Topic
Triazene
About: Triazene is a research topic. Over the lifetime, 759 publications have been published within this topic receiving 8714 citations. The topic is also known as: Triazene cleavage & 1-triazene.
Papers published on a yearly basis
Papers
More filters
TL;DR: In this paper, a series of N-[(N-nitrosoarylamino) methyl] succinimides were synthesized, disclosing their syn and anti equilibria in a state of solution.
Abstract: We have newly synthesized a series of N-[(N-nitrosoarylamino) methyl] succinimides, disclosing their syn and anti equilibria in a state of solution. It has been found that these nitrosoamines are capable of furnishing aromatic diazotates in basic media. By allowing the generating aromatic diazotates to react in situ, azo-couplings and triazene formations have been provided. The nitrosoamines behaved in acidic media to suffer a migration of the nitroso group similarly to the Fischer-Hepp migration.
TL;DR: In this paper, 13 Title compounds of type (III) are prepared and their 1H and 13C NMR spectra are discussed in detail, and their properties are discussed.
Abstract: 13 Title compounds of type (III) are prepared and their 1H and 13C NMR spectra are discussed in detail.
TL;DR: In this paper, the rates of reaction between 3-methyl-1p-tolytriazene and benzoic acid were measured with variation of pressure in chloroform and acetonitrile.
Abstract: Rates of reaction between 3-methyl-1p-tolytriazene and benzoic acid were measured with variation of pressure in chloroform and acetonitrile. Activation volumes were found to be–15 and–4 cm3 mol−1, respectively. The reaction mechanism is discussed in the context of these values.