Topic
Triphenyl phosphate
About: Triphenyl phosphate is a research topic. Over the lifetime, 579 publications have been published within this topic receiving 6681 citations. The topic is also known as: phenyl phosphate & TPP.
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15 Aug 1995
TL;DR: In this paper, the authors presented a method to obtain the subject pellet comprising polyphenylene ether or polycarbonate resin and a specific phosphate ester, low in load deflection temperature, easy in extrusion molding processing, excellent in handleability, and capable of imparting flame retardancy to the resin materials.
Abstract: PURPOSE:To obtain the subject pellet comprising a polyphenylene ether resin, etc., and a specific phosphate ester, low in load deflection temperature, easy in extrusion molding processing, excellent in handleability, and capable of imparting flame retardancy to the resin materials. CONSTITUTION:This pellet comprises (A) a polyphenylene ether resin or a polycarbonate resin and (B) a phosphate ester of the formula (Q1 to Q4 each is a 1-6C alkyl; R1 to R4 each is H, methyl; (n) is >=1; n1, n2 are each 0-2; m1 to m4 each is 0-3) (e.g. the ester of bisphenol A bound two or more triphenyl phosphate molecules, etc.,) and has a load deflection temperature of 120 deg.C under a flextural stress of 18.5kgf/cm . The pellets are blended with (C) a thermoplastic resin (preferably a styrenic resin) and subsequently melt-kneaded to obtain the flame-resistant resin material.
4 citations
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18 Sep 2013
TL;DR: A triphenyl phosphate modified cable sheathing compound is described in this article, which is prepared from the following raw materials in parts by weight: 70-80 parts of polytetrafluoroethylene, 30-45 parts of PVC (Polyvinyl chloride) resin powder, 1-2.3 parts of silane coupling agent KH580, 0.4-0.6 parts of antioxidant 1135, 1.2-1.
Abstract: The invention discloses a triphenyl phosphate modified cable sheathing compound. The compound is prepared from the following raw materials in parts by weight: 70-80 parts of polytetrafluoroethylene, 30-45 parts of PVC (Polyvinyl Chloride) resin powder, 1-2.3 parts of silane coupling agent KH580, 0.4-0.6 parts of antioxidant 1135, 1.2-1.8 parts of antioxidant 264, 60-80 parts of coated montmorillonoid, 10-20 parts of nanometer calcium carbonate, 1-2 parts of triphenyl phosphate, 1.5-3 parts of barium stearate, 5-7 parts of high-density polyethylene (HDPE), 6-8 parts of polyethylene wax, 1-2 parts of epoxy oleic acid butyl ester, 8-15 parts of magnesium hydroxide, 1-2 parts of sulphur, 1-2 parts of melamine, 2.3-3.5 parts of triphosphate, 1-2 parts of accelerant DM, 2-4 parts of antimonous oxide, 4-8 parts of magnesium hydroxide and 2-4 parts of antioxidant 168.
4 citations
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TL;DR: In this article , a novel microbial consortium ZY1 capable of degrading tricresyl phosphates (TCPs) was isolated, it could quickly degrade 100% of 1 mg/L tri-o-cresyl phosphate (ToCP), tri-p-chesyl phosphate(TpCP) and tri-m-Chesyl Phosphate (TmCP) within 36, 24 and 12 hours separately and intracellular enzymes occupied the dominated role in TCPs biodegradation.
4 citations
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TL;DR: In this article, the interaction between poly(bisphenol A carbonate) (PBAC) and phosphorus compounds such as triphenylphosphine oxide (TPPO),triphenyl phosphate (TPP), and resorcinol bis(diphenyl phosph) (RDP) was clarified.
Abstract: To clarify the interaction between poly(bisphenol A carbonate) (PBAC) and phosphorus compounds such as triphenylphosphine oxide (TPPO), triphenyl phosphate (TPP), and resorcinol bis(diphenyl phosphate) (RDP), PBAC was heated in the presence of these phosphorus compounds at 240 °C for 2 h, and the resulting polymers were analyzed by 1H NMR spectroscopy and gel permeation chromatography. When heated in the presence of TPPO, the PBAC sample decomposed extensively, resulting in a substantial decrease in molecular weight. On the other hand, thermal treatment in the presence of the phosphates increased the molecular weight. In both cases the molecular weight distribution became narrower. Thermal treatment of PBAC in the presence of both TPPO and TPP allowed us to control the molecular weight with a narrower distribution. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1069–1074, 2004
3 citations
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19 Mar 1993
TL;DR: In this paper, the subject adhesive comprising specific PVA and a specified amount of a hydrophobic plasticizer solid at the ordinary temperature, having good cohesive forces at high temperatures and high humidities and good flexibility at low temperatures, used for tapes, labels, etc., used for book making, packaging, etc.
Abstract: PURPOSE:To provide the subject adhesive comprising specific PVA and a specified amount of a hydrophobic plasticizer solid at the ordinary temperature, having good cohesive forces at high temperatures and high humidities and good flexibility at low temperatures, and suitable for tapes, labels, etc., used for book making, packaging, etc. CONSTITUTION:The objective adhesive comprises (A) 100 pts.wt. of PVA having an average polymerization degree of 50-600 (preferably 80-400), a saponification degree of 20-70mol.% (preferably 40-60mol.%, but 20-60mol.% in the case of a modified PVA), and (B) 10-100 pts.wt. (preferably 20-80 pts.wt.) of a hydrophobic plasticizer solid at the ordinary temperature, such as dicyclohexyl phthalate, glyceroyl tribenzoate or triphenyl phosphate.
3 citations