Topic
Triazene
About: Triazene is a research topic. Over the lifetime, 759 publications have been published within this topic receiving 8714 citations. The topic is also known as: Triazene cleavage & 1-triazene.
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TL;DR: In this paper, the first representatives of a new series of 3-monosubstitued functional derivatives of 1-alkoxy-1-triazene 2-oxides were elaborated.
Abstract: Synthetic procedure to access the first representatives of a new series of 3-monosubstitued functional derivatives of 1-alkoxy-1-triazene 2-oxides, i.e., 1-alkoxy-3-(2-hydroxyethyl)- and 1-alkoxy-3-(2-acetoxyethyl)-1-triazene 2-oxides, were elaborated. 1-Alkoxy-3,3-bis(2-hydroxyethyl)-1-triazene 2-oxides were used to derive 3-(2-acetoxyethyl)-, 3-(2-bromoethyl)- and 3-(2-cyanoethyl)substituted 1-alkoxy-3-(2-acetoxyethyl)-1-triazene 2-oxides.
5 citations
30 Sep 2019
5 citations
TL;DR: 3-(Diphenylphosphino)-1,3-diphenyltriazene Ph2P-NPh-N=NPh was synthesized as mentioned in this paper.
Abstract: 3-(Diphenylphosphino)-1,3-diphenyltriazene Ph2P-NPh-N=NPh was synthesized. The reactions of this compound with bis(cycloocta-1,5-diene)nickel, (cod)2Ni, and nickel(I) bis(triphenylphosphino)bis(trimethylsilyl)amide, (Ph3P)2Ni-N(SiMe3)2, afforded the anionic nickel complex [Ph4P]+[Ni(PhNNNPh)3]− in 15 and 78% yields, respectively.
4 citations
TL;DR: Micelles with poly[2-(diisopropylamino)ethyl methacrylate] (PDPA) cores are the best option for the encapsulation of triazene compounds because they are prepared in absence of organic phase, the drug concentration in the particles is high enough for a therapeutic effect and the responsiveness properties of PDPA is appropriate for practical applications in pH-triggered drug release systems.
4 citations
TL;DR: The first general protocol for the synthesis of unprotected indoles via the title reaction was presented in this paper, which is the basis for the present paper, as well as the present protocol.
Abstract: The first general protocol for the synthesis of unprotected indoles via the title reaction is presented.
4 citations