Topic
Triphenyl phosphate
About: Triphenyl phosphate is a research topic. Over the lifetime, 579 publications have been published within this topic receiving 6681 citations. The topic is also known as: phenyl phosphate & TPP.
Papers published on a yearly basis
Papers
More filters
Patent•
14 Dec 1971TL;DR: In this paper, a Ziegler-type catalyst was used to produce cyclododecatriene-1,5,9 in the presence of a Ti-compound, e.g., Ti (OPrCl)Cl3, an Alcompound and electron-donor compounds containing S and containing P, such as dimethyl sulfoxide and triphenyl phosphate.
Abstract: Crude butadiene-1,3 which is a B-B fraction is subjected to catalytic trimerization to produce cyclododecatriene-1,5,9 in the presence of a Ziegler-type catalyst comprising a Ti-compound, e.g., Ti (OPrCl)Cl3, an Al-compound, e.g., AlEt2Cl, and electron-donor compounds containing S and containing P, e.g., dimethyl sulfoxide and triphenyl phosphate.
17 citations
TL;DR: In this article, the effect of epoxy sorts, mass ratio of OMMT and Epoxy, and the contents of Epoxy/OMMT and TPP on properties of polypropylene (PP) were studied.
Abstract: Epoxy/organophilic montorillonite (Epoxy/OMMT) nanocomposites were prepared by epoxy intercalated into the interlayer of OMMT, and flame retardant polypropylene (PP) was obtained with Epoxy/OMMT nanocomposites and triphenyl phosphate (TPP) mixture as flame retardant agent. The effect of epoxy sorts, mass ratio of OMMT and Epoxy, and the contents of Epoxy/OMMT and TPP on properties of PP were studied. It was found that there is a remarkable synergistic flame retardant effect of novolac epoxy/organophilic montorillonite (NE/OMMT) and TPP on PP. Flame retardant PP with oxygen index (OI) value of 36.5%, peak heat release rate (PHRR) of 654 kW/m2, notched Izod impact strength of 6.93 kJ/m2 and tensile strength of 30.56 MPa was obtained when the mass ratio of OMMT and NE is 5:100, the content of NE/OMMT and TPP is 13.33 and 6.67 wt.%, respectively. The materials were characterized via X-Ray diffraction (XRD), transmission electron microscope (TEM), Fourier transform infrared spectrum (FT-IR), and thermogravimet...
16 citations
16 citations
TL;DR: The 13C n.m.r. spectra of triphenyl phosphite andtriphenyl phosphate showed significant differences in chemical shifts and C-P coupling constants.
Abstract: The 13C n.m.r. spectra of triphenyl phosphite and triphenyl phosphate show significant differences in chemical shifts and C–P coupling constants.
16 citations
TL;DR: Wang et al. as discussed by the authors investigated the presence of tri-OPEs and di-OPE in the atmosphere of an e-waste dismantling park and surrounding area in South China for three consecutive years.
16 citations