Topic
X-ray absorption fine structure
About: X-ray absorption fine structure is a research topic. Over the lifetime, 4505 publications have been published within this topic receiving 111874 citations. The topic is also known as: XAFS.
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TL;DR: In this paper, a selfconsistent real-space multiple-scattering (RSMS) approach for calculations of x-ray-absorption near-edge structure (XANES) is presented and implemented in an ab initio code applicable to arbitrary aperiodic or periodic systems.
Abstract: A self-consistent real-space multiple-scattering (RSMS) approach for calculations of x-ray-absorption near-edge structure (XANES) is presented and implemented in an ab initio code applicable to arbitrary aperiodic or periodic systems This approach yields a quantitative interpretation of XANES based on simultaneous, self-consistent-field (SCF) calculations of local electronic structure and x-ray absorption spectra, which include full multiple scattering from atoms within a small cluster and the contributions of high-order MS from scatterers outside that cluster In addition, the code includes a SCF estimate of the Fermi energy and an account of orbital occupancy and charge transfer We also present a qualitative, scattering-theoretic interpretation of XANES Sample applications are presented for cubic BN, ${\mathrm{UF}}_{6},$ Pu hydrates, and distorted ${\mathrm{PbTiO}}_{3}$ Limitations and various extensions are also discussed
3,879 citations
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TL;DR: In this paper, the authors focus on extended x-ray absorption fine structure (EXAFS) well above an X-ray edge, and, to a lesser extent, on xray absorption near-edge structure (XANES) closer to an edge.
Abstract: Dramatic advances in the understanding of x-ray absorption fine structure (XAFS) have been made over the past few decades, which have led ultimately to a highly quantitative theory. This review covers these developments from a unified multiple-scattering viewpoint. The authors focus on extended x-ray absorption fine structure (EXAFS) well above an x-ray edge, and, to a lesser extent, on x-ray absorption near-edge structure (XANES) closer to an edge. The discussion includes both formal considerations, derived from a many-electron formulation, and practical computational methods based on independent-electron models, with many-body effects lumped into various inelastic losses and energy shifts. The main conceptual issues in XAFS theory are identified and their relative importance is assessed; these include the convergence of the multiple-scattering expansion, curved-wave effects, the scattering potential, inelastic losses, self-energy shifts, and vibrations and structural disorder. The advantages and limitations of current computational approaches are addressed, with particular regard to quantitative experimental comparisons.
2,721 citations
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1,464 citations
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TL;DR: In this paper, Fourier analysis was applied to the point-scattering theory of x-ray absorption fine structure to invert experimental data formally into a radial structure function with determinable structural parameters of distance from the absorbing atom, number of atoms, and widths of coordination shells.
Abstract: We have applied Fourier analysis to our point-scattering theory of x-ray absorption fine structure to invert experimental data formally into a radial structure function with determinable structural parameters of distance from the absorbing atom, number of atoms, and widths of coordination shells. The technique is illustrated with a comparison of evaporated and crystalline Ge. We find that the first and second neighbors in amorphous Ge are at the crystalline distance within the accuracy of measurement (1%).
1,180 citations