Topic
Supporting electrolyte
About: Supporting electrolyte is a research topic. Over the lifetime, 5011 publications have been published within this topic receiving 104172 citations.
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TL;DR: In this paper, the adsorption of chloride ion on gold electrodes in 0.2 M H2SO4 was studied and it was shown that adsorbed chloride causes an increase in the amount of soluble gold produced during the anodic and cathodic parts of a potential cycle at the electrode.
45 citations
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TL;DR: In this paper, polarographic and cyclic voltammetric studies on the reduction of iron(II) complexes with bidentate imine ligands were carried out in acetonitrile solutions with 0,8 M tetraethyl ammonium perchlorate as supporting electrolyte.
45 citations
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TL;DR: The highly regioselective anodic monofluorination of 2-substituted 1,3-oxathiolan-5-ones was successfully carried out using a novel supporting electrolyte, Et(4)NF.4HF, while use of a conventional support electrolyte resulted in no formation or extremely low yields of the fluorinated products.
Abstract: The highly regioselective anodic monofluorination of 2-substituted 1,3-oxathiolan-5-ones was successfully carried out using a novel supporting electrolyte, Et(4)NF.4HF, while use of a conventional supporting electrolyte, Et(3)N.3HF, resulted in no formation or extremely low yields of the fluorinated products.
45 citations
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TL;DR: In this article, the authors presented a systematic study of the nucleation effect and growth mechanism of ZnO nanostructures from electrolyte mixed with different concentration of the Zn(NO 3 ) 2 ·6H 2 O and KCl by cathodic electrochemical deposition.
44 citations
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TL;DR: In this article, the electrochemical properties of C60/Pd films were investigated under multicyclic scans in an acetonitrile/toluene (1:4, v/v) mixture containing fullerene C60 and palladium(II) acetate trimer as the film precursors and tetra(n-butyl)ammonium perchlorate as supporting electrolyte.
Abstract: Cyclic voltammetric studies of the electrochemical formation and redox properties of C60/Pd films are reported. Films used in this work are generated under multicyclic scans in an acetonitrile/toluene (1:4, v/v) mixture containing fullerene C60 and palladium(II) acetate trimer as the film precursors and tetra(n-butyl)ammonium perchlorate as supporting electrolyte. The structure and electrochemical properties of the deposited layers depend on the relative concentrations of the precursors (C60 and {Pd(OAc)2}3) present in the growth solution. In the presence of excess palladium(II) acetate trimer, palladium, as well as the redox active film, is deposited, as shown by electrochemical studies of the behavior of the modified electrodes toward hydrogen evolution and palladium oxidation in aqueous acidic solution. At very negative potentials, all of the films decompose which is presumed to be due to the repulsive interaction between negatively charged C60 centers and mechanical strain induced by the incorporation...
44 citations