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Tilt (optics)

About: Tilt (optics) is a research topic. Over the lifetime, 12892 publications have been published within this topic receiving 130653 citations.


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TL;DR: The 23 Glazer tilt systems described in this article describe octahedral tilting in perovskites have been compared in terms of their A-cation coordination and it is shown that those tilt systems in which all the Acation sites remain crystallographically equivalent are strongly favored, when all A sites are occupied by the same ion.
Abstract: The 23 Glazer tilt systems describing octahedral tilting in perovskites have been investigated. The various tilt systems have been compared in terms of their A-cation coordination and it is shown that those tilt systems in which all the A-cation sites remain crystallographically equivalent are strongly favored, when all the A sites are occupied by the same ion. Calculations based on both ionic and covalent models have been performed to compare the seven equivalent A-site tilt systems. Both methods predict that when the tilt angles become large, the orthorhombic a+b−b− tilt system will result in the lowest energy structure. This tilt system gives the lowest energy structure because it maximizes the number of short A—O interactions. The rhombohedral a−a−a− tilt system gives a structure with a slightly lower Madelung energy, but increased ion–ion repulsions destabilize this structure as the tilt angles increase. Consequently, it is stabilized by highly charged A cations and small to moderate tilt angles. The ideal cubic a0a0a0 tilt system is only observed when stabilized by oversized A cations and/or M—O π-bonding. Tilt systems with nonequivalent A-site environments are observed when at least two A cations with different sizes and/or bonding preferences are present. In these compounds the ratio of large-to-small cations dictates the most stable tilt system.

546 citations

Journal ArticleDOI
TL;DR: Tilt reduces respiratory gating of sympathetic and vagal motoneurone responsiveness to stimulatory inputs for different reasons; during tilt, sympathetic stimulation increases to a level that overwhelms the respiratory gate, andvagal stimulation decreases to alevel below that necessary for maximal respiratory gates to occur.
Abstract: 1. We examined interactions between haemodynamic and autonomic neural oscillations during passive upright tilt, to gain better insight into human autonomic regulatory mechanisms. 2. We recorded the electrocardiogram, finger photoplethysmographic arterial pressure, respiration and peroneal nerve muscle sympathetic activity in nine healthy young adults. Subjects breathed in time with a metronome at 12 breaths min-1 (0.2 Hz) for 5 min each, in supine, and 20, 40, 60, 70 and 80 deg head-up positions. We performed fast Fourier transform (and autoregressive) power spectral analyses and integrated low-frequency (0.05-0.15 Hz) and respiratory-frequency (0. 15-0.5 Hz) spectral powers. 3. Integrated areas of muscle sympathetic bursts and their low- and respiratory-frequency spectral powers increased directly and significantly with the tilt angle. The centre frequency of low-frequency sympathetic oscillations was constant before and during tilt. Sympathetic bursts occurred more commonly during expiration than inspiration at low tilt angles, but occurred equally in expiration and inspiration at high tilt angles. 4. Systolic and diastolic pressures and their low- and respiratory-frequency spectral powers increased, and R-R intervals and their respiratory-frequency spectral power decreased progressively with the tilt angle. Low-frequency R-R interval spectral power did not change. 5. The cross-spectral phase angle between systolic pressures and R-R intervals remained constant and consistently negative at the low frequency, but shifted progressively from positive to negative at the respiratory frequency during tilt. The arterial baroreflex modulus, calculated from low-frequency cross-spectra, decreased at high tilt angles. 6. Our results document changes of baroreflex responses during upright tilt, which may reflect leftward movement of subjects on their arterial pressure sympathetic and vagal response relations. The intensity, but not the centre frequency of low-frequency cardiovascular rhythms, is modulated by the level of arterial baroreceptor input. Tilt reduces respiratory gating of sympathetic and vagal motoneurone responsiveness to stimulatory inputs for different reasons; during tilt, sympathetic stimulation increases to a level that overwhelms the respiratory gate, and vagal stimulation decreases to a level below that necessary for maximal respiratory gating to occur.

492 citations

Journal ArticleDOI
TL;DR: In this paper, a classification of tilt boundaries in cubic crystals is developed that reveals which boundaries to choose in order to study equilibrium faceting or intrinsic grain boundary dislocations (g.b.ds) accommodating a misorientation.
Abstract: The results of the study of symmetrical tilt boundaries, reported in the preceding part I, are generalized to asymmetrical tilt boundaries. A classification of tilt boundaries in cubic crystals is developed that reveals which boundaries to choose in order to study equilibrium faceting or intrinsic grain boundary dislocations (g.b.ds) accommodating a misorientation. Two series of atomistic studies of asymmetrical tilt boundary structures are presented based on this classification. The first is a study of long-period (27 ^ 97) [110] asymmetrical tilt boundaries in aluminium. The aims of this study are to investigate whether these boundaries are composed of fundamental structural elements, in the same way as was found in part I for symmetrical tilt boundaries, and to see if localized, distinct stress fields of edge g.b.ds exist throughout the misorientation range. With use of the results of this study, and the principle of continuity of boundary structure enunciated in part I, the boundary unit representation of a 27 — 1193 asymmetrical tilt boundary is derived as an example. It is generally found that the Burgers vectors of intrinsic secondary g.b.ds in tilt boundaries, based on favoured boundary reference structures, are non-primitive d.s.c. vectors. The reason for this is given and a simple formula is presented to derive the Burgers vectors of such dislocations for any favoured tilt boundary reference structure. It is pointed out that, in general, very low angle {0

486 citations

Journal ArticleDOI
TL;DR: Three-dimensional reconstruction techniques are described that are applicable to data obtained from tilt series with regular tilt geometry, followed by the extensions of these techniques to permit analysis of projection series with randomly spaced tilts.
Abstract: To overcome the radiation damage-induced limitations to the resolution of three-dimensional reconstructions from electron microscopic tilt series, novel reconstruction schemes have been developed that require only a single exposure of the specimen. The tilt series collected with these methods have random projection directions. First, three-dimensional reconstruction techniques are described that are applicable to data obtained from tilt series with regular tilt geometry, followed by the extensions of these techniques to permit analysis of projection series with randomly spaced tilts. The main emphasis is placed on the weighted back-projection methods, which have recently been extended so as to be applicable to random tilt series. Besides a description of the algorithms, the complete procedure for a threedimensional reconstruction from a single-exposure, random conical tilt series is explained, including the determination of the azimuthal angles, the alignment scheme for conical tilt series, the dependence of the achievable resolution on the number of projections for regular conical and single-axis geometries, and the method to calculate the actual resolution of two-dimensional image averages and of three-dimensional reconstructions using the phase residual and Fourier ring correlation criteria. Examples are given of biological specimens to which these three-dimensional reconstruction methods have been applied.

479 citations

Journal ArticleDOI
TL;DR: In this paper, the influence of dust on the performance of photovoltaic (PV) systems has not been given much attention, and the work described here contributes considerably to overcome this deficit.

471 citations


Performance
Metrics
No. of papers in the topic in previous years
YearPapers
202211
2021344
2020427
2019504
2018475
2017417