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Supporting electrolyte
About: Supporting electrolyte is a research topic. Over the lifetime, 5011 publications have been published within this topic receiving 104172 citations.
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TL;DR: An electroactive hybrid film composed of amorphous α-zirconium phosphate and polyaniline (α-ZrP/PANI) is controllably synthesized on carbon nanotubes (CNTs) modified Au electrodes in aqueous solution by cyclic voltammetry method as discussed by the authors.
42 citations
TL;DR: The growth inhibition assay with Escherichia coli cells showed that the toxicity of CEX solution decreased along the electrochemical treatment due to the rupture of the β-lactam ring of the antibiotic.
42 citations
TL;DR: In this paper, cyclic voltammograms of pyrrole monomer and polypyrrole films prepared potentiostatically at 1.0 V versus an Ag/AgCl electrode have been examined.
Abstract: Cyclic voltammograms of pyrrole monomer and polypyrrole films prepared potentiostatically at 1.0 V versus an Ag/AgCl electrode have been examined. The insulating natural fibers, such as cotton, silk, and wool become electrically conducting when they are subjected to electrical treatment in the polymerizing solution of pyrrole in acetonitrile containing p-toluenesulfonic acid as a supporting electrolyte. The weight gain and the electrical conductivity of the fibers increase with the time of electrolysis and impressed current levels. The conductivities are in the range of 0.2 to 15 s/cm and dependent on the nature of the fibers. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 64: 1073–1077, 1997
42 citations
TL;DR: In this paper, a two-phase mixture of soybean oil in a water/t-butanol solvent containing tetraethylammoniump-toluenesulfonate as the supporting electrolyte was determined.
Abstract: Soybean oil has been hydrogenated electrocatalytically at a moderate temperature, without an external supply of pressurized H2 gas. In the electrocatalytic reaction scheme, atomic hydrogen is produced on an active Raney nickel powder cathode surface by the electrochemical reduction of water molecules from the electrolytic solution. Adsorbed hydrogen then reacts with an oil’s triglycerides to form a hydrogenated product. Experiments were carried out at 70°C with a flow-through electrochemical reactor operating in a batch recycle mode. The reaction medium was a two-phase mixture of soybean oil in a water/t-butanol solvent containing tetraethylammoniump-toluenesulfonate as the supporting electrolyte. In all experiments the reaction was allowed to continue for sufficient time to synthesize a brush hydrogenation product. The effects of oil content, applied current, solvent composition, and supporting electrolyte concentration on the efficiency of hydrogen addition to the oil and on the chemical properties of the hydrogenated oil product were determined. The electrohydrogenated oil is characterized by a high stearic acid content and a low percentage of totaltrans isomers, as compared to that produced in a traditional hydrogenation process.
42 citations
TL;DR: In this paper, the authors investigated the oscillatory behavior in the kinetics of formic acid electrooxidation on Pt(100) in 1 mM HClO4 solution and found that once the individual reactions in the dual path mechanism reach steady state the oscillations vanish.
42 citations