Topic
Triazene
About: Triazene is a research topic. Over the lifetime, 759 publications have been published within this topic receiving 8714 citations. The topic is also known as: Triazene cleavage & 1-triazene.
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TL;DR: In this article , a new cadmium metal-organic framework (Cd-MOF) has been synthesized by one-pot reaction between 5,5′-(triaz-1-ene-1,3-diyl)diisophthalic acid (H4TEDA) and cadmmium acetate.
3 citations
TL;DR: By combining triazenes with chalcones, 12 novel glycosides are designed and synthesized that might serve as bioactive fragments and lead compounds for developing more potent cytotoxic agents.
Abstract: By combining triazenes with chalcones, we designed and synthesized 12 novel glycosides. The antiproliferative activity of all products was screened using an MTT assay against MGC803 cells and PC-3 cells. Compound $$\mathbf{2b}_{6}$$
displayed more potent antiproliferative activity than dacarbazine. Furthermore, we explored the preliminary structure activity relationship of all target compounds. The derivatives in this work might serve as bioactive fragments and lead compounds for developing more potent cytotoxic agents.
3 citations
3 citations
TL;DR: Schmidbaur and Veith as discussed by the authors showed that BATT adopts a terdentate-planar mode of coordination involving the two triazole cycles and the N2 atom of the triazenido group.
Abstract: The title ligand (hereafter abbreviated as BATTH) is composed of a triazenic and two triazolic functional groups. The synthesis of metal complexes of general formula [M(BATT)X] (M=Cu(II), X=CI, Br, I, SCN, CN; M=Pd(II), X=CI, Br), and of the intermediate product [Cu(BATT)H2O]NO3 are reported. These complexes (including 15N isotopes) are characterized by IR, micro-Raman, NMR (1H,13C) and UV-visible spectroscopies. From these results, it is proposed that BATT-adopts a terdentate-planar mode of coordination involving the two triazole cycles and the N2 atom of the triazenido group, which appears as a new type of coordination for this group. Referee I: H. Schmidbaur Referee II: M. Veith
3 citations
TL;DR: In this paper, the Sandmeyer reaction was used to convert triazenyl triazenes to substituted anilines by reduction or to novel substituted aromatics by a modified sandmeyer reaction.
Abstract: Reaction of (2-, (3-, and (4-bromophenyl)-3,3-(1,4-butanediyl)triazenes (derived from the corresponding 2-, 3-, and 4-bromoanilines) with sec- or tert-butyllithiums gave the corresponding (triazenylaryl)lithiums; these intermediates reacted with a variety of electrophiles to give substituted aryl triazenes. These products cound be converted to substituted anilines by reduction or to novel substituted aromatics by a modified Sandmeyer reaction
3 citations