Topic
Supporting electrolyte
About: Supporting electrolyte is a research topic. Over the lifetime, 5011 publications have been published within this topic receiving 104172 citations.
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TL;DR: A catalyst- and supporting electrolyte-free method for electrochemical dehydrogenative C-S bond formation in continuous flow has been developed and clearly improves the reported methods for the synthesis of benzothiazoles.
Abstract: A catalyst- and supporting electrolyte-free method for
electrochemical dehydrogenative C–S bond formation in continuous
flow has been developed. A broad range of N‑ arylthioamides have
been converted to the corresponding benzothiazoles in good to
excellent yields and with high current efficiencies. This transformation
is achieved using only electricity and laboratory grade solvent,
avoiding degassing or the use of inert atmosphere. This work
highlights three advantages of electrochemistry in flow, which is (i) a
supporting electrolyte-free reaction, (ii) an easy scale‑ up of the
reaction without the need for a larger reactor and, (iii) the important
and effective impact of having a good mixing of the reaction mixture,
which can be achieved effectively with the use of flow systems. This
clearly improves the reported methods for the synthesis of
benzothiazoles.
93 citations
TL;DR: The most satisfactory methods for the determination of the pzc are capacitance, static friction, immersion, and tension vibration methods as discussed by the authors, which are the capacitance and static friction between surfaces in solution.
93 citations
TL;DR: The first molal hydrolysis quotient of aluminum(III) was measured potentiometrically from 25 to 125°C at 25° intervals at ionic strengths of 0.1, 0.3, 1.0 and 5 mol · kg−1 with sodium chloride as the supporting electrolyte as mentioned in this paper.
93 citations
TL;DR: In this article, it was shown that heteropolytungstate and heteropolymolybdate anions spontaneously adsorb from aqueous solutions onto mercury, gold, pyrolytic graphite and glassy carbon electrodes.
92 citations
TL;DR: In this paper, the steadystate transport-limited voltammetry of ions has been modelled in the presence of excess supporting electrolyte and in its total absence, and the results show that the IR drop is small.
92 citations