Surface modification

About: Surface modification is a research topic. Over the lifetime, 35544 publications have been published within this topic receiving 859567 citations.

Surface modification of Sylgard-184 poly(dimethyl siloxane) networks by ultraviolet and ultraviolet/ozone treatment.

Abstract: We report on the surface modification of Sylgard-184 poly(dimethyl siloxane) (PDMS) networks by ultraviolet (UV) radiation and ultraviolet/ozone (UVO) treatment. The effects of the UV light wavelength and ambient conditions on the surface properties of Sylgard-184 are probed using a battery of experimental probes, including static contact angle measurements, Fourier transform infrared spectroscopy, near-edge X-ray absorption fine structure, and X-ray reflectivity. Our results reveal that when exposed to UV, the PDMS macromolecules in the surface region of Sylgard-184 undergo chain scission, involving both the main chain backbone and the side groups. The radicals formed during this process recombine and form a network whose wetting properties are similar to those of a UV-modified model PDMS. In contrast to the UV radiation, the UVO treatment causes very significant changes in the surface and near-surface structure of Sylgard-184. Specifically, the molecular oxygen and ozone created during the UVO process interact with the UV-modified specimen. As a result of these interactions, the surface of the sample contains a large number of hydrophilic (mainly -OH) groups. In addition, the material density within the first approximately 5 nm reaches about 50% of that of pure silica. A major conclusion that can be drawn from the results and analysis described in this work is that the presence of the silica fillers in Sylgard-184 does not alter the surface properties of the UVO- and UV-modified Sylgard-184.

Effect of fiber surface treatment on the fiber-matrix bond strength of natural fiber reinforced composites

Abstract: The interfacial shear strength (IFSS) between natural fibers and a thermoplastic matrix has been improved by the morphological and silane chemical modification of the fiber surface. An alkaline treatment was used to enhance both the matrix fiber wetting and the chemical surface modification in order to improve the physicochemical interactions at the fiber–matrix interphase. For characterization of the mechanical properties of such interphase, a modification of the micromechanical techniques commonly used in the characterization of the IFSS for circular-cross-section smooth fibers is proposed. The relationships developed for circular fibers were modified to incorporate the natural fiber perimeter instead of an equivalent fiber diameter. From the micromechanical test's results it was found that both surface modifications, preimpregnation and chemical, improves the fiber–matrix IFSS. Finally, the results obtained from the single fiber fragmentation test seem to better agree with the effective mechanical properties measured for the laminated material than those obtained with the pull out test.

Surface Restructuring of Nanoparticles: An Efficient Route for Ligand−Metal Oxide Crosstalk

Abstract: Surface modification of nanocrystalline metal oxide particles with enediol ligands was found to result in altered optical properties of nanoparticles. The surface modification results in a red shift of the semiconductor absorption compared to unmodified nanocrystallites. The optical shift is correlated to the dipole moment of the Ti−ligand complexes at the particle surface and decreases with the ligand size. The binding was found to be exclusively characteristic of colloids in the nanocrystalline domain(<20 nm). X-ray near-edge structure measurements at Ti K edge indicate that in this size domain the surface Ti atoms adjust their coordination environment to form undercoordinated sites. These five-coordinated defect sites are the source of novel enhanced and selective reactivity of the nanoparticle toward bidentate ligand binding as observed using IR spectroscopy. Enediol ligands have the optimal geometry for chelating surface Ti atoms, resulting in a five-membered ring coordination complex and restored si...

Covalent surface modification of oxide surfaces.

Abstract: The modification of surfaces by the deposition of a robust overlayer provides an excellent handle with which to tune the properties of a bulk substrate to those of interest. Such control over the surface properties becomes increasingly important with the continuing efforts at down-sizing the active components in optoelectronic devices, and the corresponding increase in the surface area/volume ratio. Relevant properties to tune include the degree to which a surface is wetted by water or oil. Analogously, for biosensing applications there is an increasing interest in so-called “romantic surfaces”: surfaces that repel all biological entities, apart from one, to which it binds strongly. Such systems require both long lasting and highly specific tuning of the surface properties. This Review presents one approach to obtain robust surface modifications of the surface of oxides, namely the covalent attachment of monolayers.