Topic
Tetrahydrofuran
About: Tetrahydrofuran is a research topic. Over the lifetime, 11778 publications have been published within this topic receiving 158241 citations. The topic is also known as: diethylene oxide & 1,4-epoxybutane.
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TL;DR: The organometallic produced by reaction of trimethylsilylpropargyl bromide with aluminum amalgam in anhydrous tetrahydrofuran condenses readily with aldehydes and ketones to give allenic alcohols resulting from coupling α to the trimethyl silyl substituent.
55 citations
TL;DR: The mono-and bis-(tetramethylphospholyl)uranium complexes [U(tmp)(Cl) 3 (L) 2 ] (tmp = C 4 Me 4 P, L = tetrahydrofuran or L 2 = dimethoxyet) as mentioned in this paper
55 citations
TL;DR: A new π-conjugated charge-transfer-type copolymer of electron-donating thiophene and electron-accepting quinoxaline was prepared by organometallic polycondensation as mentioned in this paper.
Abstract: A new π-conjugated charge-transfer-type copolymer of electron-donating thiophene and electron-accepting quinoxaline was prepared by organometallic polycondensation. The polymer was soluble in organic solvents such as tetrahydrofuran, and showed a UV-vis peak at long wavelengths of 598 nm in chloroform and 629 nm in the film. Its film exhibited a χ (3) peak in the resonance region with a χ (3) value comparable to that of regioregular head-to-tail poly(3-hexylthiophene-2,3-diyl).
55 citations
TL;DR: In this paper, the solvent composition in the first coordination sphere of Eu(III) in water/non-aqueous solvent mixtures was investigated by measuring the luminescence lifetime.
54 citations
TL;DR: In this paper, the solubllltles of ammonla and hydrogen sulflde gases are reported for temperatures ranging from 263 to 333 K in acetone, butanol, chlorobenzene, and ethylene glycol solvents, and for hydrogen sulfide In methanol, tetrahydrofuran, and acetic acid as well.
Abstract: Solubllltles of ammonla and hydrogen sulflde gases are reported for temperatures ranglng from 263 to 333 K In acetone, butanol, chlorobenzene, and ethylene glycol solvents, and for hydrogen sulflde In methanol, tetrahydrofuran, and acetic acid as well. These gases and solvents exhlblt extreme molecular lnteractlons whlch are reflected In the corresponding unusual solubility behavlor. Whereas, among the solvents utllized, the solublllty of hydrogen sulflde Is the lowest In ethylene glycol, the solublllty of ammonla In that solvent Is the hlghest. Thls anomaly and other solublllty behavior are dlscussed.
54 citations