Volcanoes are unstable structures that deform laterally and frequently experience mass wasting events. Hydrothermal alteration is often invoked as a mechanism that contributes significantly to volcano instability. We present a study that combines laboratory experiments, geophysical data, and large-scale numerical modeling to better understand the influence of alteration on volcano stability, using La Soufriere de Guadeloupe (Eastern Caribbean) as a case study. Laboratory experiments on variably altered (advanced argillic alteration) blocks show that uniaxial compressive strength, Young's modulus, and cohesion decrease as a function of increasing alteration, but that the internal friction angle does not change systematically. Simplified volcano cross sections were prepared (a homogenous volcano, a volcano containing the alteration zone identified by a recent electrical survey, and a volcano with an artificially enlarged area of alteration) and mechanical properties were assigned to zones corresponding to unaltered and altered rock. Numerical modeling performed on these cross sections, using a hydro-thermo-mechanical modeling code, show (a) the importance of using upscaled values in large-scale models and (b) that alteration significantly increases volcano deformation and collapse volume. Finally, we combined published muon tomography data with our laboratory data to create a 3D strength map, exposing a low-strength zone beneath the southern flank of the volcano coincident with the hydrothermal system. We conclude that hydrothermal alteration decreases volcano stability and thus expedites volcano spreading and increases the likelihood of mass wasting events and associated volcanic hazards. Hydrothermal alteration, and its evolution, should therefore be monitored at active volcanoes worldwide.

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Alteration-Induced Volcano Instability at La Soufrière de Guadeloupe (Eastern Caribbean)

Active and fossil hydrothermal zones of the Apacheta volcano: Insights for the Cerro Pabellón hidden geothermal system (Northern Chile)


 The hydrothermally active Brothers volcano on the Kermadec arc, New Zealand, hosts two geochemically distinct hydrothermal systems within a single caldera. At the NW Caldera, metal-sulfide–rich black smoker spires form on the caldera wall. In contrast, Fe-rich crusts and native sulfur-rich chimneys occur at the resurgent central Upper Cone. Previous studies have revealed that the contrasting styles of hydrothermalism relate to the variable contribution of magmatic volatiles between these sites, with the Upper Cone experiencing relatively higher amounts of magmatic volatile influx. We present results of a study of the hydrothermal alteration within Brothers volcano based on core samples to a depth of 453 meters below sea floor (mbsf) from both the Upper Cone (Site U5128) and NW Caldera sites (Site U1527 and U1530), drilled by the International Ocean Discovery Program. The dacitic to rhyolitic breccias that make up the volcano are variably altered to alteration mineral assemblages consisting of chlorite + quartz, illite + pyrophyllite, natroalunite + pyrophyllite, and smectite-rich assemblages. The distribution and textures of the alteration minerals within and between different sites at Brothers volcano reflect variations in temperature, fluid pH, and fluid flux. We find that natroalunite only occurs at the Upper Cone, while alteration at the NW Caldera is more diverse and is characterized by both chlorite and pyrophyllite-rich alteration, indicating that seawater-derived hydrothermal fluids overprinted earlier magmatic volatile-influenced alteration. Our data indicate that in magmatic volatile-dominated systems, the alteration mineralogy transitions from natroalunite to pyrophyllite-rich with increasing age or maturity. This is accompanied by a distinct change in sample texture from dominantly bleached selvages to a more massive, equigranular texture.

Hydrothermal Alteration Within the Brothers Submarine Arc Volcano, Kermadec Arc, New Zealand

Ophiolites are the remnants of ancient oceanic crust that can serve as tools to reconstruct the evolutionary history of fossil oceans. At Boumnyebel, the western part of the Yaoundé group, the sole of the lower unit (magnesian mica-schists and gneiss) of the Pan-African nappes is made up of ophiolitic rocks (talc schists, chlorite schists, serpentinites, amphibolites, pyroxenites, hornblendites). Structurally, the lower unit has a flat-lying schistosity with some recumbent folds while the underlying TTG gneisses are marked by a high-dipping foliation at Mapan. The contact between the Pan-African mica schists and the basement formations (Congo craton) is therefore discordant. In ophiolitic rocks, amphibole is actinolite, tremolite or magnesio-riebeckite. Chlorite compositions correspond to clinochlore. Talc shows notable substitution of Mg by Fe whereas substitution of Mg by Fe and Al prevails in serpentine. Spinel compositions are either Cr-rich with high FeO/Fe2O3 values (peridotitic spinels) or Cr-poor with low FeO/Fe2O3 values (melt-derived or magmatic spinels). Main mineral features indicate a metamorphic retromorphosis of the original lherzolites, harzburgites, dunites and pyroxenites to hornblendites and serpentinites. This is followed by hydrothermal alteration (at various temperatures: 250–570 °C and low pressure: < 2 kbar) that yielded chlorite schists and talc schists. Chemically, talc schists are made up of SiO2, MgO and minor FeO and Al2O3, while chlorite schists and hornblendites contain notable amounts of Al2O3 and CaO, respectively. All the ultramafic rocks display the same range of high Ni, Cr, Co contents with various LREE enrichments but flat HREE patterns. Multi-element patterns show that most talc schist are depleted in almost all elements. All the ultramafic rocks are marked by deep Nb, Ta, K, Pb, Sr, Ti, Zr and Hf troughs suggesting that the ultramafic rocks possibly derived from heterogeneous mantle sources varying from fertile to refractory peridotites. Amphibolites are generated from N-MORB, IAT or CA geotectonic settings. The compositions of spinel and ultramafic whole rocks reveal an arc setting that has evolved from divergent plate setting (oceanisation, N-MORB) to convergent plate (IAT, CA, SSZ D-MORB) settings. In summary, ophiolites emplaced in various geotectonic settings and were amalgamated during the Pan-African collision. 

Petrology of ophiolites of Memel, Nsimè-Kellé and Mapan (Yaoundé group): Evidence of the geodynamic evolution of the Pan-African orogeny in South Cameroon

Clay minerals are the signature of hydrothermal alterations related to fluid circulation in volcanic and crystalline rocks. In the French part of the Upper Rhine Graben, in the deep-seated granites, illitic minerals (illite and I/S mixed layers (ml)) are typical products of the structurally-controlled argillic alteration in the Paleozoic granitic basement. In the new Illkirch geothermal well, GIL-1, drill-cuttings were studied with various petrographic methods to determine the characteristics of illite in paleo- and present-permeable zones, and to compare the alteration mineralogy with that of geothermal Soultz-sous-Forets and Rittershoffen sites. Alteration petrography, crystal structure as well as the chemical composition of the illitic minerals and the altered bulk rocks were performed all along the well. This complete characterization, combined with geophysical logs and structural results, highlighted that the illitic minerals at Illkirch, Soultz-sous-Forets, and Rittershoffen are composed of illite and illite-rich illite-smectite mixed layers (I/S ml) (<10% smectite). Two mineralogical assemblages were distinguished: chlorite + illite resulting from the propylitic alteration after the emplacement of the granitic basement under temperatures higher than 350 °C, and illite + I/S ml + carbonates + quartz resulting from the argillic alteration due to fluid circulation in the fractures at temperatures between 130 and 160 °C. Fracture zones are characterized by the occurrence of illitic minerals (illite and I/S ml), and specifically, by higher quantities of I/S ml in present-day permeable zones than in paleo-permeable zones. A conceptual model of the fracture zones at the interface between the overlying sedimentary rocks and the granitic basement is proposed. The present-day permeability distribution is controlled by the fault and fracture network, which consists of sealed zones and unsealed zones. Fluid convection in the URG implies paleo and present fluids circulating in both fractured sedimentary and crystalline reservoirs. Such circulations develop illitic minerals that could be considered as exploration guides for future geothermal sites in the URG. At Illkirch, the repartition of the present-permeable fracture zones (KFZs) in the GIL-1 well indicates that the moderately argillically altered granite distally situated from the Eschau fault is more permeable than the intensely argillically altered granite close to the Eschau fault.

https://www.mdpi.com/2075-163X/11/5/479/pdf

Clay Mineralogy: A Signature of Granitic Geothermal Reservoirs of the Central Upper Rhine Graben

The study of active and fossil hydrothermal systems shows clay minerals to be a fundamental tool for the identification and characterization of hydrothermal alteration facies. The occurrence and composition of hydrothermal alteration facies could provide useful information on the physicochemical conditions of the hydrothermal activity affecting a rock volume. In particular, clay minerals (i.e., smectite group, chlorite, illite, kaoline group, pyrophyllite, biotite) are pivotal for extrapolating important parameters that strongly affect the development of water/rock interaction processes such as the temperature and pH of the hydrothermal environment. This work aims to give a general reference scheme concerning the occurrence of clay minerals in hydrothermal alteration paragenesis, their significance, and the information that can be deduced by their presence and chemical composition, with some examples from active and fossil hydrothermal systems around the world. The main mineralogical geothermometers based on chlorite and illite composition are presented, together with the use of hydrogen and oxygen isotope investigation of clay minerals in hydrothermal systems. These techniques provide a useful tool for the reconstruction of the origin and evolution of fluids involved in hydrothermal alteration. Finally, a list of oxygen and hydrogen fractionation factor equations between the main clay minerals and water is also provided.

Paolo Fulignati

Papers

Clay Minerals in Hydrothermal Systems