scispace - formally typeset
Search or ask a question
Topic

Tertiary amine

About: Tertiary amine is a research topic. Over the lifetime, 17528 publications have been published within this topic receiving 284817 citations.


Papers
More filters
Journal ArticleDOI
TL;DR: The neurotoxic chemical MPTP is metabolized by rat brain mitochondrial fractions at a rate of 0.91 +/- 0.02 nmoles/mg protein/min, and the major metabolite has been identified as the 1-methyl-4- phenylpyridinium species.

1,111 citations

Journal ArticleDOI
TL;DR: In this article, a new method of arylating NH and OH containing compounds at room temperature with phenylboronic acids and cupric acetate in the presence of a tertiary amine promoter is described.

1,011 citations

Journal ArticleDOI
TL;DR: This tutorial review aims to give a brief overview of the functionalization of C-H bonds and the visible light photoredox catalysis and state the main results obtained in the reactions.
Abstract: The functionalization of C–H bonds and the visible light photoredox catalysis represent two prominent challenges in organic chemistry. In this regard, the combination of visible-light catalysis and C–H bond functionalization adjacent to a tertiary amine has been successfully developed in the past three years. In this tutorial review, we aim to give a brief overview of this issue and state the main results obtained in the reactions.

890 citations

Journal ArticleDOI
TL;DR: Changes in concentrations of HDL cholesterol, VLDL cholesterol, and triglyceride, but not LDL cholesterol, exceed those expected either from weight loss alone or when induced by other selective therapies for low concentrations of LDL cholesterol relating to coronary heart disease.

824 citations

Journal ArticleDOI
TL;DR: A new route involving the intermediacy of TPrA cation radicals (TPrA(*+)) in the generation of Ru(bpy)(3)(2+) was established, based on results of scanning electrochemical microscopy (SECM)-electrogenerated chemiluminescence (ECL) experiments, as well as cyclic voltammetry simulations.
Abstract: The reaction occurring on electrooxidation of Ru(bpy)32+ (bpy = 2,2‘-bipyridine) and tri-n-propylamine (TPrA) leads to the production of Ru(bpy)32+* and light emission. The accepted mechanism of this widely used reaction involves the reaction of Ru(bpy)33+ and a reduced species derived from the free radical of the TPrA. However, this mechanism does not account for many of the observed features of this reaction. A new route involving the intermediacy of TPrA cation radicals (TPrA•+) in the generation of Ru(bpy)32+* was established, based on results of scanning electrochemical microscopy (SECM)-electrogenerated chemiluminescence (ECL) experiments, as well as cyclic voltammetry simulations. A half-life of ∼0.2 ms was estimated for TPrA•+ in neutral aqueous solution. Direct evidence for TPrA•+ in this medium was obtained via flow cell electron spin resonance (ESR) experiments at ∼20 °C. The ESR spectra of the TPrA•+ species consisted of a relatively intense and sharp septet with a splitting of ∼20 G and a g v...

786 citations


Network Information
Related Topics (5)
Alkyl
223.5K papers, 2M citations
93% related
Aryl
95.6K papers, 1.3M citations
90% related
Ligand
67.7K papers, 1.3M citations
89% related
Aqueous solution
189.5K papers, 3.4M citations
88% related
Reagent
60K papers, 1.2M citations
88% related
Performance
Metrics
No. of papers in the topic in previous years
YearPapers
202328
202266
2021252
2020380
2019482
2018467