Topic
Xanthene
About: Xanthene is a research topic. Over the lifetime, 2132 publications have been published within this topic receiving 34803 citations. The topic is also known as: Xanthene & dibenzo[a,e]pyran.
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5 citations
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23 Oct 1992TL;DR: In this article, a combination of low linear coefficient of thermal expansion, low dielectric constant, and low water absorption of 9-aryl-9(perfluoroalkyl)xanthene-2,3,6,7-dianhydride or 9-9'-bis-xanthenes-2.3, 6,7, 7-diamidyl benzidine derivatives is proposed.
Abstract: Polyimide compositions, films, and electronic devices using polyimides, based on 9-aryl-9(perfluoroalkyl)xanthene-2,3,6,7-dianhydride or 9,9'-bis(perfluoroalkyl)xanthene-2,3,6,7-dianhydride and benzidine derivatives. These polyimides offer a combination of low linear coefficient of thermal expansion, low dielectric constant, and low water absorption.
5 citations
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TL;DR: In this article, the UV absorption spectra of rhodamine B and G molecules were obtained from industrial dye samples and the conclusion was drawn that the chromaticity property in the series of xanthene dyes appeared because of the formation of supramolecular dimeric and larger aggregates, as was earlier established for triphenylmethane dyes.
Abstract: The UV absorption spectra of rhodamine B and G molecules isolated from industrial dye samples were obtained. Two procedures were used. In one of them, rhodamine B molecules were displaced with water into a heptane layer from a solution of the dye in an alcohol-heptane mixture. The second procedure involved heating of the dye introduced into cellulose triacetate films. Individual rhodamine molecules (namely, dye cation-chlorine anion ion pairs) prepared by both methods did not absorb visible light. The spectra of individual rhodamine molecules coincided with the spectra of so-called pseudoleucobases of xanthene dyes reported in the literature. The conclusion was drawn that the chromaticity property in the series of xanthene dyes appeared because of the formation of supramolecular dimeric and larger aggregates, as was earlier established for triphenylmethane dyes (TPMDs) and copper phthalocyanine (CuPc). At the same time, individual xanthene dye molecules, like TPMD and CuPc molecules, are not chromogens.
5 citations
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30 Jun 1983
TL;DR: In this article, a naphthoic acid derivative was added to a thermo-sensitive recording material containing an electron-donating leuco dye and an electron accepting compound.
Abstract: PURPOSE:To obtain thermo-sensitive recording material, the density of color formation thereof and the sensitivity of color formation thereof are sufficient and the fastness of the color former contained therein is enough, by adding a naphthoic acid derivative to a thermo-sensitive recording material containing an electron-donating leuco dye and an electron accepting compound. CONSTITUTION:An electron-donating leuco dye, such as a triarylmethane compound, a diphenylmethane compound, a xanthene compound, a thiazine compound, or a spiro-pyrane compound, an electron-accepting compound, such as a phenol compound, and a naphthoate ester of the formula (wherein R is an alkoxy group, an aralkyloxy group, an arylamino group, etc., and a naphthalene ring may have a substituent such as a halogen atom or an alkyl group) or naphthoamide are dispersed separately in water-soluble polymer solutions and mixed, and an inorganic pigment, such as kaoline, and other additives are added to prepare a coating liquid. The liquid is applied onto thick paper.
5 citations
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04 Feb 2014TL;DR: In this article, a colorant dispersion liquid which is able to form a high-luminance coating film having better heat resistance compared to the case of using conventional dyes is presented.
Abstract: The present invention is to provide a colorant dispersion liquid which is able to form a high-luminance coating film having better heat resistance compared to the case of using conventional dyes. Disclosed is a colorant dispersion liquid containing (A) a colorant, (B) a dispersant, and (C) a solvent, wherein the colorant (A) contains a color material represented by the following general formula (I) and a xanthene-based dye; a solubility of the color material in the solvent (C) and that of the xanthene-based dye in the solvent (C) are each 0.2 (g/100 g solvent) or less at 23° C.; and the color material and the xanthene-based dye are dispersed in the solvent (C) by the dispersant (B): (The symbols in the formula are as described in the Description.)
5 citations