Topic
Triazene
About: Triazene is a research topic. Over the lifetime, 759 publications have been published within this topic receiving 8714 citations. The topic is also known as: Triazene cleavage & 1-triazene.
Papers published on a yearly basis
Papers
More filters
TL;DR: In this article, 5-Azidotriazoles bearing a thiazole, benzothiazole or pyridine ring at the 4 position were synthesized and thermolyzed at 60°C.
Abstract: 5-Azidotriazoles bearing a thiazole, benzothiazole or pyridine ring at the 4-position were synthesized and thermolyzed at 60°C. Whereas the 5-azido-4-(thiazol-2-yl)triazole 4 decomposed with extrusion of nitrogen and formation of the triazene 5 as the sole reaction product, the 5-azido-4-(benzothiazol-2-yl)triazoles 11a,b furnished mixtures of the triazenes 12a,b and the tetrazoles 14a,b. In the case of the 5-azido-4-(2-pyridyl)triazoles 17a-d, the product distribution was found to depend strongly on the N-1 aryl substituent, favouring the tetrazole 20 by increasing the electron-withdrawing capacity of this group.
01 Jan 2014
TL;DR: In this paper, the synthesis, characterization, and spectrophotometric studies of three mercury (II) complexes of 1-(2-ethoxyphenyl)-3-(4-nitrophenyl) triazene (ENT) are reported.
Abstract: Synthesis, characterization, spectrophotometric studies of three mercury (II) complexes of 1-(2-ethoxyphenyl)-3-(4-nitrophenyl) triazene (ENT) are reported in this article and it was characterized by means of NMR, FT-IR, UV spectroscopy and CHN analysis, then determination of Hg(II) was performed by spectrophotometric determination using chemo metric techniques and new triazen ligand which was prepared by us. The calibration graphs of individual components were linear in the ranges of 1 -5.25 mg·L -1 . The root means square errors of prediction (RMSEP) were 4.4 х10 -3 The proposed method are simple, fast, inexpensive and do not need to any separation or preparation method.
TL;DR: The X-ray crystallographic study of the title compound, C37H41N3O6, at 150 K establishes the N-oxide form of the triazene 1-oxide unit.
Abstract: The X-ray crystallographic study of the title compound, C37H41N3O6, at 150 K establishes the N-oxide form of the triazene 1-oxide unit There is one intramolecular N—H⋯O hydrogen-bonding interaction and the crystal packing is stabilized by one N—H⋯O, three C—H⋯O and three C—H⋯π intermolecular interactions The dihedral angles between pairs of adjacent benzene rings are 149 (3), 563 (1) and 560 (1)°