providing a more complete picture of the metastable and stable behaviour of water.

Relation between inelastic deformability and thermal expansion of glass in its annealing range

Abstract: In accordance with experience concerning the behavior of glass at temperatures within its annealing range, an equation is proposed which relates the various extraordinary heat effects to the inelastic deformability and to the degree of superheating or undercooling. By using this equation in connection with the thermal-expansion curves of a glass within its annealing range, certain constants that are related to the coefficient of viscosity and its changes with temperature and the degree of superheating or undercooling have been determined with reasonable results. Such results make it possible to estimate the inelastic deformability of a glass in its various conditions at all annealing temperatures and are therefore valuable in connection with problems that are encountered in the process of annealing glass. The apparent success achieved in applying the proposed equation to experimental data suggests that the concepts underlying this equation are fundamental and must be considered in any theory concerning the constitution of glass or that of any other extremely viscous liquid.

Hydrodynamic Aspects of Boiling Heat Transfer

Abstract: A study concerned with the determination of the limiting hydrodynamic conditions which characterize nucleate and transitional boiling was conducted. The critical heat flux and the minimum heat flux are derived from these hydrodynamic limits. Results of investigations of nucleate boilin g are discussed and the theory of bubble growth is extended to include the effect of non-uniform temperature fields. An equation is derived for the product bubble diameter times frequency of bubble emission, and data showing that the diameter of nucleating cavities can he related to the heat flux density and superheat difference are presented. (J.R.D.)

On the Size Range of Active Nucleation Cavities on a Heating Surface

Abstract: The importance of surfare condition on nucleate boiling has long been recognized. It has also been known that only cavities of a narrow size range can be active nucleation sites. In order to define the size range of active cavities as a function of wall temperature or heat flux, a model is proposed. The model pictures a bubble nucleus at a site enveloped by a warm liquid. The nucleus will begin to grow into a bubble only when the surrounding liquid is sufficiently superheated. The time required for the liquid to attain this superheat is called the waiting period. The transfer of heat from the superheated liquid into the bubble is considered to be a transient conduction process. A cavity is considered effective only if the waiting period is finite. This criterion gives the limiting sizes of effective cavities. The equations show that maximum and minimum sizes of effective cavities are functions of subcooling, pressure of the system, physical properties, and the thickness of the superheated liquid layer. Comparison of theoretical prediction with experimental data from several sources was made. The fluids considered were ether, pentane, and water, with water under various degrees of subcooling. The theory did predict the incipience of boiling and size range of cavities successfully.