Ultraviolet light

About: Ultraviolet light is a research topic. Over the lifetime, 49494 publications have been published within this topic receiving 843151 citations.

Pyrolysis of Negative Photoresists to Fabricate Carbon Structures for Microelectromechanical Systems and Electrochemical Applications

Abstract: Carbon structures were fabricated by the pyrolysis of photopatterned negative photoresists (SU-8 and photosensitive polyimide) on silicon and fused silica wafers. Results here are compared with those of positive resists published earlier by this group. Negative resist films need exposure to ultraviolet light prior to pyrolysis to produce carbon films. The pyrolysis was carried out in a closed quartz tube furnace in a forming gas (95% N 2 , 5% H 2 ) atmosphere. The pyrolysis process was characterized using a combination of thermogravimetric analysis and differential thermal analysis. The pyrolysis of SU-8 involved gas evolution in a narower range of temperature than polyimide, The adhesion of the carbon film was found to depend on the resist, the substrate, and the heating cycle used. The carbon structures were characterized in terms of their shrinkage during the pyrolysis, the resistivity, the degree of crystallinity and the peak separation in cyclic voltammetry. Carbons derived from pyrolysis of negative resists showed higher resistivity, vertical shrinkage, and peak-to-peak separation voltage than positive resists. Transmission electron microscope results showed a distinct lack of crystallinity even after pyrolysis at 1100°C, unlike the positive resist derived carbon.

Tropical Forests under the Climates of the Last 30,000 Years

Abstract: Vegetational history can help us to predict future environments by providing data for testing AGCMs, for indicating the vegetational response to rapid warming and changing CO2 concentrations, and for mathematical modelling of vegetation. Most of the data are palynological, and there are well over 100 pollen diagrams from tropical regions. Maps are presented showing summarized pollen diagrams from the lowlands of South-East Asia and the West Pacific, Tropical Latin America and Tropical Africa. In all these regions there is some evidence suggesting that at the LGM lowland forests were somewhat restricted in area and included montane elements. This is consistent with cooler and drier climate at the LGM. From the montane and lowland areas of these three regions, the pollen evidence is summarized in altitudinal diagrams. These suggest considerable depression of altitudinal zones at the LGM, suggesting temperatures c. 5–10°C cooler than now. These results conflict with earlier oxygen isotope data from marine foraminifera, but do not conflict with more recent oxygen isotope measurements from tropical corals. It is also suggested that altitudinal movements may be partly controlled by CO2 concentration and ultraviolet light.

Photocurable surgical tissue adhesive glues composed of photoreactive gelatin and poly(ethylene glycol) diacrylate.

Abstract: This article presents a novel photochemically driven surgical tissue adhesive technology using photoreactive gelatins and a water-soluble difunctional macromer (poly(ethylene glycol) diacrylate: PEGDA).The gelatins were partially derivatized with photoreactive groups, such as ultraviolet light (UV)-reactive benzophenone and visible light-reactive xanthene dye (e.g., fluorescein sodium salt, eosin Y, and rose bengal). A series of the prepared photocurable tissue adhesive glues, consisting of the photoreactive gelatin, PEGDA, and a saline solution with or without ascorbic acid as a reducing agent, were viscous solutions under warming, and their effectiveness was evaluated as hemostasis- and anastomosis-aid in cardiovascular surgery. Regardless of the type of photoreactive groups, the irradiation of the photocurable tissue adhesive glues by UV or visible light within 1 min produced water-swollen gels, which had a high adhesive strength to wet collagen film. These were due to the synergistic action of photoreactive group-initiated photo-cross-linking and photograft polymerization. An increase in the irradiation time resulted in increased gel yield and reduced water swellability. A decrease in the molecular weight of PEGDA and an increase in concentration of both gelatin and PEGDA resulted in reduced water swellability and increased tensile and burst strengths of the resultant gels. In rats whose livers were injured with a trephine in laparotomy, the bleeding spots were coated with the photocurable adhesive glue and irradiated through an optical fiber. The coated solution was immediately converted to a swollen gel. The gel was tightly adhered to the liver tissue presumably by interpenetration, and concomitantly hemostasis was completed. The anastomosis treatment with the photocurable glue in the canine abdominal or thoracic aortas incised with a knife resulted in little bleeding under pulsatile flow after declamping. Histological examination showed that the glues photocured on rat liver surfaces were gradually degraded with time in vivo with infiltration of inflammatory cells and connective tissues without necrotic sign in surrounding tissue. In addition, in the laparoscopic surgery, percutaneous delivery of the glue and its in situ photogelation on rat liver surfaces were demonstrated using a specially designed fiberscope. These results indicate that the photocurable glues developed here may serve as a biodegradable tissue adhesive glue usable in cardiovascular surgery and endoscopic surgery.

Tunable photochromism of spirobenzopyran via selective metal ion coordination: an efficient visual and ratioing fluorescent probe for divalent copper ion.

Abstract: In the present paper, a new spirobenzopyran derivative was synthesized and applied in simultaneously colorimetric and fluorescence ratiometric detections of Cu2+. In contrast to the virtually photochromic character of the common spirobenzopyrans in most organic solvents, this spirobenzopyran is colorless in organic aqueous solution even irradiating by ultraviolet light. The formation of red merocyanine in an ethanol-aqueous solution is only induced by Cu2+ coordination. Furthermore, the closed form of the spirobenzopyran is highly fluorescent. Upon complexation with Cu2+, it displays not only decreasing in the initial fluorescence emission band but also appearing in a new emission at long wavelength. Thus, the Cu2+ quantitative measure can be achieved by fluorescence ratiometry. With the optimum conditions described, the Cu2+ concentration can be determined from 5.13 × 10-7 M to 3.81 × 10-4 with a detection limit of 1.06 × 10-7 M. Both the color and the fluorescence changes of the spirobenzopyran are extr...