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Showing papers on "Triphenyl phosphate published in 2016"


Journal ArticleDOI
Zhongkun Du1, Yan Zhang1, Guowei Wang1, Jianbiao Peng1, Zunyao Wang1, Shixiang Gao1 
TL;DR: It is demonstrated that low concentrations of triphenyl phosphate affect normal metabolism and cell cycle and demonstrates that triphensyl phosphate hinders the DNA damage repair system in zebrafish liver cells.
Abstract: Triphenyl phosphate is a high production volume organophosphate flame retardant that has been detected in multiple environmental media at increasing concentrations. The environmental and health risks of triphenyl phosphate have drawn attention because of the multiplex toxicity of this chemical compound. However, few studies have paid close attention to the impacts of triphenyl phosphate on liver metabolism. We investigated hepatic histopathological, metabolomic and transcriptomic responses of zebrafish after exposure to 0.050 mg/L and 0.300 mg/L triphenyl phosphate for 7 days. Metabolomic analysis revealed significant changes in the contents of glucose, UDP-glucose, lactate, succinate, fumarate, choline, acetylcarnitine, and several fatty acids. Transcriptomic analysis revealed that related pathways, such as the glycosphingolipid biosynthesis, PPAR signaling pathway and fatty acid elongation, were significantly affected. These results suggest that triphenyl phosphate exposure markedly disturbs hepatic carbohydrate and lipid metabolism in zebrafish. Moreover, DNA replication, the cell cycle, and non-homologous end-joining and base excision repair were strongly affected, thus indicating that triphenyl phosphate hinders the DNA damage repair system in zebrafish liver cells. The present study provides a systematic analysis of the triphenyl phosphate-induced toxic effects in zebrafish liver and demonstrates that low concentrations of triphenyl phosphate affect normal metabolism and cell cycle.

111 citations


Journal ArticleDOI
TL;DR: All the OPFRs tested affected mitochondrial activity, cell survival, and superoxide production and affect Leydig cells to a greater extent than the brominated flame retardants that they have replaced.

60 citations


Journal ArticleDOI
TL;DR: Interestingly, some compounds showed both estrogenic and anti-estrogenic effects, indicating both receptor-dependant and -independent mechanisms attributed to some of these compounds, in line with other studies.

42 citations


Journal ArticleDOI
TL;DR: In this article, the relationship between flame retardant (FR) chemical structures and their flame retardancy was investigated using FTIR and X-ray photoelectron spectroscopy (XPS).
Abstract: In an attempt to suppress the flammability of unsaturated polyesters (RUP) derived from recycled poly(ethylene terephthalate) (PET) and investigate the relationship between flame retardant (FR) chemical structures and their flame retardancy, RUP was incorporated with four organo-phosphorus FRs; triphenyl phosphate (TPP), aluminum hydrogen phosphonate (AHP), diammonium hydrogen phosphate (DAP), and aluminum diethyl phosphinate (OP). The effects of adding FR with regard to the thermal stability of RUP/FR mixtures were investigated via thermogravimetric analysis (TGA). The chemical structure of FR and its mixtures with RUP were determined via FTIR and X-ray photoelectron spectroscopy (XPS). The morphology of the residual char was investigated using a field emission scanning electron microscope (FE-SEM). Flame retardancies were evaluated by a UL-94 vertical test and limiting oxygen index (LOI) measurements. The results indicated that the presence of FR significantly improved the flame retardancy and thermal stability of RUP. LOI values increased from 20 to 28 and V-0 ratings were obtained with an 8 wt% FR loading for DAP and with a 10 wt% FR loading for OP. In contrast, no ratings were recorded for the mixture containing 30 wt% of TPP or AHP. These findings clearly indicate that the efficiency of a phosphorus-based FR depends on the quantity of phosphorus elements within the FR itself, although interactions of the FR with the target polymer should also be accounted for when determining its effectiveness as a FR.

27 citations


Journal ArticleDOI
TL;DR: Results indicated that the UCT process showed better removal efficiency than that of the AO process, indicating that OPs with high Kow value (e.g. tri(dichloropropyl)phosphate and triphenyl phosphate) are prone to be removed by adsorption on the residual activated sludge.

20 citations


Journal ArticleDOI
TL;DR: In this paper, the effects of Triphenyl Phosphate (TPP) nanoparticles on the styrene polymerization process were investigated, and the results showed that TPP were nanosized spherical particles, distributed homogenously and uniformly in a polystyrene (PS) matrix.
Abstract: Preparation of polystyrene nanocomposites containing flame retardants is difficult to achieve in one step by suspension polymerization. Styrene suspension polymerization was studied to determine the effects of the flame retardant on the polymerization process and properties of polystyrene beads. Triphenyl phosphate (TPP) was used in this work, which can dissolve completely in styrene monomers. The results showed that TPP were nanosized spherical particles, distributed homogenously and uniformly in a polystyrene (PS) matrix, and the formation mechanism of TPP nanoparticles was also investigated. In addition, the effects of TPP on the styrene polymerization process were investigated. With TPP amount increasing, the polymerization time increased significantly; molecular weight of PS nanocomposites also decreased and molecular weight distribution became wide; the particle size distribution (PSD) of the PS nanocomposites became wider than pure PS slightly as the particle size decreased. PS/TPP nanocomposites obtained good flame retardance because of nanodispersed TPP particles in its matrix. In a word, the suspension polymerization method provides a facile approach to prepare PS/TPP nanocomposites with better properties.

8 citations


Journal ArticleDOI
TL;DR: In this paper, an organically modified montmorillonite (Cloisite 15A) was used to prepare FR polystyrene nanocomposites and the flammability properties and thermal stability of FR composites were investigated.
Abstract: Polystyrene was melt blended with a halogen-based flame retardant (FR), hexabromocyclododecane, and a non-halogenated FR, triphenyl phosphate (TPP), in a twin-screw extruder. An organically modified montmorillonite (Cloisite 15A) was used to prepare FR polystyrene nanocomposites. The flammability properties and thermal stability of FR polystyrene composites and nanocomposites were investigated. X-ray diffraction analysis showed that the exfoliation structure of organically modified montmorillonite in polystyrene nanocomposites may be achieved by melt-compounding in a twin-screw extruder. Furthermore, a good dispersion of FRs and nanoparticles of organically modified montmorillonite was observed by energy dispersive X-ray analysis. Thermogravimetric analysis demonstrated that the thermal stability of FR nanocomposites enhanced in the presence of clay nanoparticles and antioxidant. The aim of this study was to reduce the FR level, especially in the brominated FRs. The good results obtained by the limiting oxygen index test showed high-performance flammability properties in the composites containing hexabromocyclododecane and TPP, resulted from the synergy effects between these two FRs. However, in spite of producing high thermal performance polystyrene nanocomposites and dispersing clay nanoparticles efficiently into the polystyrene matrix, the flame retardancy properties were deteriorated in the presence of clay nanoparticles. Therefore, the organically modified clay (Cloisite 15A) was not a good synergic compound to improve the flame retardancy of polystyrene nanocomposites.

7 citations


Patent
11 May 2016
TL;DR: In this article, a composite-flame-retardant modified elastomer flame retardant cable sheathing compound has been proposed to improve the performance of cable-sheathing compound.
Abstract: The invention discloses a composite-flame-retardant modified-elastomer flame-retardant cable sheathing compound. The composite-flame-retardant modified-elastomer flame-retardant cable sheathing compound comprises chlorinated polyethylene, modified SEBS elastomer, linear low-density polyethylene, high-density polyethylene, polytetrafluoroethylene, calcium stearate, glass fibers, nylon, calcium carbonate, mica, nanometer barium sulfate, zinc borate, fatty acid, polypropylene wax, diphenylamine, sulfur, triphenyl phosphate, glycerol triacetate, paraffin, calcium carbonate, antimony trioxide and aluminum hydroxide. According to the flame-retardant cable sheathing compound, the composite-flame-retardant modified elastomer serves as a main material, the elastomer is subjected to effective flame-retardant modification through the comprehensive flame-retardant performance of the composite flame retardant, and therefore the flame-retardant performance of the cable sheathing compound is effectively improved while the comprehensive performance of the cable sheathing compound is improved.

7 citations


Posted Content
01 Aug 2016-viXra
TL;DR: In this article, the impact of bio-field treatment on physicochemical and spectroscopic properties of Triphenyl Phosphate (TPP) was evaluated in two groups i.e. control and treatment.
Abstract: Triphenyl phosphate (TPP) is a triester of phosphoric acid and phenol. It is commonly used as a fire-retarding agent and plasticizer for nitrocellulose and cellulose acetate. The present study was an attempt to evaluate the impact of biofield treatment on physicochemical and spectroscopic properties of TPP. The study was carried out in two groups i.e. control and treatment. The treatment group was subjected to Mr. Trivedi’s biofield treatment. The control and treated samples of TPP were characterized using X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transform infrared (FT-IR), and ultraviolet-visible (UV-Vis) spectroscopy. XRD study revealed the decrease in crystallite size (6.13%) of treated TPP that might be due to presence of strains and increase in atomic displacement from their ideal lattice positions as compared to control sample. DSC thermogram of treated TPP showed the increase in melting temperature (1.5%) and latent heat of fusion (66.34%) with respect to control. TGA analysis showed the loss in weight by 66.79% in control and 47.96% in treated sample. This reduction in percent weight loss suggests the increase of thermal stability in treated sample as compared to control. FT-IR and UV spectroscopic results did not show the alteration in the wavenumber and wavelength of FT-IR and UV spectra, respectively in treated TPP with respect to control. Altogether, the XRD and DSC/TGA results suggest that biofield treatment has the impact on physical and thermal properties of treated TPP.

5 citations


Patent
13 Jan 2016
TL;DR: In this article, an anti-aging cable sheath material which comprises natural rubber, ethylene-propylene-diene monomer, epoxy resin, carboxyl-terminated butadieneacrylonitrile copolymer, acidulation starch, carbon black, modified nano silica, carbon nanofibers, zinc oxide, stearic acid, antiaging agent, polytetrafluoroethylene, adipic acid.
Abstract: The invention discloses an anti-aging cable sheath material which comprises natural rubber, ethylene-propylene-diene monomer, epoxy resin, carboxyl-terminated butadieneacrylonitrile copolymer, acidulation starch, carbon black, modified nano silica, carbon nanofibers, zinc oxide, stearic acid, anti-aging agent, polytetrafluoroethylene, adipic acid, bis(2-(2-butoxyethoxy)ethyl) ester, triphenyl phosphate, sulphur, phenyl isothiocyanate, accelerator CZ, accelerator M, accelerator TMTD, lanthanum glutamate dithiocarbamate and gamma-aminopropyl triethoxysilane. The anti-aging cable sheath material is high in strength, good in aging resistance and long in service life.

4 citations


DOI
16 Dec 2016
TL;DR: Experiments revealed that triphenyl phosphate stimulated pre-adipocyte differentiation to lipid-laden adipocytes at a concentration that disrupted the PPAR signalling network, and provided a regulatory scenario that could lead to weight gain and other symptoms of metabolic syndrome.
Abstract: 1. Abstract Triphenyl phosphate is an organophosphate flame retardant and plasticizer that has been detected in a variety of environmental media and shown to cause weight gain in rats. We hypothesized that triphenyl phosphate would modify the activity of the PPAR: RXR signalling network in a manner that would favor lipid accumulation. Gal4-driven luciferase-based transcription reporter gene assays were used to evaluate the responses of human PPARα: RXRα, PPARγ: RXR α, and the individual receptor subunits, to triphenyl phosphate. Triphenyl phosphate was a potent inhibitor of PPARα: RXRαsignalling. The flame retardant interacted with both the PPARαand RXRαsubunits to inhibit their respective activities at concentrations that were not overtly toxic to the cells. Bioluminescence resonance energy transfer experiments revealed that triphenyl phosphate actually inhibited the dimerization of PPARαand RXRα. In contrast, triphenyl phosphate modestly activated the PPARγ: RXRαreceptor complex. This net activation of the complex was due to strong activation of the PPARγreceptor subunit and modest inhibition of the RXRαsubunit. Further experiments revealed that triphenyl phosphate stimulated pre-adipocyte differentiation to lipid-laden adipocytes at a concentration that disrupted the PPAR signalling network. This dual activity of triphenyl phosphate, as an inhibitor of PPARα: RXRαsignalling and an activator of PPARγ: RXRαsignalling provides a regulatory scenario that could lead to weight gain and other symptoms of metabolic syndrome.

Patent
17 Feb 2016
TL;DR: The halogen-free high-strength high-flame-retardant stone paper is prepared from polyolefin, inorganic packing, halogen free flame retardant, plasticizer triphenyl phosphate, a dispersing agent, a lubricating agent, coupling agent, an antioxidant, a 4A-level molecular sieve powder catalyst.
Abstract: The invention discloses halogen-free high-strength high-flame-retardant stone paper The halogen-free high-strength high-flame-retardant stone paper is prepared from polyolefin, inorganic packing, halogen-free flame retardant, plasticizer triphenyl phosphate, a dispersing agent, a lubricating agent, a coupling agent, an antioxidant, a 4A-level molecular sieve powder catalyst The halogen-free high-strength high-flame-retardant stone paper has both the good mechanical performance and flame retardant performance, the tensile strength can reach up to 94 MPa, the tear strength can reach up to 39 kN/m, the mechanical performance and the flame retardant performance are good, the maximum limit oxygen index reaches 297, the UL-94 perpendicular combustion grade reaches V-0 grade (08mm), and automatic extinguishment can be rapidly achieved after ignition is performed in air; furthermore, all the raw materials of the halogen-free high-strength high-flame-retardant stone paper are free of halogen and environmentally friendly, no toxic gas is generated during ignition, and the halogen-free high-strength high-flame-retardant stone paper is safe, reliable, simple in preparation technology and short in production cycle

Patent
08 Jun 2016
TL;DR: In this paper, a halogen-free flame-retardant modified polyolefin cable sheath material was presented, which has excellent flame retardancy, free of the halogen element, environmentally friendly, free from pollution, high in hardness and good in toughness.
Abstract: The invention discloses a halogen-free flame-retardant modified polyolefin cable sheath material. The material is prepared from modified polyolefin elastomer, polyvinyl chloride, medium-density polyethylene, EVA resin, cellulose acetate, stearic acid, magnesium oxide, calcium stearate, polyethylene glycol, titanium dioxide, an anti-aging agent A, triphenyl phosphate, a cross-linking agent TAIC, 3-aminopropyltrimethoxysilane, an accelerator DM, zinc stearate, dioctyl phthalate, hydroxyl-fluoro silicone oil, tributyl citrate, bauxite powder, calcined clay, limestone powder, paraffin and auxiliaries. The cable sheath material has excellent flame retardancy, free of the halogen element, environmentally friendly, free of pollution, high in hardness and good in toughness.

Patent
12 Oct 2016
TL;DR: In this paper, a computer advertising art design sample surface protection coating material is described, which is composed of chlorinated polyethylene, polydimethylsiloxane, heterogeneous decanol polyoxyethylene ether, isocyanate, propylparaben, ethoxyquin, montmorillonoid, vinyl acetate, toluene diisocyanates, sorbic acid, phenolic resin diisopropanolamine, quartz powder, polyvinyl butyral, acrylic acid, tricresyl phosphate, aluminum hydroxide
Abstract: The invention relates to a computer advertising art design sample surface protection coating material. The material is composed of chlorinated polyethylene, polydimethylsiloxane, heterogeneous decanol polyoxyethylene ether, isocyanate, propylparaben, ethoxyquin, montmorillonoid, vinyl acetate, toluene diisocyanate, sorbic acid, phenolic resin diisopropanolamine, quartz powder, polyvinyl butyral, acrylic acid, tricresyl phosphate, aluminum hydroxide powder, dibasic lead phthalate, polyamide-imide, potassium acetate, tea saponin, 2,2-dipyridyl, tebuconazole, difenoconazole, stearin, octamethylcyclotetrasiloxane, nitrile rubber, triphenyl phosphate, trioctyl trimellitate, zinc borate and epoxidized soybean oil. The material has excellent flame retarding, acid and base resisting, anti-mildew and anti-microbial properties, and product performance is improved.

Patent
21 Dec 2016
TL;DR: A multifunctional lubricating oil additive composed of polychloroprene, polyethylene, triazine resin, polyvinyl acetate emulsion, polyglycerol polyricinoleate, hexamethylphosphorotriamide, coal tar, vanillin, arbutin, acetylspiramycin, sodium lauroyl sarcosinate, a tourmaline powder, molybdenum disilicide powder, a silica powder, vaseline, a cerium oxide powder, sodium humate, a kaolin powder,
Abstract: The invention relates to a multifunctional lubricating oil additive composed of the following components: polychloroprene, polyethylene, triazine resin, a polyvinyl acetate emulsion, polyglycerol polyricinoleate, a polyvinyl acetate emulsion, hexamethylphosphorotriamide, coal tar, vanillin, arbutin, acetylspiramycin, sodium lauroyl sarcosinate, a tourmaline powder, a molybdenum disilicide powder, a silica powder, vaseline, a cerium oxide powder, sodium humate, a kaolin powder, a sodium zirconate powder, trioctyl phosphate, polyacrylonitrile fibers, polythiophene, triphenyl phosphate, N-methyl-2-pyrrolidone, gamma-(2,3-epoxypropoxy)propyl trimethoxy silane, amino silane, benzothiazole, phenoxyphosphoryl dichloride, and sodium benzoate. The product has relatively excellent flame retardant, acid and alkali resistant, mildew proof and antibacterial properties, and improves the product performance.

Patent
13 Jul 2016
TL;DR: In this article, a lignin/polypropylene composite material with a compatibilizer and a plasticizer has been proposed to improve the mechanical properties of the composite material.
Abstract: The invention relates to a lignin/polypropylene composite material, particularly to a lignin/polypropylene composite material prepared through adding a compatibilizer and a plasticizer and having good compatibility. The composite material comprises 100 parts by mass of polypropylene, 10-50 parts by mass of lignin, 0-20 parts by mass of the compatibilizer, 0-10 parts by mass of the plasticizer and 0.1-1 part by mass of a coupling agent. The compatibilizer is maleic anhydride grafted polypropylene the grafting ratio of which is 0.8-1.2%. The plasticizer is one selected from a group comprising triphenyl phosphate, dibutyl phthalate and dioctyl phthalate. Through adding the compatibilizer and the plasticizer, compatibility of a lignin/polypropylene blending system is improved, thus facilitating improvement of mechanical properties of the composite material.

Patent
20 Jan 2016
TL;DR: In this paper, the authors provided a preparation method of triphenyl phosphate using an organic solvent, phosphorus oxychloride is added in a drop-wise mode, meanwhile, a metal catalyst is added, and after a heat preservation reaction, Triphenyl Phosphate is obtained through after-treatment.
Abstract: The invention provides a preparation method of triphenyl phosphate. Firstly, phenol is added to an organic solvent, phosphorus oxychloride is added in a dropwise mode, meanwhile, a metal catalyst is added, and after a heat preservation reaction, triphenyl phosphate is obtained through after-treatment. The preparation method is simple in process step, high in product yield and low in production energy consumption, three-waste emission is greatly reduced, production cost is reduced, the product purity is high, the impurity content is low, and the yield is high.

Patent
01 Feb 2016
TL;DR: A flame-retardant electrolyte composition for enhancing safety of a lithium secondary battery, according to the present invention, comprises: 76.9 to 96.2 wt% of an electrolyte material for a lithium primary battery, 1.0 to 7.7 wt % of a triphenyl phosphate compound, and 2.9to 15.4 wt percent of a fluorinated benzene solvent as discussed by the authors.
Abstract: A flame-retardant electrolyte composition for enhancing safety of a lithium secondary battery, according to the present invention, comprises: 76.9 to 96.2 wt% of an electrolyte material for a lithium secondary battery, 1.0 to 7.7 wt% of a triphenyl phosphate compound, and 2.9 to 15.4 wt% of a fluorinated benzene solvent. The electrolyte material for the lithium secondary battery is a first solvent in which lithium salt is dissolved. The first solvent is one or more solvents selected from the group consisting of ethylene carbonate, propylene carbonate, butylene carbonate, vinylene carbonate, dimethyl carbonate, diethyl carbonate, ethyl methyl carbonate, etc. The triphenyl phosphate compound is a mixture of one or more materials selected from the group consisting of triphenyl phosphate, diphenyl cresyl phosphate, and trifluoride diphenyl phosphate. In the case of existing battery, the shape of the battery changes and an ignition and explosion occur due to high-temperature gas contained inside the battery when the temperature of the existing battery rises by an abnormal operation. However, the electrolyte composition, according to the present invention, has an effect of enhancing safety of the battery since flame retardant additives are added to the electrolyte to lower combustibility of the electrolyte so as to solve the above problems.

Patent
21 Dec 2016
TL;DR: In this article, a coating material for an electric power distribution cabinet is described, which includes polypropylene resin, hydrogenated rosin, acrylate resin, grape seed oil, lavender oil, oleate, palm oil, carbon tetrachloride, silthiopham, 8-hydroxyquinoline copper, dioctadecyl dimethyl ammonium chloride, polyhexamethylene guanidine hydrochloride, granite powder, cobalt naphthenate powder, ash-calcium powder, volcano ash, spinel powder
Abstract: The invention relates to a coating material for an electric power distribution cabinet. The coating material comprises polypropylene resin, hydrogenated rosin, acrylate resin, grape seed oil, lavender oil, oleate, palm oil, carbon tetrachloride, silthiopham, 8-hydroxyquinoline copper, dioctadecyl dimethyl ammonium chloride, polyhexamethylene guanidine hydrochloride, granite powder, cobalt naphthenate powder, ash-calcium powder, volcano ash, spinel powder, sodium polymethylacrylate, lithium tourmaline powder, calcium phosphate powder, triphenyl phosphate, trichloroethyl phosphate, triclofos, ammonium polyphosphate, polyamide imide, methyl acetate, hydroxyethyl methylacrylate, methyl cellulose, dimethylaminoethyl acrylate and maleic anhydride-grafted polyethylene. The coating material provided by the invention has superior flame retardation, acid and alkali resistance, mildew resistance, antibacterial properties and improved performance.

Patent
24 Feb 2016
TL;DR: In this paper, a method for the preparation of an antibiotic finish liquid for fabric is described. But the preparation method comprises steps as follows: (1), 1-2 parts by weight of sodium oleoyl amino fatty acid, 0.9 parts of hydroxyl propyl cellulose, 1.2 parts of water-soluble chitosan and 1.3 parts of sodium hypophosphite are sequentially added to 16 parts by mass of deionized water, and the mixture is stirred uniformly.
Abstract: The invention discloses a preparation method of an antibiotic finish liquid for fabric. The preparation method comprises steps as follows: (1), 1-2 parts by weight of sodium oleoyl amino fatty acid, 0.9 parts by weight of hydroxyl propyl cellulose, 1.2 parts by weight of water-soluble chitosan and 1.3 parts by weight of sodium hypophosphite are sequentially added to 16 parts by mass of deionized water, and the mixture is stirred uniformly ; (2), 1.5 parts by weight of a solanum khassianum extract, 0.8 parts by weight of chlorine dioxide, 1.3 parts by weight of triphenyl phosphate and 2.5 parts by weight of 2,3-dimercapto-1-propanol are added simultaneously, the mixture is stirred continuously until the mixture is uniformly mixed, and the finishing liquid is prepared. The prepared finishing liquid has good hydrophilia and good permeability, and the fabric finished with the finishing liquid has excellent anti-static performance, flame retardancy, mothproof performance, mildewproof performance, and antibacterial performance and high washability and touches soft.

Patent
12 Oct 2016
TL;DR: In this paper, a method for degrading triphenyl phosphate through brevibacillus brevis and application thereof and belongs to the technical field of environment organic pollutant biotreatment.
Abstract: The invention discloses a method for degrading triphenyl phosphate through brevibacillus brevis and application thereof and belongs to the technical field of environment organic pollutant biotreatment. The method specifically comprises the steps that a degradation culture medium with triphenyl phosphate as a unique carbon source is inoculated with the brevibacillus brevis under the condition that the temperature is 30 DEG C; five days after degradation of a constant-temperature shaking table, the concentration of the triphenyl phosphate left in the culture medium is measured through a gas chromatography-mass spectrometer (GC-MS), and in this way, the degrading effect of the brevibacillus brevis on the triphenyl phosphate is analyzed. According to the method, environment suitability of the method is high, and the cost is low; the degradation rate of organophosphorus fire retardant can reach 95.4% five days later. The actual application value is high, and a reference is provided for solving the problem of water organophosphorus fire retardant pollution treatment.

Patent
14 Dec 2016
TL;DR: In this article, an acid-resistant and alkali-resistant nano-silicon dioxide-coated modified sheet aluminum powder pigment was presented. But the pigment was not shown to have the same performance as the one described in this paper.
Abstract: The invention discloses acid-resistant and alkali-resistant nano-silicon dioxide coated modified sheet aluminum powder pigment, which is prepared from the following raw materials in parts by weight: 2 to 2.3 parts of aluminum pigment, 3 to 3.5 parts of TEOS, 4.5 to 5 parts of ammonia water, a proper amount of anhydrous ethanol, 5 to 5.5 parts of distilled water, 0.3 to 0.4 part of nano-cobalt aluminate, 0.2 to 0.3 part of triphenyl phosphate, 0.3 to 0.4 part of nano-ZnWO4, 0.4 to 0.5 part of trifluoroethyl acrylate and 0.03 to 0.04 part of dicumyl peroxide. The acid-resistant and alkali-resistant nano-silicon dioxide coated modified sheet aluminum powder pigment has the advantages that the nano-cobalt aluminate and the triphenyl phosphate are used for performing mixed modification, so the dispersibility of the nano-cobalt aluminate is improved, the surface of the aluminum powder can be coated by the nano-cobalt aluminate uniformly, yellow light is filtered, the brightness of the aluminum powder is improved, and the wear resistance, the acid resistance and the alkali resistance of the aluminum powder are improved.

Patent
20 Apr 2016
TL;DR: In this article, a method for halogen-free flame-retardant high-impact polystyrene is presented, where the halogen free flame-residant consists of phosphate ester, zinc borate and phenolic resin.
Abstract: The invention discloses a preparation method for halogen-free flame-retardant high-impact polystyrene. The halogen-free flame-retardant high-impact polystyrene is prepared from the following components in parts by weight: 100 parts of high-impact polystyrene resin, 1 to 15 parts of a styrene-butadiene-styrene block copolymer, 10 to 30 parts of a halogen-free composite flame retardant, 0.2 to 2.5 parts of a lubricant and 0.3 to 1.6 parts of a stabilizer, wherein the halogen-free composite flame-retardant consists of phosphate ester, zinc borate and phenolic resin according to the weight ratio of phosphate ester to zinc borate to phenolic resin being (10-20):1:(5-10), and the phosphate ester is triphenyl phosphate or dibenzyl phosphate. The halogen-free flame-retardant high-impact polystyrene is higher in flame retardancy, strong in comprehensive mechanical strength, high in melt fluidity, low in production cost, environment-friendly and nontoxic.

Patent
26 Oct 2016
TL;DR: In this paper, a carbon black toughened modified PVC pipe is described, which is made from polyvinyl chloride resin, phenol, a formaldehyde aqueous solution with the content of 8-10%, aluminum hydroxide, an acetic acid aaqueous solution, carbon black, triphenyl phosphate, 2-ethylhexyl acrylate, vinyl chloride, epoxidized butyl oleate, dibenzoyl peroxide, polyethylene, zinc stearate, polymethylene wax, methyltin merc
Abstract: The invention discloses a carbon black toughened modified PVC pipe The carbon black toughened modified PVC pipe is prepared from polyvinyl chloride resin, phenol, a formaldehyde aqueous solution with the content of 8-10%, aluminum hydroxide, an acetic acid aqueous solution with the content of 8-10%, carbon black, triphenyl phosphate, 2-ethylhexyl acrylate, vinyl chloride, epoxidized butyl oleate, dibenzoyl peroxide, polyethylene, zinc stearate, polyethylene wax, methyltin mercaptide, octadecyl imidazoline, polyethylene glycol and a proper amount of deionized water The PVC pipe has high strength, high toughness, good impact resistance, low product ingredient price and large market competitiveness

Patent
12 Oct 2016
TL;DR: In this article, a building material environment-friendly flame-retardant acid-alkaline treatment-resistant coating is described, which is prepared from vermiculite, nitroethane, clove, carnauba wax, benzyl bromide, thifluzamide, PVC resin powder, pearl powder, benzoyl peroxide, dioctyl phthalate, triphenyl phosphate, triethylene glycol di-2-ethylhexoate(triglycol dIOctate), melamine cyanurate, ferroc
Abstract: The invention relates to a building material environment-friendly flame-retardant acid-alkaline-treatment-resistant coating. The coating is prepared from vermiculite, nitroethane, clove, carnauba wax, benzyl bromide, thifluzamide, PVC resin powder, pearl powder, benzoyl peroxide, dioctyl phthalate, triphenyl phosphate, triethylene glycol di-2-ethylhexoate(triglycol dioctate), melamine cyanurate, ferrocene, barium stearate, methyltrimethoxysilane, dioctyl sebacate, bisphenol A diglycidyl ether, metallocene polyethylene, glutaric acid, butantriol, magnesium oxide powder, benzimidazole, diallyl sulfide, sodium lauroyl sarcosine, sodium hydrogen sulfite and sulfur trioxide. The product has excellent flame retardance, acid and alkaline resistance, mildew resistance and antibacterial performance, and the performance of the product is improved.

Patent
16 Nov 2016
TL;DR: In this paper, a flame-retardant acid and alkali resistant coating for metal surface treatment is described, which has superior flame resistance, acid and acid resistance and anti-mildew anti-bacterial performances, and product performances are improved.
Abstract: The invention relates to a flame-retardant acid and alkali resistant coating for metal surface treatment. The flame-retardant acid and alkali resistant coating comprises etidronic acid, naphthenic acid, PVC (polyvinyl chloride) resin powder, modified phenolic resin, methyl silicone resin, bisphenol-F epoxy resin, 10,10'-oxybis-phenoxarsine, 4-hydroxy-4-methyl-2-pentanone, octafluorocyclobutane, butyl hydroxy anisd, chlorfenvinphos, dimethyl ketoxime, bee wax, barium chromate powder, silthiopham, dibutyl sebacate, methanesulfonic acid, polyoxyethylene polyoxy propyl alcohol amidogen ether, butyl benzyl phthalate, triphenyl phosphate, cypermethrin, tributyl citrate, clothianidin, cetyl trimethyl ammonium bromide, chlorothalonil carbendazim, dimethyl triethylene glycol ester, carboxyethyl cellulose, cesium carbonate powder, caprylin, brominated butyl rubber and cerium oxide powder. The flame-retardant acid and alkali resistant coating has superior flame resistance, acid and alkali resistance and anti-mildew anti-bacterial performances, and product performances are improved.

Patent
14 Dec 2016
TL;DR: In this article, an inflame-retardant and antibacterial coating for a digital printing fabric is described, which has excellent flame retardance, acid-alkali resistance, anti-mildew property and anti-bacterial property.
Abstract: The invention relates to an inflame-retardant and antibacterial coating for a digital printing fabric. The inflame-retardant and antibacterial coating is prepared from a folium artemisiae argyi extract, zinc phosphate, zeolite powder, pyridine, sodium fatty acid, butyl stearate, cupric oxalate, crystalline graphite powder, lauryl sodium sulfate, zinc pyrithione, nut oil, 10,10.-oxybisphenoxarsine, a styrene thermoplastic elastomer, butadiene-styrene rubber, hydrogenated nitrile butadiene rubber, trioctyl phosphate, pyromellitic anhydride, triphenyl phosphate, potassium sorbate, menthol, polyester yarn, alumina, zinc sulfate, cottonseed oil, litsea cubeba oil, sldium lauryl sulfate, oleic acid polyoxyethylene ester, petroleum sulfonate, vinyl benzene and cobalt iso-octoate. The product has the excellent flame retardance, acid-alkali resistance, anti-mildew property and anti-bacterial property, and the product properties are improved.

Patent
22 Jun 2016
TL;DR: In this article, a method for preparing halogen-free flame-retardant high-impact polystyrene is presented, which is composed of 10-20 parts by weight of phosphate, zinc borate and phenolic resin, wherein the phosphate is triphenyl phosphate or dimethylphenyl phosphate.
Abstract: The invention discloses a method for preparing halogen-free flame-retardant high-impact polystyrene The halogen-free flame-retardant high-impact polystyrene is prepared from the following components in parts by weight: 100 parts of high-impact polystyrene resin, 1-15 parts of styrene-butadiene-styrene block copolymer, 10-30 parts of halogen-free composite flame retardant, 02-25 parts of lubricant and 03-16 parts of stabilizer The halogen-free composite flame retardant is composed of 10-20 parts by weight of phosphate, 1 part by weight of zinc borate and 5-10 parts by weight of phenolic resin, wherein the phosphate is triphenyl phosphate or dimethylphenyl phosphate The halogen-free flame-retardant high-impact polystyrene has the advantages of favorable flame retardancy, high comprehensive mechanical strength, favorable melt flowability, low production cost, environment friendliness and no toxicity

Patent
21 Sep 2016
TL;DR: In this article, a flame-retardant and anti-corrosive coating for power equipment was proposed, which consists of the following components of melamine copolymer resin, styrene-maleic anhydride copolymers, nitrile rubber powder, polychlorinated biphenyl, ammonium polyphosphate, triphenyl phosphate, zinc hydroxystannate, zinc sulfate, diazolidinyl urea, propiconazole, calcium hypochlorite, sulfadiazine silver, limonene, sodium phosphate
Abstract: The invention relates to a flame-retardant and anti-corrosive coating for power equipment. The flame-retardant and anti-corrosive coating consists of the following components of melamine copolymer resin, styrene-maleic anhydride copolymer, nitrile rubber powder, polychlorinated biphenyl, ammonium polyphosphate, triphenyl phosphate, zinc hydroxystannate, diazolidinyl urea, propiconazole, calcium hypochlorite, sulfadiazine silver, limonene, sodium phosphate, crystalline graphite powder, diaminodiphenylmethane, calcium sulphate dehydrate, zinc fluoride, zirconite powder, aluminum phosphate powder, zinc sulfate, bowlder powder, glass fiber powder, transformer oil, propylene glycol methyl ether acetate, amyl propionate, aminopropyltriethoxysilane, amino silicone oil, amino acid, aminoethylpiperazine, and alkylolamide. The flame-retardant and anti-corrosive coating has the advantages that the flame-retardant, acid and alkali-resistant, mildew-proof and anti-bacterial properties are excellent; the product property is improved.

Patent
21 Dec 2016
TL;DR: In this article, a halogen-free flame retardant PBT material is presented, which is made from 100 parts of PBT resin, 15-25 parts of a halogenic-free composite flame-retardant, 05-5 parts of processing agent and 0.5-010 part of a complex antioxidant, with a weight ratio of (4-6):(1-4):(13-21):( 1-4), polysiloxane serves as the processing agent, and the complex antioxidant is prepared from the antioxidant 1076 and the antioxidant 168
Abstract: The invention discloses a halogen-free flame retardant PBT material The halogen-free flame retardant PBT material is prepared from, by weight, 100 parts of PBT resin, 15-25 parts of a halogen-free composite flame retardant, 05-5 parts of a processing agent and 005-010 part of a complex antioxidant, wherein the halogen-free composite flame retardant is prepared from pentaerythritol diphosphonate melamine salt, melamine cyanurate, aluminum hypophosphite and triphenyl phosphate in the weight ratio of (4-6):(1-4):(13-21):(1-4), polysiloxane serves as the processing agent, and the complex antioxidant is prepared from the antioxidant 1076 and the antioxidant 168 in the weight ratio of (002-003):(004-006) According to the halogen-free flame retardant PBT material, the using amount of a halogen-free composite flame retardant system is small, and the flame retardant effect is good; meanwhile, the comprehensive mechanical performance of the halogen-free flame retardant PBT material is not influenced, and especially the halogen-free flame retardant PBT material has high heat resistance