Tungsten carbide

Abstract: Tungsten carbide catalyzes the formation of water from hydrogen and oxygen at room temperature, the reduction of tungsten trioxide by hydrogen in the presence of water, and the isomerization of 2,2-dimethylpropane to 2-methylbutane. This catalytic behavior, which is typical of platinum, is not exhibited at all by tungsten. The surface electronic properties of the latter are therefore modified by carbon in such a way that they resemble those of platinum.

Abstract: Although there have been great advances in the development of cutting tool materials which have significantly improved the machinability of a large number of metallic materials, including cast irons, steels and some high temperature alloys such as nickel-based alloys, no equivalent development has been made for cutting titanium alloys due primarily to their peculiar characteristics. This paper reviews the main problems associated with the machining of titanium as well as tool wear and the mechanisms responsible for tool failure. It was found that the straight tungsten carbide (WC/Co) cutting tools continue to maintain their superiority in almost all machining processes of titanium alloys, whilst CVD coated carbides and ceramics have not replaced cemented carbides due to their reactivity with titanium and their relatively low fracture toughness as well as the poor thermal conductivity of most ceramics. This paper also discusses special machining methods, such as rotary cutting and the use of ledge tools, which have shown some success in the machining of titanium alloys.

Abstract: A systematic study of carbide and nitride additions on the heterogeneous nucleation behavior of supercooled liquid iron was undertaken. It was found that titanium nitride and titanium carbide were very effective in promoting heterogeneous nucleation. These compounds were followed by silicon carbide, zirconium nitride, zirconium carbide, and tungsten carbide in decreasing order of effectiveness. The degree of potency of the nucleation catalysts is explained on the basis of the disregistry between the lattice parameters of the substrate and the nucleating phase. Through the inclusion of planar terms the Turnbull-Vonnegut “linear” disregistry equation was modified to more accurately describe the crystallographic relationship at the interface during heterogeneous nucleation.

Abstract: Cellulose, the most abundant source of biomass, is currently regarded as a promising alternative for fossil fuels as it cannot be digested by human beings and thus its use, unlike corn and starch, will not impose a negative impact on food supplies. One of the most attractive routes for the reaction of cellulose utilization is its direct conversion into useful organic compounds. A recent example of the catalytic conversion of cellulose has been demonstrated by Fukuoka and Dhepe, who utilized Pt/Al2O3 as an effective catalyst to convert cellulose into sugar alcohols (Scheme 1, Route A). The product sugar alcohols can be used as chemicals in their own right or as new starting materials for the production of fuels, as demonstrated by Dumesic and co-workers. 6] Recently, Luo et al. have studied this process further. In their work, the reaction was conducted at elevated temperatures so that water could generate H ions to catalyze the hydrolysis reactions. The subsequent hydrogenation reaction was catalyzed by Ru/C. An increased sugar alcohol yield was obtained, which was attributed to the higher reaction temperatures and the wellknown high efficiency of Ru/C in the hydrogenation reaction. . A disadvantage of the above two studies is the use of precious-metal catalysts. The amount of precious metals needed for the degradation of cellulose was relatively high, 4– 10 mg per gram of cellulose. This is too expensive for the conversion of large quantities of cellulose, even though the solid catalyst could be reused. Therefore, it is highly desirable to develop a less expensive but efficient catalyst to replace precious-metal catalysts in this cellulose degradation process. The carbides of Groups 4–6 metals show catalytic performances similar to those of platinum-group metals in a variety of reactions involving hydrogen. In our previous work, tungsten and molybdenum carbides were found to exhibit excellent performances in the catalytic decomposition of hydrazine, which were comparable with those of expensive iridium catalysts. Tungsten carbides have been used as electrocatalysts because of their platinum-like catalytic behavior, stability in acidic solutions, and resistance to CO poisoning. 18] However, to the best of our knowledge, there have been no attempts so far to utilize metal carbides as catalysts for cellulose conversion. Herein we report the first observation that carbonsupported tungsten carbide (W2C/AC; AC = activated carbon) can effectively catalyze cellulose conversion into polyols (Scheme 1, Route B). More interestingly, when the catalyst is promoted with a small amount of nickel, the yield of polyols, especially ethylene glycol (EG) and sorbitol, can be significantly increased. These Ni-W2C/AC catalysts showed a remarkably higher selectivity for EG formation than Pt/Al2O3 [4] and Ru/C. After 30 minutes at 518 K and 6 MPa H2, the cellulose could be completely converted into polyols and the yield of EG was as high as 61 wt % with a 2% Ni-30% W2C/AC-973 catalyst. This value is the highest yield reported to date. Currently in the petrochemical industry, EG is mainly produced from ethylene via the intermediate ethylene oxide. The global production of EG in 2007 is estimated to be 17.8 million tonnes, an increase of Scheme 1. Catalytic conversion of cellulose into polyols.

Abstract: The performance of a multilayer tungsten carbide tool was described using response surface methodology (RSM) when turning AISI 1045 steel. Cutting tests were performed with constant depth of cut and under dry cutting conditions. The factors investigated were cutting speed, feed and the side cutting edge angle (SCEA) of the cutting edge. The main cutting force, i.e. the tangential force and surface roughness were the response variables investigated. The experimental plan was based on the face centred, central composite design (CCD). The experimental results indicate that the proposed mathematical models suggested could adequately describe the performance indicators within the limits of the factors that are being investigated. The feed is the most significant factor that influences the surface roughness and the tangential force. However, there are other factors that provide secondary contributions to the performance indicators. In the case of surface roughness, the SCEA2 and the interaction of feed and SCEA provides these contributions whilst for tangential force, the SCEA2, the interaction of feed and SCEA; and the cutting speed provides them.