Topic
Valency
About: Valency is a research topic. Over the lifetime, 1632 publications have been published within this topic receiving 26141 citations.
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TL;DR: In this paper, a new oxime-based hexanuclear MnIII complex containing the structural core (Mn6III(μ3-O)2) was synthesized through a general route.
Abstract: Abstract A new oxime-based hexanuclear MnIII complex containing the structural core [Mn6III(μ3-O)2] was synthesized through a general route. We describe the preparation and characterization of the manganese(III) complex [Mn6III(μ3-O)2(Salox)6(CH3CH2OH)4{(CH3)3CCOO}2] by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS). Therefore we offer the first core level XPS, and XAS reference spectra of polynuclear complexes comprising only Mn(III) ions in octahedral surrounding.
4 citations
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08 Sep 2003
TL;DR: An automatic procedure for pre-annotation of verbal modifications using this valency lexicon of Czech verbs, nouns and adjectives is developed and substantially increases the baseline recall, at the cost of only small decrease of precision.
Abstract: While assigning sentences their so-called tectogrammatical representation, annotators of the Prague Dependency Treebank are also creating a valency lexicon of Czech verbs, nouns and adjectives. Until now, the information contained in it has only been used for visual checking of consistency of valency frame assigned by the annotators. We have developed an automatic procedure for pre-annotation of verbal modifications using this valency lexicon. When adding nodes into the tectogrammatical representation of sentences, our tool substantially increases the baseline recall, at the cost of only small decrease of precision.
4 citations
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4 citations
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TL;DR: In this article, the authors study the influence of the filling of sp states from boron to oxygen impurities in α-iron and show that the main effect of satisfying Friedel's rule is an increase of ionicity in going from bboron to o oxygen.
4 citations