Showing papers on "Surface roughness published in 2014"

Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process

Abstract: Hybrid organic/inorganic perovskites (e.g., CH3NH3PbI3) as light absorbers are promising players in the field of third-generation photovoltaics. Here we demonstrate a low-temperature vapor-assisted solution process to construct polycrystalline perovskite thin films with full surface coverage, small surface roughness, and grain size up to microscale. Solar cells based on the as-prepared films achieve high power conversion efficiency of 12.1%, so far the highest efficiency based on CH3NH3PbI3 with the planar heterojunction configuration. This method provides a simple approach to perovskite film preparation and paves the way for high reproducibility of films and devices. The underlying kinetic and thermodynamic parameters regarding the perovskite film growth are discussed as well.

Experimental investigation of FDM process for improvement of mechanical properties and production cost

Abstract: Purpose – The mechanical properties and surface finish of functional parts are important consideration in rapid prototyping, and the selection of proper parameters is essential to improve manufacturing solutions. The purpose of this paper is to describe how parts manufactured by fused deposition modelling (FDM), with different part orientations and raster angles, were examined experimentally and evaluated to achieve the desired properties of the parts while shortening the manufacturing times due to maintenance costs. Design/methodology/approach – For this purpose, five different raster angles (0°, 30°, 45°, 60° and 90°) for three part orientations (horizontal, vertical and perpendicular) have been manufactured by the FDM method and tested for surface roughness, tensile strength and flexural strength. Also, behaviour of the mechanical properties was clarified with scanning electron microscopy images of fracture surfaces. Findings – The research results suggest that the orientation has a more significant in...

Contact between rough surfaces and a criterion for macroscopic adhesion.

Abstract: At the molecular scale, there are strong attractive interactions between surfaces, yet few macroscopic surfaces are sticky. Extensive simulations of contact by adhesive surfaces with roughness on nanometer to micrometer scales are used to determine how roughness reduces the area where atoms contact and thus weakens adhesion. The material properties, adhesive strength, and roughness parameters are varied by orders of magnitude. In all cases, the area of atomic contact is initially proportional to the load. The prefactor rises linearly with adhesive strength for weak attractions. Above a threshold adhesive strength, the prefactor changes sign, the surfaces become sticky, and a finite force is required to separate them. A parameter-free analytic theory is presented that describes changes in these numerical results over up to five orders of magnitude in load. It relates the threshold adhesive strength to roughness and material properties, explaining why most macroscopic surfaces do not stick. The numerical results are qualitatively and quantitatively inconsistent with classical theories based on the Greenwood−Williamson approach that neglect the range of adhesion and do not include asperity interactions.

On the Fractal Dimension of Rough Surfaces

Abstract: Most natural surfaces and surfaces of engineering interest, e.g., polished or sand blasted surfaces, are self affine fractal over a wide range of length scales, with the fractal dimension \(D_\mathrm{f} = 2.15 \pm 0.15\). We give several examples which illustrate this and a simple argument, based on surface fragility, for why the fractal dimension usually is \(<\)2.3. A kinetic model of sand blasting is presented, which gives surface topographies and surface roughness power spectra in good agreement with experiments.

Study of Factors Governing Oil–Water Separation Process Using TiO2 Films Prepared by Spray Deposition of Nanoparticle Dispersions

Abstract: Surfaces which possess extraordinary water attraction or repellency depend on surface energy, surface chemistry, and nano- and microscale surface roughness. Synergistic superhydrophilic-underwater superoleophobic surfaces were fabricated by spray deposition of nanostructured TiO2 on stainless steel mesh substrates. The coated meshes were then used to study gravity driven oil–water separation, where only the water from the oil–water mixture is allowed to permeate through the mesh. Oil–water separation efficiencies of up to 99% could be achieved through the coated mesh of pore sizes 50 and 100 μm, compared to no separation at all, that was observed in the case of uncoated meshes of the same material and pore sizes. An adsorbed water on the TiO2 coated surface, formation of a water-film between the wires that form the mesh and the underwater superoleophobicity of the structured surface are the key factors that contribute to the enhanced efficiency observed in oil–water separation. The nature of the oil–water...

Superhydrophobic nanocomposite surface topography and ice adhesion.

Abstract: A method to reduce the surface roughness of a spray-casted polyurethane/silica/fluoroacrylic superhydrophobic nanocomposite coating was demonstrated. By changing the main slurry carrier fluid, fluoropolymer medium, surface pretreatment, and spray parameters, we achieved arithmetic surface roughness values of 8.7, 2.7, and 1.6 μm on three test surfaces. The three surfaces displayed superhydrophobic performance with modest variations in skewness and kurtosis. The arithmetic roughness level of 1.6 μm is the smoothest superhydrophobic surface yet produced with these spray-based techniques. These three nanocomposite surfaces, along with a polished aluminum surface, were impacted with a supercooled water spray in icing conditions, and after ice accretion occurred, each was subjected to a pressurized tensile test to measure ice-adhesion. All three superhydrophobic surfaces showed lower ice adhesion than that of the polished aluminum surface. Interestingly, the intermediate roughness surface yielded the best perf...

Enhanced surface flashover strength in vacuum of polymethylmethacrylate by surface modification using atmospheric-pressure dielectric barrier discharge

Abstract: Polymer materials, such as polymethylmethacrylate (PMMA), are widely used as insulators in vacuum. The insulating performance of a high-voltage vacuum system is mainly limited by surface flashover of the insulators rather than bulk breakdown. Non-thermal plasmas are an efficient method to modify the chemical and physical properties of polymer material surfaces, and enhance the surface insulating performance. In this letter, an atmospheric-pressure dielectric barrier discharge is used to treat the PMMA surface to improve the surface flashover strength in vacuum. Experimental results indicate that the plasma treatment method using Ar and CF4 (10:1) as the working gas can etch the PMMA surface, introduce fluoride groups to the surface, and then alter the surface characteristics of the PMMA. The increase in the surface roughness can introduce physical traps that can capture free electrons, and the fluorination can enhance the charge capturing ability. The increase in the surface roughness and the introduction of the fluoride groups can enhance the PMMA hydrophobic ability, improve the charge capturing ability, decrease the secondary electron emission yield, increase the surface resistance, and improve the surface flashover voltage in vacuum.

The effects of cooling conditions on surface integrity in machining of Ti6Al4V alloy

Abstract: This paper presents results from a comparative study of machining of Ti6Al4V alloy under dry, minimal quality lubrication, and cryogenic cooling conditions using coated tools at varying cutting speeds and feed rates. The influence of the cooling conditions on surface integrity and the product performance was studied in terms of surface roughness, metallurgical conditions, including microstructure, hardness, grain refinement, and phase transformation of the machined product. Results show that cooling conditions affect surface integrity of the product signifying the benefits of cryogenic cooling in improving the overall product performance.

Theory of adhesion: role of surface roughness.

Abstract: We discuss how surface roughness influences the adhesion between elastic solids. We introduce a Tabor number which depends on the length scale or magnification, and which gives information about the nature of the adhesion at different length scales. We consider two limiting cases relevant for (a) elastically hard solids with weak (or long ranged) adhesive interaction (DMT-limit) and (b) elastically soft solids with strong (or short ranged) adhesive interaction (JKR-limit). For the former cases we study the nature of the adhesion using different adhesive force laws (F ∼ u−n, n = 1.5–4, where u is the wall-wall separation). In general, adhesion may switch from DMT-like at short length scales to JKR-like at large (macroscopic) length scale. We compare the theory predictions to results of exact numerical simulations and find good agreement between theory and simulation results.

Cutting performance and wear mechanism of nanoscale and microscale textured Al2O3/TiC ceramic tools in dry cutting of hardened steel

Abstract: Nanoscale and microscale textures with different geometrical characteristics were fabricated on the surface of the Al 2 O 3 /TiC ceramic tool, and molybdenum disulfide (MoS 2 ) solid lubricants were burnished into the textures. The effect of the textures on the cutting performance was investigated using the textured self-lubricated tools and conventional tools in dry cutting tests. The tool wear, cutting force, cutting temperature, friction coefficient, surface roughness and chip topography were measured. Results show that the cutting force, cutting temperature, friction coefficient and tool wear of nanoscale and microscale textured self-lubricated tools are significantly reduced compared with the conventional tool, and the developed tool with wavy microscale textures on the rake face is the most effective in improving the cutting performance. The textured self-lubricated tools increase the surface roughness of machined workpiece, while they can reduce the vibration for a stable cutting and produce more uniform surface quality. The chip topography is changed by the textured self-lubricated tools. As a result, the nanoscale and microscale textured self-lubricated tools effectively improve the cutting performance of conventional Al 2 O 3 /TiC ceramic tool, and they are applicable to a stable dry cutting of the hardened steel.

Micro/Nanotribology and Its Applications

Abstract: Atomic force microscopy/friction force microscopy (AFM/FFM) techniques are increasingly used for tribological studies of engineering surfaces at scales, ranging from atomic and molecular to microscales. These techniques have been used to study surface roughness, adhesion, friction, scratching/wear, indentation, detection of material transfer, and boundary lubrication and for nanofabrication/nanomachining purposes. Micro/nanotribological studies of single-crystal silicon, natural diamond, magnetic media (magnetic tapes and disks) and magnetic heads have been conducted. Commonly measured roughness parameters are found to be scale dependent, requiring the need of scale-independent fractal parameters to characterize surface roughness. Measurements of atomic-scale friction of a freshly-cleaved highly-oriented pyrolytic graphite exhibited the same periodicity as that of corresponding topography. However, the peaks in friction and those in corresponding topography were displaced relative to each other. Variations in atomic-scale friction and the observed displacement has been explained by the variations in interatomic forces in the normal and lateral directions. Local variation in microscale friction is found to correspond to the local slope suggesting that a ratchet mechanism is responsible for this variation. Directionality in the friction is observed on both micro- and macro scales which results from the surface preparation and anisotropy in surface roughness. Microscale friction is generally found to be smaller than the macrofriction as there is less ploughing contribution in microscale measurements. Microscale friction is load dependent and friction values increase with an increase in the normal load approaching to the macrofriction at contact stresses higher than the hardness of the softer material. Wear rate for single-crystal silicon is approximately constant for various loads and test durations. However, for magnetic disks with a multilayered thin-film structure, the wear of the diamond like carbon overcoat is catastrophic. Breakdown of thin films can be detected with AFM. Evolution of the wear has also been studied using AFM. Wear is found to be initiated at nono scratches. AFM has been modified to obtain load-displacement curves and for nanoindentation hardness measurements with depth of indentation as low as 1 mm. Scratching and indentation on nanoscales are the powerful ways to screen for adhesion and resistance to deformation of ultrathin fdms. Detection of material transfer on a nanoscale is possible with AFM. Boundary lubrication studies and measurement of lubricant-film thichness with a lateral resolution on a nanoscale have been conducted using AFM. Self-assembled monolyers and chemically-bonded lubricant films with a mobile fraction are superior in wear resistance. Finally, AFM has also shown to be useful for nanofabrication/nanomachining. Friction and wear on micro-and nanoscales have been found to be generally smaller compared to that at macroscales. Therefore, micro/nanotribological studies may help def'me the regimes for ultra-low friction and near zero wear.

Roughness effects on wall-bounded turbulent flowsa)

Abstract: This paper outlines the authors' experimental research in rough-wall-bounded turbulent flows that has spanned the past 15 years. The results show that, in general, roughness effects are confined to the inner layer. In accordance with Townsend's Reynolds number similarity hypothesis, the outer layer is insensitive to surface condition except in the role it plays in setting the length and velocity scales for the outer flow. An exception to this can be two-dimensional roughness which has been observed in some cases to suffer roughness effects far from the wall. However, recent results indicate that similarity also holds for two-dimensional roughness provided the Reynolds number is large, and there is sufficient scale separation between the roughness length scale and the boundary layer thickness. The concept of similarity between smooth- and rough-wall flows is of great practical importance as most computational and analytical modeling tools rely on it either explicitly or implicitly in predicting flows over rough walls. Because of the observed similarity, the roughness function (ΔU+), or shift in the log layer, is a useful way of characterizing the roughness effect on the mean flow and the frictional drag. In the fully rough regime, it is shown that the hydraulic roughness length scale is related to the root-mean-square height (krms) and skewness (sk) of the surface elevation probability density function. On the other hand, the onset of roughness effects is seen to be associated with the largest surface features which are typified by the peak-to-trough height (kt). Roughness function behavior in the transitionally rough regime varies significantly between roughness types. Since no “universal” roughness function exists, no single roughness length scale can characterize all roughness types in all the flow regimes. Despite this, research using roughness with a systematic variation in texture is ongoing in an effort to uncover surface parameters that lead to the variation in the frictional drag behavior witnessed in the transitionally rough regime.

Effect of surface roughness of biomaterials on Staphylococcus epidermidis adhesion.

Abstract: Background: Implant-related infections are caused by adhesion of bacteria to the surface of biomaterials. In this in vitro research, we evaluated the ability of Staphylococcus epidermidis (ATCC35984) to adhere to the surface of solid biomaterials at different levels of roughness below 30 nm Ra and investigated the minimum level of roughness required to promote bacterial adhesion on five kinds of biomaterials: oxidized zirconium-niobium alloy (Oxinium), cobalt-chromium-molybdenum alloy (Co-Cr-Mo), titanium alloy (Ti-6Al-4 V), commercially pure titanium (Cp-Ti) and stainless steel (SUS316L), samples of which were categorized into a fine group and a coarse group according to surface roughness. The test specimens were physically analyzed and the viable bacterial density of the adhered bacteria was quantitatively determined (n=20). Results: The amount of bacteria that adhered to the biomaterials in the coarse group was higher than those in the fine group. Oxinium, Ti-6Al-4 V and SUS316L in particular demonstrated statistically significant differences between the two groups (P<0.05). Of the materials, the Co-Cr-Mo specimens exhibited significantly lower amounts of adhered bacteria than the Ti-6Al-4 V, Cp-Ti and SUS316L specimens in the fine group. Similarly, the Co-Cr-Mo specimens in the coarse group exhibited significantly lower values than the other four materials. Conclusions: These results suggest that minimum level of roughness affecting initial bacterial adherence activity differs according to the type of biomaterial used, and that even a surface roughness of below 30 nm Ra in Oxinium, Ti-6Al-4 V and SUS316L can promote bacterial adhesion. Relative hydrophobic Co-Cr-Mo surfaces were less susceptible to bacterial adherence.

Development of Sol–Gel Icephobic Coatings: Effect of Surface Roughness and Surface Energy

Abstract: Sol–gel coatings with different roughness and surface energy were prepared on glass substrates. Methyl triethoxysilane (MTEOS), 3-Glycidyloxypropyl trimethoxysilane (GLYMO) and fluoroalkylsilane (FAS) were used to obtain a mechanically robust icephobic coating. Different amount of hydrophobic silica nano particles was added as fillers to introduce different roughness and surface energy to the coatings. The microstructure, roughness, and surface energy, together with elemental information and surface chemical state, were investigated at room temperature. The contact angle and sliding angle were measured at different temperatures to correlate the wetting behavior at low temperature with the anti-icing performance. The ice adhesion shear strength was measured inside an ice chamber using a self-designed tester. The factors influencing the ice adhesion were discussed, and the optimum anti-icing performance found in the series of coatings. It was found that lower surface energy leads to lower ice adhesion regar...

Substrate support apparatus having reduced substrate particle generation

Abstract: Embodiments of apparatus for supporting a substrate are disclosed herein In some embodiments, an apparatus for supporting a substrate includes: a support surface; and a plurality of substrate contact elements protruding from the support surface, wherein the plurality of substrate contact elements are formed of a material having a hardness less than or equal to a hardness of silicon, having a low adhesion, having a coefficient of static friction large enough to prevent sliding, having a surface roughness less than or equal to 10 Ra, and that is electrically conductive

Performance of laser polishing in finishing of metallic surfaces

Abstract: Laser polishing is presently regarded as one of the enabling technologies hoped to eventually replace the need for time-consuming and error-prone manual polishing operations which are often required by metallic surfaces. During laser polishing, a thin layer of material is being melted as a result of laser irradiation. Since molten metal is characterized by increased relocation capabilities, laser polishing is generally accompanied by a more or less significant decrease in the surface roughness. The primary objective of this study is to present a comprehensive snapshot of the advancements made over more than one decade with respect to theoretical and experimental investigation of laser polishing technology. However, in addition to the usual review of the state-of-the-art in the field, the study places an increased emphasis on the finishing performance of the process, defined through the perspective of pre- and postpolishing surface roughness. The implementation of this metric with strong practical implications has revealed that under appropriate process parameters, certain classes of metallic materials can reduce their average surface roughness by more than 80 %, possibly to R a = 5 nm. Nonetheless, a more rigorous and fundamental understanding of the intrinsic mechanisms underlying laser polishing remains one of the currently unfulfilled premises toward a wider industrial adoption of the process.

Experimental study of surface quality and damage when drilling unidirectional CFRP composites

Abstract: a b s t r a c t In this study, an experimental investigation on the drilling of unidirectional carbon fiber reinforced plastic (UD-CFRP) composite was conducted using polycrystalline diamond (PCD) tipped eight facet drill. The quality of the drilled hole surface was examined through surface roughness measurements and surface damage by scanning electron microscopy (SEM). It was found that fiber pullout occurred in two specific sectors relative to the angle between the cutting direction and the fiber orientation. The thrust force was highly influenced by the feed rate than the cutting speed and it shows a significant variation throughout the rotation of the drill.