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Surface tension
About: Surface tension is a research topic. Over the lifetime, 25410 publications have been published within this topic receiving 695471 citations.
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TL;DR: In this article, it has been demonstrated that small bubbles in pure liquids can be held stationary or driven downwards by means of a sufficiently strong negative temperature gradient in the vertical direction, due to the stresses resulting from the thermal variation of surface tension at the bubble surface.
Abstract: It has been observed experimentally that small bubbles in pure liquids can be held stationary or driven downwards by means of a sufficiently strong negative temperature gradient in the vertical direction. This effect is demonstrated to be due to the stresses resulting from the thermal variation of surface tension at the bubble surface. The flow field within and around the bubble is derived, and an expression for the magnitude of the temperature gradient required to hold the bubble stationary is obtained. This expression is verified experimentally.
894 citations
01 May 1950
TL;DR: In this paper, a distinction is made between the surface Helmholtz free energy F, and the surface tension γ, which is the tangential stress (force per unit length) in the surface layer; this stress must be balanced either by external forces or by volume stresses in the body.
Abstract: A distinction is made between the surface Helmholtz free energy F, and the surface tension γ. The surface energy is the work necessary to form unit area of surface by a process of division: the surface tension is the tangential stress (force per unit length) in the surface layer; this stress must be balanced either by external forces or by volume stresses in the body. The surface tension of a crystal face is related to the surface free energy by the relation γ=F+A(dF/dA), where A is the area of the surface. For a one-component liquid, surface free energy and tension are equal. For crystals the surface tension is not equal to the surface energy. The standard thermodynamic formulae of surface physics are reviewed, and it is found that the surface free energy appears in the expression for the equilibrium contact angle, and in the Kelvin expression for the excess vapour pressure of small drops, but that the surface tension appears in the expression for the difference in pressure between the two sides of a curved surface. The surface tensions of inert-gas and alkali-halide crystals are calculated from expressions for their surface energies and are found to be negative. The surface tensions of homopolar crystals are zero if it is possible to neglect the interaction between atoms that are not nearest neighbours.
882 citations
TL;DR: The analysis of solubility and Chromatographic data shows that the overall salt effect can be described by the two antagonistic effects of salts on electrostatic and hydrophobic interactions.
850 citations
NEC1
TL;DR: The wetting and capillarity of carbon Nanotubes were studied in detail here and have important implications for the further use of carbon nanotubes in experiments on a nanometer scale.
Abstract: The wetting and capillarity of carbon nanotubes were studied in detail here. Nanotubes are not "super-straws," although they can be wet and filled by substances having low surface tension, such as sulfur, selenium, and cesium, with an upper limit to this tension less than 200 millinewtons per meter. This limit implies that typical pure metals will not be drawn into the inner cavity of nanotubes through capillarity, whereas water and organic solvents will. These results have important implications for the further use of carbon nanotubes in experiments on a nanometer scale.
821 citations
TL;DR: In this article, the impact of a liquid drop of low viscosity on a super-hydrophobic surface was studied. But the authors focused on the effect of the drop on the spread of the liquid on the surface.
Abstract: We first study the impact of a liquid drop of low viscosity on a super-hydrophobic surface. Denoting the drop size and speed as are the liquid density and surface tension). This law is also observed to hold on partially wettable surfaces, provided that liquids of low viscosity (such as water) are used. The law is interpreted as resulting from the effective acceleration experienced by the drop during its impact. Viscous drops are also analysed, allowing us to propose a criterion for predicting if the spreading is limited by capillarity, or by viscosity.
820 citations