Topic
Terpene
About: Terpene is a research topic. Over the lifetime, 2208 publications have been published within this topic receiving 51480 citations. The topic is also known as: terpenes.
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TL;DR: In this paper, samples were obtained of the volatile essential oils of the two types of curry leaf, Murraya koenigii and Pandanus latifolius, which contained mainly terpenes and sesquiterpene hydrocarbons.
50 citations
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TL;DR: In this paper, the fatty acid composition and volatile compounds of selected traditional Macedonian edible oils of several varieties, including sunflower seeds, pumpkin seeds, flax seed, rapeseed and sesame seeds, were analyzed.
50 citations
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TL;DR: This chapter provides an overview of terpenoid hydroxylation reactions catalyzed by bacterial P450s and highlights the achievements made by protein engineering to establish productive hydroxymation processes.
Abstract: Terpenoids comprise a highly diverse group of natural products. In addition to their basic carbon skeleton, they differ from one another in their functional groups. Functional groups attached to the carbon skeleton are the basis of the terpenoids' diverse properties. Further modifications of terpene olefins include the introduction of acyl-, aryl-, or sugar moieties and usually start with oxidations catalyzed by cytochrome P450 monooxygenases (P450s, CYPs). P450s are ubiquitously distributed throughout nature, involved in essential biological pathways such as terpenoid biosynthesis as well as the tailoring of terpenoids and other natural products. Their ability to introduce oxygen into nonactivated C-H bonds is unique and makes P450s very attractive for applications in biotechnology. Especially in the field of terpene oxidation, biotransformation methods emerge as an attractive alternative to classical chemical synthesis. For this reason, microbial P450s depict a highly interesting target for protein engineering approaches in order to increase selectivity and activity, respectively. Microbial P450s have been described to convert industrial and pharmaceutically interesting terpenoids such as ionones, limone, valencene, resin acids, and triterpenes (including steroids) as well as vitamin D3. Highly selective and active mutants have been evolved by applying classical site-directed mutagenesis as well as directed evolution of proteins. As P450s usually depend on electron transfer proteins, mutagenesis has also been applied to improve the interactions between P450s and their respective redox partners. This chapter provides an overview of terpenoid hydroxylation reactions catalyzed by bacterial P450s and highlights the achievements made by protein engineering to establish productive hydroxylation processes.
50 citations
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TL;DR: The effects of long-term water stress on water and terpene contents of the foliage of Cupressus sempervirens were studied in this article, where a great deal of water was lost over 2 months before a remarkable stabilization.
Abstract: The effects of long-term water stress on water and terpene contents of the foliage of Cupressus sempervirens were studied. A great deal of water was lost over 2 months before a remarkable stabilization. A strong decrease of all the classes of terpenes accompanied this dehydration. Mono- and sesquiterpene hydrocarbons and free terpenols were almost entirely metabolized, whereas esters and terpene glycosides rose slightly and remained at a constant level when the water content had stabilized. Although a significant part of the mono- and sesquiterpene hydrocarbons was emitted in the early stage of stress application, the major part was used by the plant in response to the drought conditions.
50 citations
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TL;DR: Feeding trials suggest that the higher quantity of volatile terpenes in the leaves of nitrate-limited plants may better defend these leaves against generalist-feeding insects.
Abstract: Nitrogen-limited plants ofHeterotheca subaxillaris accumulate greater quantities of leaf volatile terpenes than do nitrogen-rich plants. A series of feeding trials were performed to determine if such nitrate-limited plants are better defended against generalist-feeding insect herbivores. Soybean looper (Pseudoplusia includens) larvae were fed leaves fromH. subaxillaris rosettes grown under high and low nitrate supply regimes. Larval consumption, growth, and survival declined as the leaf volatile terpene content increased. Larval consumption and growth were enhanced by higher plant nitrate supply and with increasing leafage. The results suggest that the higher quantity of volatile terpenes in the leaves of nitrate-limited plants may better defend these leaves against generalist-feeding insects.
50 citations