Surface tension

About: Surface tension is a research topic. Over the lifetime, 25410 publications have been published within this topic receiving 695471 citations.

Hydrophobicity, surface tension, and zeta potential measurements of glass-reinforced hydroxyapatite composites.

Abstract: Wettability and zeta potential studies were performed to characterize the hydrophobicity, surface tension, and surface charge of P2O5-glass-reinforced hydroxyapatite composites. Quantitative phase analysis was performed by the Rietveld method using GSAS software applied to X-ray diffractograms. Surface charge was assessed by zeta potential measurements. Protein adsorption studies were performed using vitronectin. Contact angles and surface tensions variation with time were determined by the sessile and pendent drop techniques, respectively, using ADSA-P software. The highest (-18.1 mV) and lowest (-28.7 mV) values of zeta potential were found for hydroxyapatite (HA) and beta-tricalcium phosphate (beta-TCP), respectively, with composite materials presenting values in between. All studied bioceramic materials showed similar solid surface tension. For HA and beta-TCP, solid surface tensions of 46.7 and 45.3 mJ/m2, respectively, were obtained, while composites presented intermediate surface tension values. The dispersive component of surface tension was the predominant one for all materials studied. Adhesion work values between the vitronectin solution and HA and beta-TCP were found to be 79.8 and 88.0 mJ/m2, respectively, while the 4.0 wt % glass composites showed slightly lower values than the 2.5 wt % ones. The presence of beta-TCP influenced surface charge, hydrophobicity, and protein adsorption of the glass-reinforced HA composites, and therefore indirectly affected cell-biomaterial interactions.

Adsorption Kinetics of C12E8 at the Air−Water Interface: Adsorption onto a Clean Interface

Abstract: The adsorption of C12E4 onto a fresh air−water interface was investigated by using video-enhanced pendant bubble tensiometry. From the comparison between the equilibrium surface tension data and the theoretical relaxation profiles predicted by the Frumkin adsorption isotherm, the adsorption process was found to be anticooperative. Dynamic surface tension data for C12E4 molecules absorbing onto a freshly created air−water interface for different bulk concentrations were used for the determination of the controlling mechanism and the evaluation of diffusivity. Comparison was made for the entire relaxation period of the surface tension data and the model predictions. It is concluded that the adsorption process is of diffusion control and the diffusion coefficient is 6.4 × 10-6 cm2/s. The lower limit of the adsorption rate constant of C12E4 were obtained from the theoretical simulation. Besides, the pendant bubble, at which the interface had reached the equilibrium state, was expanded rapidly and a relationsh...

Single-wall carbon nanotubes as molecular pressure sensors

Abstract: Specific peaks of the Raman spectrum of single-wall nanotubes shift significantly upon immersion of the tubes in a liquid, relative to the corresponding peaks in air. This observation means that nanotubes are sensitive to molecular forces, and is interpreted by relating the corresponding molecular strain to a thermodynamic parameter, the cohesive energy density (or more loosely, the surface tension) for a range of liquids. We find that nanotubesdeform by a different amount for each liquid.Calibration of this phenomenon enables the construction of a compressive stress–strain curve for carbon nanotubes.

Air cushioning and bubble entrapment in three-dimensional droplet impacts

Abstract: Droplet deformation by air cushioning prior to impact is considered. A model is presented coupling the free-surface deformation of a droplet with the pressure field in the narrow air layer generated as a droplet approaches an impact. The model is based upon the density and viscosity in the air being small compared with those in the liquid. Additionally, the Reynolds number, defined using the droplet radius PI and approach velocity H'(1), is such that lubrication forces dominate in the air layer. In the absence of significant surface tension or compressibility effects, these assumptions lead to coupled nonlinear integro-differential equations describing the evolution of a droplet free surface approaching a solid wall through air, with or without topography.The problem is studied numerically with a boundary-element method in the inviscid droplet coupled with a finite-difference method in the lubricating air. In normal impacts, air cushioning will be shown to deflect the free surface upwards, delaying the moment of touchdown and trapping a bubble. The volume of the bubble is found to be (mu(4/3)(g) R-5/3/rho(4/3)(1) W-1(4/3))(V) over cap, where mu(g) is the gas viscosity and rho(l) is the liquid density and the numerically computed pre-factor (V) over cap = 94.48. Bubble volumes predicted by this relationship are shown to be in good agreement with experimental observations. In oblique impact or impact with a moving surface with sufficient horizontal motion a bubble is not trapped beneath the approaching droplet. In this case, the region of touchdown is initially crescent shaped with air effects accelerating the moment of touchdown.

Energy stability theory for free-surface problems: buoyancy-thermocapillary layers

Abstract: Energy stability theory has been formulated for two-dimensional buoyancy–thermocapillary convection in a layer with a free surface. The theory yields a critical Rayleigh number RE for which R < RE is a sufficient condition for stability of the layer. RE emerges from the variational formulation as an eigenvalue of a nonlinear system of Euler–Lagrange equations. For the case of small capillary number (large mean surface tension) explicit values are obtained for RE. The analogous linear-theory results for this case are obtained in terms of a critical Rayleigh number RL. These are compared. It is found that the existence of the deformable interface can lead to a stabilization relative to the case of a planar interface. This result is explained in physical terms. The energy theory is then generalized to include general flow problems having three-dimensional disturbances, non-Newtonian bulk fluids and general interfacial mechanics such as surface viscosity and elasticity.