Topic
Triazene
About: Triazene is a research topic. Over the lifetime, 759 publications have been published within this topic receiving 8714 citations. The topic is also known as: Triazene cleavage & 1-triazene.
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TL;DR: Etudes par voltammetrie cyclique et. as mentioned in this paper a impulsions differentielles des reactions des complexes des metaux de transition avec les derives a des triazene oxyde-1 abreges sous la forme M(RX) p avec M=Cu, p=2, M=Co, Fe, Ru et p=3; R=Et, Ph; X=OMe, Me, H, Cl, CO 2 et No 2
Abstract: Etudes par voltammetrie cyclique et par voltammetrie a impulsions differentielles des reactions des complexes des metaux de transition avec les derives a des triazene oxyde-1 abreges sous la forme M(RX) p avec M=Cu, p=2, M=Co, Fe, Ru et p=3; R=Et, Ph; X=OMe, Me, H, Cl, CO 2 Et, No 2
3 citations
3 citations
01 Jan 2000
TL;DR: A series of modified nucleosides bearing at varied positions of the sugar moiety one 3-aryl-1-triazeno N1-oxide group and a variable number of O-TBDMS groups have been prepared and their cytotoxicities and cytostaticities measured on different cell lines indicate that the O- TBDMS group per se is not cytotoxicity.
Abstract: A series of modified nucleosides bearing at varied positions of the sugar moiety one 3-aryl-1-triazeno N1-oxide group and a variable number of O-TBDMS groups have been prepared and their cytotoxicities and cytostaticities measured on different cell lines. Nucleosides bearing an aryltriazeno N-oxide group and O-TBDMS groups are either devoid of cytotoxicity or possess a selective cytotoxicity. On the other hand, nucleosides bearing one triazeno group and no silyl group are devoid of cytotoxicity and silylated nucleosides without triazeno group are generally either devoid of cytotoxicity or unselectively cytotoxic. This indicates that the O-TBDMS group per se is not cytotoxic.
3 citations
TL;DR: In this paper, the pmr spectra of tridentate triazene 1-oxide ligands were used to determine the equilibrium constants for several equilibria and the structures of mixed-ligand complexes.
3 citations
TL;DR: This rapid, regiospecific synthesis represents as improved method for the preparation of [123I]IPP.
Abstract: The triazene derivative of 15-(p-aminophenyl)pentadecanoic acid, 1-[4-(15-oxopentadecanoyl)phenyl]-3,3-(1,5-pentanediyl)triazene, has been sythesized as a new substrate which is readily converted to 15-(p-iodophenyl)-pentadecanoic acid (IPP). Iodine-123-labeled IPP is prepared in ∼30% yield in less than 30 min by reaction of the triazene with no-carrier added H123I, obtained by decay of123Xe. This rapid, regiospecific synthesis represents as improved method for the preparation of [123I]IPP.
3 citations