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Surface modification

About: Surface modification is a research topic. Over the lifetime, 35544 publications have been published within this topic receiving 859567 citations.


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Journal ArticleDOI
TL;DR: In this article, the formation and modification of polycatecholamines; how they adhere to surfaces; and the chemical, physical, and electronic properties of the resultant materials are investigated.
Abstract: Polydopamine and related polycatecholamines can be easily deposited onto almost any surface from mild, aqueous solution. This results in durable, nanoscale coatings that exhibit high biocompatibility and have useful chemical and electronic properties. Additionally, these materials can be readily chemically and physically modified, and consequently, they are used extensively for surface modification. This review investigates the formation and modification of polycatecholamines; how they adhere to surfaces; and the chemical, physical, and electronic properties of the resultant materials. There is also an exploration of the extraordinary array of applications in which these fascinating materials are employed.

252 citations

Journal ArticleDOI
TL;DR: Post-synthesis functionalization methods, such as the one presented here, maximize the density of nanomaterials at the membrane surface and may provide a more efficient route for fabricating diverse array of reactive nanocomposite membranes.
Abstract: Ultrafiltration (UF) membranes perform critical pre-treatment functions in advanced water treatment processes. In operational systems, however, biofouling decreases membrane performance and increases the frequency and cost of chemical cleaning. The present work demonstrates a novel technique for covalently or ionically tethering antimicrobial nanoparticles to the surface of UF membranes. Silver nanoparticles (AgNPs) encapsulated in positively charged polyethyleneimine (PEI) were reacted with an oxygen plasma modified polysulfone UF membrane with and without 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrochloride (EDC) present. The nucleophilic primary amines of the PEI react with the electrophilic carboxyl groups on the UF membrane surface to form electrostatic and covalent bonds. The irreversible modification process imparts significant antimicrobial activity to the membrane surface. Post-synthesis functionalization methods, such as the one presented here, maximize the density of nanomaterials at th...

252 citations

Journal ArticleDOI
TL;DR: In this article, the effect of surface modification on mechanical properties was evaluated by tensile and impact tests under controlled conditions, and it was concluded that the enhancement of mechanical properties after coupling agent modification could be attributed to the formation of chemical bonds between the cellulose and the epoxy coupled with the coupling agent.
Abstract: Bamboo cellulose fibers were treated with NaOH aqueous solution and silane coupling agent, respectively, before they were applied into epoxy composites. The effect of surface modification on mechanical properties was evaluated by tensile and impact tests under controlled conditions. Compared with the untreated cellulose filled epoxy composites, the NaOH solution treatment increased the tensile strength by 34% and elongation at break by 31%. While silane coupling agent treatment produced 71% enhancement in tensile strength and 53% increase in elongation at break. The scanning electron microscopy (SEM) was used to observe the surface feature of the cellulose fibers and the tensile fractures as well as cryo-fractures of the composites. The Fourier transform infrared (FTIR) was employed to analyze the chemical structure of the cellulose fibers before and after modifications. The results indicated different mechanisms for the two modifications of cellulose. The NaOH solution partly dissolved the lignin and amorphous cellulose, which resulting in splitting the fibers into smaller size. This led to easier permeating into the gaps of the fibers for epoxy resin (EP) oligmer and forming effective interfacial adhesion. Based on the emergence of Si–O–C and Si–O–Si on the cellulose surface, it was concluded that the enhancement of mechanical properties after coupling agent modification could be ascribed to the formation of chemical bonds between the cellulose and the epoxy coupled with the coupling agent.

251 citations

Journal ArticleDOI
TL;DR: In this article, a unified model is presented to account for crater and subwavelength ripple formation based on a synergy of electron excitation and capillary wave solidification, and details of the surface morphology attained are elaborated as a function of the imposed conditions, and results are tested against experimental data.
Abstract: An investigation of ultrashort pulsed laser--induced surface modification due to conditions that result in a superheated melted liquid layer and material evaporation are considered. To describe the surface modification occurring after cooling and resolidification of the melted layer and understand the underlying physical fundamental mechanisms, a unified model is presented to account for crater and subwavelength ripple formation based on a synergy of electron excitation and capillary wave solidification. The proposed theoretical framework aims to address the laser--material interaction in subablation conditions and thus the minimal mass removal in combination with a hydrodynamics-based scenario of the crater creation and ripple formation following surface irradiation with single and multiple pulses, respectively. The development of the periodic structures is attributed to the interference of the incident wave with a surface plasmon wave. Details of the surface morphology attained are elaborated as a function of the imposed conditions, and results are tested against experimental data.

251 citations

Journal ArticleDOI
TL;DR: In this paper, three kinds of Co3O4 catalysts with different concentrations of surface oxygen vacancies were successfully synthesized through a solvothermal and subsequent thermolysis method, and they exhibited the best performance for formaldehyde oxidation due to their larger specific surface area, higher low-temperature reducibility and abundant active surface oxygen species.

251 citations


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Performance
Metrics
No. of papers in the topic in previous years
YearPapers
20232,530
20225,209
20211,961
20202,217
20192,313
20182,263