Topic
Supporting electrolyte
About: Supporting electrolyte is a research topic. Over the lifetime, 5011 publications have been published within this topic receiving 104172 citations.
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TL;DR: In this paper, constant potential reduction was conducted to improve the Cr(VI) removal capacity of magnetite, and the influence of pH, potential and supporting electrolytes including KNO3, KCl, and K2SO4 on the adsorption capacity was also investigated.
106 citations
TL;DR: Electrochemical studies indicate that the adsorbed Co(II) complex on the surface of mercury is the active catalyst for the reduction of protons to dihydrogen.
Abstract: The macrocyclic cobalt hexaamines [Co(trans-diammac)]3+ and [Co(cis-diammac)]3+ (diammac = 6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine) are capable of reducing the overpotential for hydrogen evolution on a mercury cathode in aqueous solution. Protons are reduced in a catalytic process involving reoxidation of the CoII species to its parent CoIII complex. The cycle is robust at neutral pH with no decomposition of catalyst. The stability of the [Co(trans-diammac)]2+ and [Co(cis-diammac)]2+ complexes depends on the pH of the solution and the coordinating properties of the supporting electrolyte. Electrochemical studies indicate that the adsorbed CoII complex on the surface of mercury is the active catalyst for the reduction of protons to dihydrogen.
105 citations
TL;DR: In this article, the diffusion coefficients of both ferrocene and ferrocenium (Fc +) in acetonitrile containing 0.1 M tetra-n-butylammoniumperchlorate (TBAPF6) or 0. 1 M tetrasn-methanehexafluorophosphate (TBPF6), were determined using the technique of double potential step chronoamperometry at a microdisk electrode.
105 citations
TL;DR: In this article, a technique has been developed for the rapid analysis of samples injected into a streaming supporting electrolyte in small volumes, where the peak area of the voltammetric signal is proportional to the amount of electroactive material injected.
104 citations
TL;DR: In this paper, an efficient paired electrosynthesis involving C-H functionalization and subsequent C-S and C-N bond formation for the assembly of valuable 3-amino-2-thiocyanato-α,β-unsaturated carbonyl derivatives has been developed.
104 citations