Magnetic cooling could be a radically different energy solution that could replace conventional vapour compression refrigeration in the future. It is now shown that a Heusler-type magnetocaloric alloy exhibits a remarkable cooling capability due to the effect of a sharp structural transformation at a specific temperature. The finding may be of relevance beyond Heusler alloys and represents an important step towards the implementation of cooling systems based on magnetocaloric materials.

Giant magnetocaloric effect driven by structural transitions

A magnetically, electrically or mechanically responsive material can undergo significant thermal changes near a ferroic phase transition when its order parameter is modified by the conjugate applied field. The resulting magnetocaloric, electrocaloric and mechanocaloric (elastocaloric or barocaloric) effects are compared here in terms of history, experimental method, performance and prospective cooling applications.

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Caloric materials near ferroic phase transitions

This review paper illustrates the main normal and superconducting state properties of magnesium diboride, a material known since the early 1950s but only recently discovered to be superconductive at a remarkably high critical temperature Tc = 40 K for a binary compound. What makes MgB2 so special? Its high Tc, simple crystal structure, large coherence lengths, high critical current densities and fields, and transparency of grain boundaries to current promise that MgB2 will be a good material for both large-scale applications and electronic devices. During the last seven months, MgB2 has been fabricated in various forms: bulk, single crystals, thin films, tapes and wires. The largest critical current densities, greater than 10 MA cm−2, and critical fields, 40 T, are achieved for thin films. The anisotropy ratio inferred from upper critical field measurements is yet to be resolved as a wide range of values have been reported, γ = 1.2–9. Also, there is no consensus on the existence of a single anisotropic or double energy gap. One central issue is whether or not MgB2 represents a new class of superconductors, which is the tip of an iceberg awaiting to be discovered. To date MgB2 holds the record for the highest Tc among simple binary compounds. However, the discovery of superconductivity in MgB2 revived the interest in non-oxides and initiated a search for superconductivity in related materialss; several compounds have since been announced to be superconductive: TaB2, BeB2.75, C–S composites, and the elemental B under pressure.

https://iopscience.iop.org/article/10.1088/0953-2048/14/11/201/pdf

Review of the superconducting properties of MgB2

Magnetocaloric effect: From materials research to refrigeration devices

This review paper illustrates the main normal and superconducting state properties of magnesium diboride, a material known since early 1950's, but recently discovered to be superconductive at a remarkably high critical temperature Tc=40K for a binary compound. What makes MgB2 so special? Its high Tc, simple crystal structure, large coherence lengths, high critical current densities and fields, transparency of grain boundaries to current promises that MgB2 will be a good material for both large scale applications and electronic devices. During the last seven month, MgB2 has been fabricated in various forms, bulk, single crystals, thin films, tapes and wires. The largest critical current densities >10MA/cm2 and critical fields 40T are achieved for thin films. The anisotropy ratio inferred from upper critical field measurements is still to be resolved, a wide range of values being reported, between 1.2 and 9. Also there is no consensus about the existence of a single anisotropic or double energy gap. One central issue is whether or not MgB2 represents a new class of superconductors, being the tip of an iceberg who awaits to be discovered. Up to date MgB2 holds the record of the highest Tc in its class. However, the discovery of superconductivity in MgB2 revived the interest in non-oxides and initiated a search for superconductivity in related materials, several compounds being already announced to become superconductive: TaB2, BeB2.75, C-S composites, and the elemental B under pressure.

Review of superconducting properties of MgB2

A relatively high critical temperature, Tc, approaching 40 K, places the recently-discovered superconductor magnesium diboride (MgB2) intermediate between the families of low- and copper-oxide-based high-temperature superconductors (HTS). Supercurrent flow in MgB2 is unhindered by grain boundaries, unlike the HTS materials. Thus, long polycrystalline MgB2 conductors may be easier to fabricate, and so could fill a potentially important niche of applications in the 20 to 30 K temperature range. However, one disadvantage of MgB2 is that in bulk material the critical current density, Jc, appears to drop more rapidly with increasing magnetic field than it does in the HTS phases. The magnitude and field dependence of Jc are related to the presence of structural defects that can "pin" the quantised magnetic vortices that permeate the material, and prevent them from moving under the action of the Lorentz force. Vortex studies suggest that it is the paucity of suitable defects in MgB2 that causes the rapid decay of Jc with field. Here we show that modest levels of atomic disorder, induced by proton irradiation, enhance the pinning, and so increase Jc significantly at high fields. We anticipate that chemical doping or mechanical processing should be capable of generating similar levels of disorder, and so achieve technologically-attractive performance in MgB2 by economically-viable routes.

https://arxiv.org/pdf/cond-mat/0104156.pdf

Enhancement of the high-field critical current density of superconducting MgB2 by proton irradiation

The recently discovered1 superconductor magnesium diboride, MgB2, has a transition temperature, Tc, approaching 40 K, placing it intermediate between the families of low- and high-temperature superconductors. In practical applications, superconductors are permeated by quantized vortices of magnetic flux. When a supercurrent flows, there is dissipation of energy unless these vortices are ‘pinned’ in some way, and so inhibited from moving under the influence of the Lorentz force. Such vortex motion ultimately determines the critical current density, Jc, which the superconductor can support. Vortex behaviour has proved to be more complicated in high-temperature superconductors than in low-temperature superconductors and, although this has stimulated extensive theoretical and experimental research2, it has also impeded applications. Here we describe the vortex behaviour in MgB2, as reflected in Jc and in the vortex creep rate, S, the latter being a measure of how fast the ‘persistent’ supercurrents decay. Our results show that naturally occurring grain boundaries are highly transparent to supercurrents, a desirable property which contrasts with the behaviour of the high-temperature superconductors. On the other hand, we observe a steep, practically deleterious decline in Jc with increasing magnetic field, which is likely to reflect the high degree of crystalline perfection in our samples, and hence a low vortex pinning energy.

Vortex dynamics in superconducting MgB2 and prospects for applications.

Magnets fabricated with HTS wire can not be operated in a true persistent mode as superconducting joints of sufficient technological quality have not been achieved to date. In order to maintain a constant magnetic field in a HTS magnet a power supply has to be permanently employed, which then leads to heat losses in the cryo-system through the employment of current leads. By using a flux pump these losses can be minimized. We present a new flux pump based on 2G HTS wire. This device energized at 77 K a 2.7 mH 2G HTS double-pancake coil to its critical current of 49 A within 112 seconds. The operating principle will be described and data of the current ramping is shown. Considering the simplicity of the device and the potential to increase the generated current to 200 A and more, this new flux pump is very promising for many superconducting devices including HTS and LTS magnets and rotating machines.

Flux Pump for HTS Magnets

First order ferromagnetic (FM) to antiferromagnetic (AFM) phase transition in doped ${\mathrm{CeFe}}_{2}$ alloys is studied with the micro-Hall probe technique. Clear visual evidence of magnetic phase coexistence on micrometer scales and the evolution of this phase coexistence as a function of temperature, magnetic field, and time across the first order FM-AFM transition is presented. Such phase coexistence and metastability arise as a natural consequence of an intrinsic disorder-influenced first order transition. The generality of these phenomena involving other classes of materials is discussed.

First Order Magnetic Transition in Doped CeFe 2 Alloys: Phase Coexistence and Metastability

The influence of the oxygen stoichiometry on magnetization and relaxation of R${\mathrm{Ba}}_{2}$${\mathrm{Cu}}_{3}$${\mathrm{O}}_{7\mathrm{\ensuremath{-}}\mathrm{\ensuremath{\delta}}}$ (R=Y,Tm) single crystals was studied for 0\ensuremath{\le}\ensuremath{\delta}\ensuremath{\le}0.55. The field dependences of the shielding currents ${\mathit{j}}_{\mathit{s}}$(H) and flux creep rates S(H) were analyzed. Three different kinds of ${\mathit{j}}_{\mathit{s}}$(H) and S(H) behavior can be seen in highly oxygenated samples (\ensuremath{\delta}0.1). (i) At high temperatures, ${\mathit{j}}_{\mathit{s}}$(H) shows a common fishtail peak, which is present for all oxygen contents. The field position and height of the ${\mathit{j}}_{\mathit{s}}$ peak increase rapidly with decreasing \ensuremath{\delta}. Approaching the stoichiometric state \ensuremath{\delta}=0, the value of the current starts to decrease with lower oxygen deficiency, in contrast to the still increasing irreversibility field ${\mathit{B}}_{\mathrm{irr}}$. This points to the importance of oxygen disorder for the pinning and stresses the melting nature of the irreversibility line. The peak position ${\mathit{B}}_{\mathrm{max}}$ is found to correlate with ${\mathit{B}}_{\mathrm{irr}}$. A possible relation of the fishtail with a synchronization effect and with the vanishing of ${\mathrm{C}}_{66}$ at the melting transition is proposed. (ii) In the intermediate-temperature region, some of the samples showed a new second peak with weak temperature and \ensuremath{\delta} dependence. The probable origin of this feature is matching with twin structure. This peak disappears for \ensuremath{\delta}g0.1, when the fishtail position shifts below the matching field. (iii) The low-temperature region is characterized by a monotonic decrease of ${\mathit{j}}_{\mathit{s}}$(B). This region becomes narrower with larger \ensuremath{\delta} and disappears for \ensuremath{\delta}g0.3. Thus in highly deoxygenated samples, the fishtail feature is observed for practically all temperatures. The possible connection of the low-temperature region with the pinning of the small vortex bundles or with the slipping of vortices along the twin planes is considered.

A.D. Caplin

Papers

Enhancement of the high-field critical current density of superconducting MgB2 by proton irradiation

Vortex dynamics in superconducting MgB2 and prospects for applications.

Flux Pump for HTS Magnets

First Order Magnetic Transition in Doped CeFe 2 Alloys: Phase Coexistence and Metastability

Influence of oxygen stoichiometry on the irreversible magnetization and flux creep in RBa2Cu3O7- delta (R=Y,Tm) single crystals.