Showing papers on "Young's modulus published in 2014"

Mechanical properties of hybrid organic-inorganic CH3NH3BX3 (B = Sn, Pb; X = Br, I) perovskites for solar cell absorbers

Abstract: The crystal structures, elastic and anisotropic properties of CH3NH3BX3 (B = Sn, Pb; X = Br, I) compounds as solar cell absorber layers are investigated by the first-principles calculations. The type and strength of chemical bond B-X are found to determine the elastic properties. B-X bonds and the organic cations are therefore crucial to the functionalities of such absorbers. The bulk, shear, Young's modulus ranges from 12 to 30 GPa, 3 to 12 GPa, and 15 to 37 GPa, respectively. Moreover, the interaction among organic and inorganic ions would have negligible effect for elastic properties. The B/G and Poisson's ratio show it would have a good ductile ability for extensive deformation as a flexible/stretchable layer on the polymer substrate. The main reason is attributed to the low shear modulus of such perovskites. The anisotropic indices AU, AB AG, A1, A2, and A3 show ABX3 perovskite have very strong anisotropy derived from the elastic constants, chemical bonds, and symmetry.

Mechanical Properties of Conjugated Polymers and Polymer‐Fullerene Composites as a Function of Molecular Structure

Abstract: Despite the importance of mechanical compliance in most applications of semiconducting polymers, the effects of structural parameters of these materials on their mechanical properties are typically not emphasized. This paper examines the effect of length of the pendant group on the tensile modulus and brittleness for a series of regioregular poly(3-alkylthiophenes) (P3ATs) and their blends with a soluble fullerene derivative, PCBM. The tensile modulus decreases with increasing length of the alkyl side-chain, from 1.87 GPa for butyl side chains to 0.16 GPa for dodecyl chains. The moduli of P3AT:PCBM blends films are greater than those of the pure polymers by factors of 2–4. A theoretical model produces a trend in the effect of alkyl side chain on tensile modulus that follows closely to the experimental measurements. Tensile modulus correlates with brittleness, as the strain at which cracks appear is 6% for P3BT and >60% for P3OT. Adhesion of the P3AT film to a polydimethylsiloxane (PDMS) substrate is believed to play a role in an apparent increase in brittleness from P3OT to P3DDT. The additive 1,8-Diiodooctane (DIO) reduces the modulus of P3HT:PCBM blend by a factor of 3. These results could enable mechanically robust, flexible, and stretchable electronics.

Cellulose Nanocrystals Mechanical Reinforcement in Composite Hydrogels with Multiple Cross-Links: Correlations between Dissipation Properties and Deformation Mechanisms

Abstract: Nanocomposites have drawn a great interest in materials science of elastomers in recent years, and tailoring interfacial interactions between fillers and polymer matrix plays a critical role in improving their mechanical properties. The synthetic platform of tough and stretchable cellulose nanocrystal–poly(acrylamide) (CNC–PAM) composite hydrogels was proposed and applied here to unravel the role of covalent network in PAM and physical interactions by CNC surface adsorption. The attractive physical interactions in the network were considered to increase the fracture strength of the hydrogels via reversible adsorption–desorption processes on the CNC surface. Stress-sensitive characteristic shifts of the Raman peak located at 1095 cm–1 indicated an efficient load transfer across the interface, where the tensile modulus was higher than the compression modulus. In situ transmission electron microscopy observation allowed to demystify the composites deformation process and interfacial bridging between CNC and ...

Effect of Nb addition on the structure and mechanical behaviors of CoCrCuFeNi high-entropy alloy coatings

Abstract: The microstructure and mechanical properties of the CoCrCuFeNiNb high-entropy alloy coating prepared by plasma transferred arc cladding process were investigated. Two phases are found in the prepared coating with Nb: one is face-centered-cubic solid solution phase; the other is the Laves phase of (CoCr) Nb type. The nano-indentation testing indicates that the microhardness (H), elastic modulus (E), the hardness/modulus of elasticity ratio (H/E ratio) and high resistance to plastic deformation (H3/E2) of the coating with Nb are 6.13 GPa, 221 GPa, 0.028 and 4.7 × 10− 3 respectively. The CoCrCuFeNiNb coating displays excellent wear and corrosion resistance. The wear resistance of the coating with Nb is about 1.5 times higher than that of the coating without Nb under the same wet sand rubber wheel abrasion testing conditions. Compared with the coating without Nb and as-cast 304 stainless steel, the coating with Nb shows the lowest icorr values in polarization curves and the highest fitted Rf values in EIS plots in 6N hydrochloric acid solution.

Effects of extrusion temperature on the rheological, dynamic mechanical and tensile properties of kenaf fiber/HDPE composites

Abstract: The effects of extrusion processing temperature on the rheological, dynamic mechanical analysis and tensile properties of kenaf fiber/high-density polyethylene (HDPE) composites were investigated for low and high processing temperatures. The rheological data showed that the complex viscosity, storage and loss modulus were higher with high processing temperature. Complex viscosities of pure HDPE and 3.4 wt% composite with zero shear viscosity of ⩽2340 Pa s were shown to exhibit Newtonian behavior while composites of 8.5 and 17.5 wt% with zero shear viscosity ⩾30,970 Pa s displayed non-Newtonian behavior. The Han plots revealed the sensitivity of rheological properties with changes in processing temperature. An increase in storage and loss modulus and a decrease in mechanical loss factor were observed for 17.5 wt% composites at high processing temperature and not observed at low processing temperature. Processing at high temperature was found to improve the tensile modulus of composites but displayed diminished properties when processed at low processing temperature especially at high fiber content. At both low and high processing temperatures, the tensile strength and strain of the composite decreased with increased content of the fiber.

Mechanical properties of MoS2/graphene heterostructures

Abstract: We perform classic molecular dynamics simulations to comparatively investigate the mechanical properties of single-layer MoS2 and a graphene/MoS2/graphene heterostructure under uniaxial tension. We show that the lattice mismatch between MoS2 and graphene will lead to an spontaneous strain energy in the interface. The Young's modulus of the heterostructure is much larger than that of MoS2. While the stiffness is enhanced, the yield strain of the heterostructure is considerably smaller than the MoS2 due to lateral buckling of the outer graphene layers owning to the applied mechanical tension.

Structural behavior of concrete filled steel tubular sections (CFT/CFSt) under axial compression

Abstract: In this study, compressive strength, modulus of elasticity and steel tensile coupon tests are performed to determine material properties. Sixteen hollow cold formed steel tubes and 48 concrete filled steel tube specimens are used for axial compression tests. The effects of width/thickness ratio (b/t), the compressive strength of concrete and geometrical shape of cross section parameters on ultimate loads, axial stress, ductility and buckling behavior are investigated. Circular, hexagonal, rectangular and square sections, 18.75, 30.00, 50.00, 100.00 b/t ratio values and 13, 26, 35 MPa concrete compressive strength values are chosen for the experimental procedure. Analytical models of specimens are developed using a finite element program (ABAQUS) and the results are compared. Circular specimens are the most effective samples according to both axial stress and ductility values. The concrete in tubes has experienced considerable amount of deformations which is not expected from such a brittle material in certain cases. The results provide an innovative perspective on using cold formed steel and concrete together as a composite material.

Young’s Modulus of Austenite and Martensite Phases in Superelastic NiTi Wires

Abstract: Young’s moduli of superelastic NiTi wires in austenite and stress-induced martensite states were evaluated by three different experimental methods (tensile tests, in situ synchrotron x-ray diffraction, and dynamic mechanical analysis) and estimated via theoretical calculation from elastic constants. The unusually low value of the Young’s modulus of the martensite phase appearing in material property tables (<40 GPa) is generally ascribed in the literature to the fact that stress-driven martensitic transformation and/or twinning processes continue even beyond the transformation range and effectively decrease the value of the tangent modulus evaluated from macroscopic stress-strain curve. In this work, we claim that this low value is real in the sense that it corresponds to the appropriate combination of elastic constants of the B19′ martensite phase forming the polycrystalline wire. However, the Young’s modulus of the martensite phase is low only for wire loaded in tension, not for compression or other deformation modes. It is shown that the low value of the martensite Young’s modulus in tension is due to the combination of the unique coincidence of elastic anisotropy of the B19′ martensite characterized by the low elastic constant C55, austenite drawing texture, and strong martensite texture due to the martensite variant selection under tensile stress.

Analysis of effect of fiber orientation on Young’s modulus for unidirectional fiber reinforced composites

Abstract: Young’s modulus of unidirectional glass fiber reinforced polymer (GFRP) composites for wind energy applications were studied using analytical, numerical and experimental methods. In order to explore the effect of fiber orientation angle on the Young’s modulus of composites, from the basic theory of elastic mechanics, a procedure which can be applied to evaluate the elastic stiffness matrix of GFRP composite as an analytical function of fiber orientation angle (from 0° to 90°), was developed. At the same time, different finite element models with inclined glass fiber were developed via the ABAQUS Scripting Interface. Results indicate that Young’s modulus of the composites strongly depends on the fiber orientation angles. A U-shaped dependency of the Young’s modulus of composites on the inclined angle of fiber is found, which agree well with the experimental results. The shear modulus is found to have significant effect on the composites’ Young’s modulus, too. The effect of volume content of glass fiber on the Young’s modulus of composites was investigated. Results indicate the relation between them is nearly linear. The results of the investigation are expected to provide some design guideline for the microstructural optimization of the glass fiber reinforced composites.

Eigenvalue approach in a three-dimensional generalized thermoelastic interactions with temperature-dependent material properties

Abstract: A three-dimensional model of the generalized thermoelasticity without energy dissipation under temperature-dependent mechanical properties is established. The modulus of elasticity is taken as a linear function of the reference temperature. The resulting formulation in the context of Green and Naghdi model II is applied to a half-space subjected to a time-dependent heat source and traction free surface. The normal mode analysis and eigenvalue approach techniques are used to solve the resulting non-dimensional coupled equations. Numerical results for the field quantities are given in the physical domain and illustrated graphically. The results are also compared to results obtained in the case of temperature-independent modulus of elasticity.

A tough shape memory polymer with triple-shape memory and two-way shape memory properties

Abstract: In this study, a tough shape memory polymer network based on polydopamine, poly(e-caprolactone) and diisocyanate was synthesized in three steps. Fourier transform infrared spectroscopy was used to confirm the synthesis process. The tensile tests demonstrated the good mechanical properties of the materials with a tensile modulus and tensile strength reaching 362 and 43 MPa, respectively, at room temperature. The thermal properties of the polymer networks were investigated using differential scanning calorimetry and dynamic mechanical analysis. With two broad transition temperatures, the dual-shape memory properties were greatly affected by the deformation temperature, which was investigated in detail. Moreover, the polymers also showed good triple-shape memory and two-way shape memory effects.

Enhanced mechanical properties of graphene/natural rubber nanocomposites at low content

Abstract: Graphene/natural rubber (GE/NR) nanocomposites were prepared by a modified latex mixing method combined with in situ chemical reduction. It was found that the GE nanosheets are well dispersed and have strong interfacial interaction with NR. Thus, adding a low content of GE can remarkably increase the tensile strength and the initial tensile modulus of NR. With incorporation of as low as 0.5 phr of GE, a 48% increase in the tensile strength and an 80% increase in the initial tensile modulus are achieved without sacrificing the ultimate strain. But further increasing the GE loading degrades the tensile strength and the ultimate strain. Dynamic mechanical measurement indicates that the storage modulus of the nanocomposites is greatly enhanced with addition of GE, while the loss tangent peak is depressed due to the reduced mobility of the rubber molecules. The reinforcement effect of GE on NR is interpreted as a change in the strain induced crystallization and network structure of the nanocomposites, based on the analysis of Mooney − Rivlin plots and the tube model.© 2013 Society of Chemical Industry

Fabrication and mechanical characterization of graphene oxide-reinforced poly (acrylic acid)/gelatin composite hydrogels

Abstract: Hydrogels have found many practical uses in drug release, wound dressing, and tissue engineering. However, their applications are restricted due to their weak mechanical properties. The role of graphene oxide nanosheets (GONS) as reinforcement agent in poly (acrylic acid) (PAA)/Gelatin (Gel) composite hydrogels is investigated. Composite hydrogels are synthesized by thermal initiated redox polymerization method. Samples are then prepared with 20 and 40 wt. % of PAA, an increasing amount of GONS (0.1, 0.2, and 0.3 wt. %), and a constant amount of Gel. Subsequently, cylindrical hydrogel samples are subjected to a series of compression tests in order to measure their elastic modulus, maximum stress and strain. The results exhibit that the addition of GONS increases the Young's modulus and maximum stress of hydrogels significantly as compared with control (0.0 wt. % GONS). The highest Young's modulus is observed for hydrogel with GO (0.2 wt. %)/PAA (20 wt. %), whereas the highest maximum stress is detected for GO (0.2 wt. %)/PAA (40 wt. %) specimen. The addition of higher amounts of GONS leads to a decrease in the maximum stress of the hydrogel GO (0.3 wt. %)/PAA (40 wt. %). No significant differences are detected for the maximum strain among the hydrogel samples, as the amount of GONS increased. These results suggest that the application of GONS could be used to improve mechanical properties of hydrogel materials. This study may provide an alternative for the fabrication of low-cost graphene/polymer composites with enhanced mechanical properties beneficial for tissue engineering applications.

Comparative study on structure, energetic and mechanical properties of a ε-CL-20/HMX cocrystal and its composite with molecular dynamics simulation

Abstract: Molecular dynamics (MD) simulation was conducted for a e-CL-20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexazisowurtzitane) crystal, a β-HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazocane) crystal, a e-CL-20/HMX cocrystal and its composite with the same molar ratio as in the cocrystal using a COMPASS force field with NPT ensemble at different temperatures. The maximum bond length (Lmax) of the N–NO2 trigger bond, cohesive energy density (CED) and binding energy (Ebind) between HMX and CL-20 molecules as well as elastic properties were calculated. Lmax increases with rising temperature and is found to be in the order of e-CL-20/HMX cocrystal < CL-20/HMX composite < e-CL-20 crystal at the same temperature. CED and Ebind of the cocrystal decrease with increasing temperature and are all greater than those of the composite at the same temperature. These indicate that the cocrystal is the most insensitive and its thermal stability is better than that of the composite. Furthermore, the pair correlation function g(r) analysis reveals that hydrogen bonds exist. The tensile modulus (E), bulk modulus (K) and shear modulus (G) of the e-CL-20/HMX cocrystal and the composite are smaller than those of e-CL-20 and β-HMX crystals and decrease with increasing temperature. However, the K/G values of the cocrystal and the composite are larger than those of the other two crystals, implying that they have better ductility.

Young's modulus

Abstract: A constant designated E, the ratio of stress to corresponding strain when the material behaves elast…