Topic
Thermal decomposition
About: Thermal decomposition is a research topic. Over the lifetime, 34363 publications have been published within this topic receiving 573658 citations. The topic is also known as: thermolysis.
Papers published on a yearly basis
Papers
More filters
TL;DR: This systematic study provides insight into the rational design of NMC-based cathode materials with a desired balance between thermal stability and high energy density.
Abstract: Thermal stability of charged LiNixMnyCozO2 (NMC, with x + y + z = 1, x:y:z = 4:3:3 (NMC433), 5:3:2 (NMC532), 6:2:2 (NMC622), and 8:1:1 (NMC811)) cathode materials is systematically studied using combined in situ time-resolved X-ray diffraction and mass spectroscopy (TR-XRD/MS) techniques upon heating up to 600 °C. The TR-XRD/MS results indicate that the content of Ni, Co, and Mn significantly affects both the structural changes and the oxygen release features during heating: the more Ni and less Co and Mn, the lower the onset temperature of the phase transition (i.e., thermal decomposition) and the larger amount of oxygen release. Interestingly, the NMC532 seems to be the optimized composition to maintain a reasonably good thermal stability, comparable to the low-nickel-content materials (e.g., NMC333 and NMC433), while having a high capacity close to the high-nickel-content materials (e.g., NMC811 and NMC622). The origin of the thermal decomposition of NMC cathode materials was elucidated by the changes ...
653 citations
TL;DR: In this paper, the authors studied the thermal decomposition of Li-ion cells in inert gas and found that the nickel materials are least stable, the manganese compounds are most stable, and that the cobalt compounds show intermediate behaviour.
646 citations
TL;DR: In this paper, a combination of traditional kinetic formal treatments and computer simulation has been made to analyze polydimethylsiloxane (PDMS) thermal degradation, and it was shown that PDMS thermally decomposes to cyclic oligomers through Si-O bond scission in a chain-folded cyclic conformation energetically favored by overlapping of empty silicon d-orbitals with orbitals of oxygen and carbon atoms.
635 citations
TL;DR: In this paper, the thermal decomposition of LiPF 6 /carbonate electrolytes has been investigated by multinuclear nuclear magnetic spectroscopy, gas chromatography with mass selective detection, and size exclusion chromatography.
Abstract: The thermal decomposition of lithium-ion battery electrolytes 1.0 M LiPF 6 in one or more carbonate solvents has been investigated. Electrolytes containing diethyl carbonate (DEC), ethylene carbonate (EC), a 1:1 mixture of EC/dimethyl carbonate (DMC), and a 1:1:1 mixture EC/DMC/DEC have been investigated by multinuclear nuclear magnetic spectroscopy, gas chromatography with mass selective detection, and size exclusion chromatography. Thermal decomposition affords products including: carbon dioxide (CO 2 ), ethylene (CH 2 CH 2 ), dialkylethers (R 2 O), alkyl fluorides (RF), phosphorus oxyfluoride (OPF 3 ), fluorophosphates [OPF 2 OR, OPF(OR) 2 ], fluorophosporic acids [OPF 2 OH, OPF(OH) 2 ], and oligoethylene oxides. The mechanism of decomposition is similar in all LiPF 6 /carbonate electrolytes. Trace protic impurities lead to generation of OPF 2 OR, which autocatalytically decomposes LiPF 6 and carbonates. The presence of DEC leads to the generation of ethylene, while the presnce of EC leads to the generation of capped oligothylene oxides [OPF 2 (OCH 2 CH 2 ) n F].
613 citations
TL;DR: Iron oxide (Fe(3)O(4), magnetite) nanocrystals of 6 to 30 nm with narrow size distributions (sigma = 5-10%) were prepared by the pyrolysis of iron carboxylate salts.
597 citations