Topic
Supporting electrolyte
About: Supporting electrolyte is a research topic. Over the lifetime, 5011 publications have been published within this topic receiving 104172 citations.
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TL;DR: In this paper, the rate constants corrected for both ion-pair formation and the double layer effect cannot be described by classical theories of heterogeneous electron transfer, and it is shown that the dynamic dielectric properties of the solvent, described by the dielectrics relaxation time, influence the rate of the heterogeneous charge transfer.
55 citations
TL;DR: In this article, an inexpensive, abundant electroactive organic molecule, 3,4-Dihydroxy-9,10-anthraquinone-2-sulfonic acid (ARS), is proposed to serve as the redox active material in the negative side of flow batteries.
55 citations
TL;DR: The copolymerization of indole and 3,4-ethylenedioxythiophene (EDOT) was achieved electrochemically in acetonitrile containing lithium perchlorate as supporting electrolyte by direct anodic oxidation of the monomer mixtures on platinum and stainless steel electrodes as mentioned in this paper.
Abstract: The copolymerization of indole and 3,4-ethylenedioxythiophene (EDOT) was achieved electrochemically in acetonitrile containing lithium perchlorate as supporting electrolyte by direct anodic oxidation of the monomer mixtures on platinum and stainless steel electrodes. As-formed copolymers own both the advantages of polyindole (PIn) and poly (3,4-ethylenedioxythiophene) (PEDOT), i.e., good thermal stability, good electrochemical behavior, high conductivity and excellent ambient stability. The structure and morphology of the copolymer were investigated by UV-vis, infrared spectroscopy, thermal analysis and scanning electron microscopy (SEM), respectively.
55 citations
TL;DR: In this paper, the interfacial behavior of electrodes fabricated from carbon film resistors of 2 and 20 Ω in supporting electrolyte solutions of varying pH used in electroanalytical experiments has been characterized by electrochemical impedance spectroscopy with complementary cyclic voltammetric experiments.
Abstract: The interfacial behavior of electrodes fabricated from carbon film resistors of 2 and 20 Ω in supporting electrolyte solutions of varying pH used in electroanalytical experiments has been characterized by electrochemical impedance spectroscopy with complementary cyclic voltammetric experiments. Equivalent circuits are proposed to fit the experimental data and the influence of electrode pretreatment has also been investigated.
55 citations
TL;DR: In this paper, the properties of iron electrode in CO2-saturated sodium chloride supporting electrolyte were investigated by cyclic voltammetry of static and rde-Ferrovac electrode in the potential region from −1.1 to −0.3 V (nhe).
55 citations