Topic
Thermal barrier coating
About: Thermal barrier coating is a research topic. Over the lifetime, 10199 publications have been published within this topic receiving 192323 citations.
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TL;DR: In this article, the structure, properties, and failure mechanisms of thermal barrier coatings (TBCs) are reviewed, together with a discussion of current limitations and future opportunities.
Abstract: Hundreds of different types of coatings are used to protect a variety of structural engineering materials from corrosion, wear, and erosion, and to provide lubrication and thermal insulation. Of all these, thermal barrier coatings (TBCs) have the most complex structure and must operate in the most demanding high-temperature environment of aircraft and industrial gas-turbine engines. TBCs, which comprise metal and ceramic multilayers, insulate turbine and combustor engine components from the hot gas stream, and improve the durability and energy efficiency of these engines. Improvements in TBCs will require a better understanding of the complex changes in their structure and properties that occur under operating conditions that lead to their failure. The structure, properties, and failure mechanisms of TBCs are herein reviewed, together with a discussion of current limitations and future opportunities.
3,548 citations
TL;DR: In this paper, the authors present relationships between the durability, the governing material properties and salient morphological features of thermal barrier coatings and show that the failure is ultimately connected to the large residual compression in the thermally grown oxide through its roles in amplifying imperfections near the interface.
2,050 citations
TL;DR: In this article, the basic properties of ceramic materials for thermal barrier coatings are summarized, showing that they are more resistant to oxidation, corrosion and wear, as well as being better thermal insulators.
Abstract: This paper summarizes the basic properties of ceramic materials for thermal barrier coatings. Ceramics, in contrast to metals, are often more resistant to oxidation, corrosion and wear, as well as being better thermal insulators. Except yttria stabilized zirconia, other materials such as lanthanum zirconate and rare earth oxides are also promising materials for thermal barrier coatings.
1,789 citations
TL;DR: In this article, a modification of the original theories of Rayleigh and Maxwell permitted the deriva tion of expressions for the effective thermal conductivity of composites consisting of a continuous matrix phase with dilute concentrations of dispersions with spherical, cylin drical and flat plate geometry with a thermal barrier resistance at the interface between the components.
Abstract: A modification of the original theories of Rayleigh and Maxwell permitted the deriva tion of expressions for the effective thermal conductivity of composites consisting of a continuous matrix phase with dilute concentrations of dispersions with spherical, cylin drical and flat plate geometry with a thermal barrier resistance at the interface between the components.
1,185 citations
TL;DR: In this article, it is shown that many of these attractive features of zirconia, especially fracture toughness and strength, are compromised after prolonged exposure to water vapor at intermediate temperatures (∼30°-300°C).
Abstract: Zirconia ceramics have found broad applications in a variety of energy and biomedical applications because of their unusual combination of strength, fracture toughness, ionic conductivity, and low thermal conductivity. These attractive characteristics are largely associated with the stabilization of the tetragonal and cubic phases through alloying with aliovalent ions. The large concentration of vacancies introduced to charge compensate of the aliovalent alloying is responsible for both the exceptionally high ionic conductivity and the unusually low, and temperature independent, thermal conductivity. The high fracture toughness exhibited by many of zirconia ceramics is attributed to the constraint of the tetragonal-to-monoclinic phase transformation and its release during crack propagation. In other zirconia ceramics containing the tetragonal phase, the high fracture toughness is associated with ferroelastic domain switching. However, many of these attractive features of zirconia, especially fracture toughness and strength, are compromised after prolonged exposure to water vapor at intermediate temperatures (∼30°–300°C) in a process referred to as low-temperature degradation (LTD), and initially identified over two decades ago. This is particularly so for zirconia in biomedical applications, such as hip implants and dental restorations. Less well substantiated is the possibility that the same process can also occur in zirconia used in other applications, for instance, zirconia thermal barrier coatings after long exposure at high temperature. Based on experience with the failure of zirconia femoral heads, as well as studies of LTD, it is shown that many of the problems of LTD can be mitigated by the appropriate choice of alloying and/or process control.
1,132 citations