Topic
Surface plasmon resonance
About: Surface plasmon resonance is a research topic. Over the lifetime, 24909 publications have been published within this topic receiving 810976 citations. The topic is also known as: Surface plasmon resonance & SPR (technology).
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TL;DR: In this article, the optical response of surface plasmon resonance (SPR) sensors based on colloidal metal nanoparticles using extended Mie theory is modeled using the particle adsorption layer, the surrounding medium as well as particle-particle and particle-substrate electromagnetic coupling effects.
Abstract: We model the optical response of surface plasmon resonance (SPR) sensors based on colloidal metal nanoparticles using extended Mie theory. The theoretical description includes the particle adsorption layer, the surrounding medium as well as particle–particle and particle–substrate electromagnetic coupling effects. We obtain quantitative agreement with recently reported experimental results on gold nanoparticle SPR sensors, indicating the possibility to perform accurate a priori estimates of detector sensitivity for different particle sizes and compositions in a variety of electromagnetic environments. The possibility to increase sensitivity by using non-spherical silver particles as SPR sensors is discussed.
171 citations
TL;DR: The concept of plasmonic engineering in designing and synthesizing PENs for biomedical applications is introduced, recent examples of biomedically functional PENS are given, and the issues and future prospects of P ENs for practical applications in bioscience, biotechnology, and medicine are discussed.
Abstract: The localized surface plasmon resonance of metal nanoparticles is the collective oscillation of electrons on particle surface, induced by incident light, and is a particle composition-, morphology-, and coupling-dependent property. Plasmonic engineering deals with highly precise formation of the targeted nanostructures with targeted plasmonic properties (e.g., electromagnetic field distribution and enhancement) via controlled synthetic, assembling, and atomic/molecular tuning strategies. These plasmonically engineered nanoprobes (PENs) have a variety of unique and beneficial physical, chemical, and biological properties, including optical signal enhancement, catalytic, and local temperature-tuning photothermal properties. In particular, for biomedical applications, there are many useful properties from PENs including LSPR-based sensing, surface-enhanced Raman scattering, metal-enhanced fluorescence, dark-field light-scattering, metal-mediated fluorescence resonance energy transfer, photothermal effect, ph...
171 citations
TL;DR: A sensitive SPR sensor for detecting small molecules is designed that possesses a good sensitivity and a high selectivity for adenosine and may offer a new direction in designing high-performance SPR biosensors for sensitive and selective detection of a wide spectrum of small molecules.
Abstract: Small molecules are difficult to detect by conventional SPR technique directly because the changes in the refractive index resulting from the binding processes of small biomolecules are often small. In order to extend the application of SPR biosensor in detecting a small molecule, we combine the advantage of aptamer technique with the amplifying effect of Au nanoparticles to design a sensitive SPR sensor for detecting small molecules. The principle of this sensor is based on surface inhibition detection. The aptamer is first immobilized on SPR gold film with its ss-DNA structure. The aptamer possessing this structure can be hybridized with Au nanoparticles-tagged complementary ss-DNA and result in a large change of SPR signal. However, the aptamer will change its structure from ss-DNA to tertiary structure after adenosine is added to the SPR cell. The aptamer possessing tertiary structure could not hybridize with Au nanoparticles-tagged complementary ss-DNA. Thus, the change of SPR signal resulted in the ...
170 citations
TL;DR: In this paper, a multispectral polarization sensitive midinfrared dots-in-a-well photodetector utilizing surface-plasmonic resonant elements, with tailorable frequency response and polarization selectivity, was demonstrated.
Abstract: We demonstrate a multispectral polarization sensitive midinfrared dots-in-a-well photodetector utilizing surface-plasmonic resonant elements, with tailorable frequency response and polarization selectivity. The resonant responsivity of the surface-plasmon detector shows an enhancement of up to five times that of an unpatterned control detector. As the plasmonic resonator involves only surface patterning of the top metal contact, this method is independent of light-absorbing material and can easily be integrated with current focal plane array processing for imaging applications.
170 citations
TL;DR: The photoelectrochemical charging of Au-NPs in the Au-CdS NP array is employed to develop a SPR sensor for acetylcholine esterase inhibitors, and indicates that 4.2 electrons are associated with each Au-nanoparticle under steady-state irradiation.
Abstract: The photoelectrochemical charging of Au-nanoparticles (NP) in a Au-nanoparticle/CdS-nanoparticle array assembled on a Au-coated glass surface is followed by means of surface plasmon resonance (SPR) spectroscopy upon continuous irradiation of the sample. The charging of the Au-NPs results in the enhanced coupling between the localized surface plasmon of the Au-NP and the surface plasmon of the bulk surface, leading to a shift in the plasmon angle. The charging effect of the Au-NPs is supported by concomitant electrochemical experiments in the dark. Analysis of the results indicates that ca. 4.2 electrons are associated with each Au-nanoparticle under steady-state irradiation. The photoelectrochemical charging effect of the Au-NPs in the Au-CdS NP array is employed to develop a SPR sensor for acetylcholine esterase inhibitors.
170 citations